Wave Front Behavior in Adsorption Reactors
Publication: Journal of Environmental Engineering
Volume 118, Issue 4
Abstract
This paper describes computer modeling experiments for single adsorbate flow through a packed‐bed adsorption reactor to examine the behavior of concentration “wave fronts” for aqueous and solid phases. Conclusions were: (1) The shape of the wave front assumes a steady‐state shape after development; (2) the wave front has constant velocity; (3) the solid‐phase wave front is synoptic with the aqueous‐phase wave front; (4) the wave‐front velocity can be predicted from isotherm data; and (5) the adsorbate‐concentration breakthrough curve can be calculated from wave‐front data. These conclusions relate directly to design and operation. First, the length of the reactor can be calculated by wave‐front velocity, which can be determined from isotherm data. Second, for pilot plant studies the major interest includes wave‐front shape, length, and velocity. Third, in operation, the progress of the wave front should be monitored to predict the breakthrough curve.
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References
1.
Water Treatment Plant Design. (1990). 2nd Ed., McGraw‐Hill Book Co., Inc., New York, N.Y.
2.
Clark, R. M., and Lykins, B. W. (1989). Granular activated carbon—design, operation, and cost. Lewis Publishers, Chelsea, Mich.
3.
Crittenden, J. C., and Weber, W. J., Jr. (1975). “MADAM I—numeric method for design of adsorption systems.” J. Water Pollution Control Federation, 47, 924–940.
4.
Dostal, K. A., Pierson, R. C., Hager, D. G., and Robeck, G. G. (1965). “Carbon bed design criteria study at Nitro, W. Va.” JAWWA, 57(5), 663–674.
5.
Process design manual for carbon adsorption. (1971). Technology Transfer Division, U.S. Environmental Protection Agency, Cincinnati, Ohio.
6.
Process design manual for carbon adsorption. (1973). Technology Transfer Division, U.S. Environmental Protection Agency, Cincinnati, Ohio.
7.
Hager, D. G., and Flentje, M. E. (1965). “Removal of organic contaminants by granular carbon‐filtration.” JAWWA, 57(11), 1440–1450.
8.
Hendricks, D. W. (1972). “Sorption in flow through porous media.” Fundamentals of transport phenomena in porous media, Elsevier Press, Amsterdam, The Netherlands.
9.
Hendricks, D. W. (1973). “Sorption kinetics. II: Modeling longitudinal concentration profiles a packed bed reactor.” Report PRW66‐2, Utah State University, Logan, Utah.
10.
Hendricks, D. W. (1980). “Convection limited sorption kinetics in packed beds.” J. Envir. Engrg. Div., ASCE, 106(4), 727–739.
11.
Hendricks, D. W., and Kuratti, L. G. (1973). “Sorption kinetics. I: Laboratory investigation of six proposed rate laws.” Report PRW66‐1, Utah State University, Logan, Utah.
12.
Hendricks, D. W., and Kuratti, L. G. (1982). “Derivation of an empirical rate equation by analysis of experimental data.” Water Res., 16(6), 829–837.
13.
Hiester, N. K., and Vermeulen, T. (1952). “Saturation performance of ion‐exchange and adsorption columns.” Chemical Engrg., Progress, 48(10), 505–516.
14.
Joyce, R. S., and Sukenik, V. A. (1964). “Feasibility of granular, activated‐carbon adsorption for waste‐water renovation.” Report, Division of Water Supply and Pollution Control, Cincinnati, Ohio.
15.
Keinath, T. M., and Weber, W. J. (1968). “A predictive model for the design of fixed bed adsorbers.” J. Water Pollution Control Federation, 40(5), 751.
16.
Keinath, T. M. (1975). “Modeling and simulation of the performance of adsorption contactors.” Mathematical modeling for water pollution control processes, T. M. Keinath, and M. Wanielista, eds., Ann Arbor Science Publishers, Ann Arbor, Mich.
17.
Rifai, M.N.E., Kaufmann, W. J., and Todd, D. K. (1956). “Dispersion phenomenon in laminar flow through porous media.” Report No. 2, I.E.R. Series 90, Sanitary Engrg. Res. Lab. University of California, Berkeley, Calif.
18.
Snoeyink, V. L. (1990). “Adsorption of organic compounds.” Water quality and treatment, 4th Ed., F. W. Pontius, ed., McGraw‐Hill Book Co., Inc., New York, N.Y.
19.
Vagliasindi, F., and Hendricks, D. W. (1990). “Adsorption wave fronts and propositions for packed bed reactor design.” Report 90‐153141 (1), Colorado State University, Fort Collins, Colo.
20.
Weber, W. J., Jr., McGinley, P. M., and Katz, L. E. (1991). “Sorption phenomena in subsurface systems: Concepts, models, and effects on contaminant face and transport.” Water Res., 25(5), 499.
21.
Weber, W. J., Jr., and Smith, E. H. (1987). “Simulation and design models for adsorption process.” Envir. Sci. and Tech., 21(11), 1040–1060.
22.
Yao, K. M., Habibian, M. T., and O'Melia, C. R. (1971). “Water and waste water filtration: Concepts and applications.” Envir. Sci. and Tech., 5(11), 1105–1112.
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Copyright © 1992 ASCE.
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Published online: Jul 1, 1992
Published in print: Jul 1992
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