Diffusion Influence Mechanism of Virgin and Aged Asphalt Binder System Based on Molecular Dynamics
Publication: Journal of Transportation Engineering, Part B: Pavements
Volume 150, Issue 3
Abstract
During the production and transport of reclaimed asphalt pavement (RAP), the diffusion of recycled aged asphalt binder and virgin asphalt binder can significantly affect the mechanical properties of the virgin and aged asphalt binder system. Therefore, a thorough understanding of the diffusion behavior of virgin and aged asphalt binder system is essential for the production of RAP. In this study, a diffusion model of the virgin and aged asphalt binder system was established based on the Fick’s law to calculate the complex shear modulus () of the system. The calculated values were then compared with the measured values () obtained from the dynamic shear rheological (DSR) test. molecular dynamics (MD) simulations were also carried out to investigate the diffusion behavior of the virgin and aged asphalt binder system and to compare the simulated and calculated values of the diffusivity (D). The influence of different asphalt binder layers and saturates, aromatics, resins, and asphaltenes (SARA) on the diffusion behavior of the system was also analyzed. The results show that the values calculated by the diffusion model are in good correlation with the values measured by the DSR test at different temperatures and times. Furthermore, the diffusivity of virgin asphalt binder was found to be smaller than that of the four individual components, suggesting that the colloid structure and intermolecular interactions of asphalt binder play a crucial role in its diffusion behavior.
Practical Applications
Asphalt pavement is a common form of pavement, but it can be seen in life that asphalt pavement often has diseases such as cracks and potholes. The cause of some pavement diseases is the decrease of the performance of asphalt binder in the pavement. Under the action of natural factors, the phenomenon that the performance of asphalt binder gradually changes with time is called asphalt aging. Therefore, if the principle of asphalt aging can be mastered, the influencing factors of asphalt aging can be clarified, and a rejuvenator that can restore the performance of aged asphalt binder to the greatest extent can be designed. It can delay the aging rate of asphalt binder and improve the durability of asphalt pavement, conversely, it can also effectively recycle and renovate old asphalt pavement, reuse waste asphalt concrete, and reduce the waste of resources. This article mainly uses molecular dynamics simulation to achieve the preceding purpose. The result is helpful in providing guidance for the production of RAP in practical application.
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Data Availability Statement
All data, models, or code that support the findings of this study are available from the corresponding author upon reasonable request.
Acknowledgments
This work was supported by the Second Tibetan Plateau Scientific Expedition and Research Program (STEP) (Grant No. 2021QZKK0205), Natural Science Foundation of Heilongjiang Province (Grant No. YQ2021E032), and National Natural Science Foundation of China (Grant Nos. 52278447 and U20A20315).
References
Abdalfattah, I. A., W. S. Mogawer, and K. Stuart. 2021. “Quantification of the degree of blending in hot-mix asphalt (HMA) with reclaimed asphalt pavement (RAP) using Energy Dispersive X-Ray Spectroscopy (EDX) analysis.” J. Cleaner Prod. 294 (Apr): 126261. https://doi.org/10.1016/j.jclepro.2021.126261.
Bowers, B. F., B. Huang, and X. Shu. 2012. “New method for detecting asphalt contamination within fine aggregate medium through chemical testing.” J. Mater. Civ. Eng. 25 (2): 252–256. https://doi.org/10.1061/(ASCE)MT.1943-5533.0000594.
Cong, P., H. Hao, Y. Zhang, W. Luo, and D. Yao. 2016. “Investigation of diffusion of rejuvenator in aged asphalt.” Int. J. Pavement Res. Technol. 9 (4): 280–288. https://doi.org/10.1016/j.ijprt.2016.08.001.
Crank, J. 1979. The mathematics of diffusion. Oxford, UK: Oxford University Press.
Cui, W., W. Huang, Z. Xiao, J. Xie, B. Hu, X. Cai, and K. Wu. 2020. “The effect of moisture on the adhesion energy and nanostructure of asphalt-aggregate interface system using molecular dynamics simulation.” Molecules 25 (18): 4165. https://doi.org/10.3390/molecules25184165.
Debbarma, S., and G. Ransinchung. 2021. “Achieving sustainability in roller compacted concrete pavement mixes using reclaimed asphalt pavement aggregates–state of the art review.” J. Cleaner Prod. 287 (Mar): 125078. https://doi.org/10.1016/j.jclepro.2020.125078.
Ding, Y., B. Huang, X. Shu, Y. Zhang, and M. E. Woods. 2016. “Use of molecular dynamics to investigate diffusion between virgin and aged asphalt binders.” Fuel 174 (Jun): 267–273. https://doi.org/10.1016/j.fuel.2016.02.022.
Gao, J., J. Yang, D. Yu, Y. Jiang, K. Ruan, W. Tao, C. Sun, and L. Luo. 2021. “Reducing the variability of multi-source reclaimed asphalt pavement materials: A practice in China.” Constr. Build. Mater. 278 (Apr): 122389. https://doi.org/10.1016/j.conbuildmat.2021.122389.
Hou, X., S. Lv, Z. Chen, and F. Xiao. 2018. “Applications of Fourier transform infrared spectroscopy technologies on asphalt materials.” Measurement 121 (Jun): 304–316. https://doi.org/10.1016/j.measurement.2018.03.001.
Karlsson, R., and U. Isacsson. 2003. “Application of FTIR-ATR to characterization of bitumen rejuvenator diffusion.” J. Mater. Civ. Eng. 15 (2): 157–165. https://doi.org/10.1061/(ASCE)0899-1561(2003)15:2(157).
Kaseer, F., A. E. Martin, and E. Arámbula-Mercado. 2019. “Use of recycling agents in asphalt mixtures with high recycled materials contents in the United States: A literature review.” Constr. Build. Mater. 211 (Jun): 974–987. https://doi.org/10.1016/j.conbuildmat.2019.03.286.
Khosla, N. P., H. Nair, B. Visintine, and G. Malpass. 2012. “Effect of reclaimed asphalt and virgin binder on rheological properties of binder blends.” Int. J. Pavement Res. Technol. 5 (5): 317. https://doi.org/10.6135/ijprt.org.tw/2012.5(5).317.
Kriz, P., D. L. Grant, B. A. Veloza, M. J. Gale, A. G. Blahey, J. H. Brownie, R. D. Shirts, and S. Maccarrone. 2014. “Blending and diffusion of reclaimed asphalt pavement and virgin asphalt binders.” Supplement, Road Mater. Pavement Des. 15 (S1): 78–112. https://doi.org/10.1080/14680629.2014.927411.
Li, D. D., and M. L. Greenfield. 2014. “Chemical compositions of improved model asphalt systems for molecular simulations.” Fuel 115 (Jan): 347–356. https://doi.org/10.1016/j.fuel.2013.07.012.
Lu, X., B. Kalman, and P. Redelius. 2008. “A new test method for determination of wax content in crude oils, residues and bitumens.” Fuel 87 (8–9): 1543–1551. https://doi.org/10.1016/j.fuel.2007.08.019.
Ministry of Transport of the People’s Republic of China. 2011. Standard test methods of bitumen and bituminous mixtures for highway engineering—Code of China. JTG E20-2011. Beijing: China Communications Press.
Navaro, J., D. Bruneau, I. Drouadaine, J. Colin, A. Dony, and J. Cournet. 2012. “Observation and evaluation of the degree of blending of reclaimed asphalt concretes using microscopy image analysis.” Constr. Build. Mater. 37 (Dec): 135–143. https://doi.org/10.1016/j.conbuildmat.2012.07.048.
Oldenburg, T., H. Huang, P. Donohoe, H. Willsch, and S. Larter. 2004. “High molecular weight aromatic nitrogen and other novel hopanoid-related compounds in crude oils.” Org. Geochem. 35 (6): 665–678. https://doi.org/10.1016/j.orggeochem.2004.02.005.
Oreto, C., R. Veropalumbo, N. Viscione, S. A. Biancardo, and F. Russo. 2021. “Investigating the environmental impacts and engineering performance of road asphalt pavement mixtures made up of jet grouting waste and reclaimed asphalt pavement.” Environ. Res. 198 (Jul): 111277. https://doi.org/10.1016/j.envres.2021.111277.
Rad, F. Y., N. R. Sefidmazgi, and H. Bahia. 2014. “Application of diffusion mechanism: Degree of blending between fresh and recycled asphalt pavement binder in dynamic shear rheometer.” Transp. Res. Rec. 2444 (1): 71–77. https://doi.org/10.3141/2444-08.
Rafiq, W., M. A. Musarat, M. Altaf, M. Napiah, M. H. Sutanto, W. S. Alaloul, M. F. Javed, and A. Mosavi. 2021. “Life cycle cost analysis comparison of hot mix asphalt and reclaimed asphalt pavement: A case study.” Sustainability 13 (8): 4411. https://doi.org/10.3390/su13084411.
Rahman, M. A., M. Zaman, S. A. Ali, R. Ghabchi, and S. Ghos. 2022. “Evaluation of mix design volumetrics and cracking potential of foamed warm mix asphalt (WMA) containing Reclaimed Asphalt Pavement (RAP)” Int. J. Pavement Eng. 23 (10): 3454–3466. https://doi.org/10.1080/10298436.2021.1902522.
Soleymani, H. R., R. McDaniel, and M. Abdelrahman. 2000. “Investigation of the black rock issue for recycled asphalt mixtures.” In Vol. 69 of Proc., Association of Asphalt Paving Technologists Annual Meeting, 366–390. Lino Lakes, MN: Association of Asphalt Paving Technologists.
Spreadbury, C. J., K. A. Clavier, A. M. Lin, and T. G. Townsend. 2021. “A critical analysis of leaching and environmental risk assessment for reclaimed asphalt pavement management.” Sci. Total Environ. 775 (Jun): 145741. https://doi.org/10.1016/j.scitotenv.2021.145741.
Wu, J., Q. Liu, S. Yang, M. Oeser, and C. Ago. 2021. “Study of migration and diffusion during the mixing process of asphalt mixtures with RAP.” Road Mater. Pavement Des. 22 (7): 1578–1593. https://doi.org/10.1080/14680629.2019.1710237.
Xiao, Y., C. Li, M. Wan, X. Zhou, Y. Wang, and S. Wu. 2017. “Study of the diffusion of rejuvenators and its effect on aged bitumen binder.” Appl. Sci. 7 (4): 397. https://doi.org/10.3390/app7040397.
Xing, C., M. Li, L. Liu, R. Lu, N. Liu, W. Wu, and D. Yuan. 2023. “A comprehensive review on the blending condition between virgin and RAP asphalt binders in hot recycled asphalt mixtures: Mechanisms, evaluation methods, and influencing factors.” J. Cleaner Prod. 398 (Apr): 136515. https://doi.org/10.1016/j.jclepro.2023.136515.
Xu, G., H. Wang, and W. Sun. 2018a. “Molecular dynamics study of rejuvenator effect on RAP binder: Diffusion behavior and molecular structure.” Constr. Build. Mater. 158 (Jan): 1046–1054. https://doi.org/10.1016/j.conbuildmat.2017.09.192.
Xu, J., P. Hao, D. Zhang, and G. Yuan. 2018b. “Investigation of reclaimed asphalt pavement blending efficiency based on micro-mechanical properties of layered asphalt binders.” Constr. Build. Mater. 163 (Feb): 390–401. https://doi.org/10.1016/j.conbuildmat.2017.12.030.
Yang, C., J. Xie, S. Wu, S. Amirkhanian, Z. Wang, J. Song, X. Zhou, F. Wang, and L. Zhang. 2021. “Enhancement mechanism of induction heating on blending efficiency of RAP-virgin asphalt in steel slag recycled asphalt mixtures.” Constr. Build. Mater. 269 (Feb): 121318. https://doi.org/10.1016/j.conbuildmat.2020.121318.
Yu, C., K. Hu, Q. Yang, D. Wang, W. Zhang, G. Chen, and C. Kapyelata. 2021. “Analysis of the storage stability property of carbon nanotube/recycled polyethylene-modified asphalt using molecular dynamics simulations.” Polymers 13 (10): 1658. https://doi.org/10.3390/polym13101658.
Zhan, Y., H. Wu, W. Song, and L. Zhu. 2022. “Molecular dynamics study of the diffusion between virgin and aged asphalt binder.” Coatings 12 (3): 403. https://doi.org/10.3390/coatings12030403.
Zhang, L., Q. Zhou, P. Zhang, M. Cheng, and J. Yi. 2022. “Interaction mechanism between montmorillonite and asphalt based on molecular dynamics simulation.” Municipal Eng. Technol. 40 (10): 13–20. https://doi.org/10.19922/j.1009-7767.2022.10.013.
Zhao, S., B. Huang, X. Shu, and M. E. Woods. 2016. “Quantitative evaluation of blending and diffusion in high RAP and RAS mixtures.” Mater. Des. 89 (Jan): 1161–1170. https://doi.org/10.1016/j.matdes.2015.10.086.
Zhu, X., Z. Du, H. Ling, L. Chen, and Y. Wang. 2020. “Effect of filler on thermodynamic and mechanical behaviour of asphalt mastic: A MD simulation study.” Int. J. Pavement Eng. 21 (10): 1248–1262. https://doi.org/10.1080/10298436.2018.1535120.
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© 2024 American Society of Civil Engineers.
History
Received: May 5, 2023
Accepted: Jan 23, 2024
Published online: Apr 25, 2024
Published in print: Sep 1, 2024
Discussion open until: Sep 25, 2024
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