Thermoregulation Performance and Mechanical Properties of Phase Change Asphalt Mortars
Publication: Journal of Materials in Civil Engineering
Volume 36, Issue 8
Abstract
This study investigated the effects of a diatomite/tetradecane composite shaped phase change material (CSPCM) on the mechanical properties and thermoregulation performance of styrene-butadiene-styrene (SBS)- and styrene-butadiene-styrene/crumb rubber (SBS/CR)-modified asphalt binders. The heat transfer and latent heat characteristics of phase change asphalt mortars (PCAMs) were analyzed using a thermal constant analyzer and differential scanning calorimeter. Furthermore, a thermoregulation test was devised to confirm the temperature-regulating characteristics of PCAMs. The rheological properties of PCAMs were analyzed using the dynamic mechanical analysis (DMA) method, and low-temperature fracture characteristics were evaluated using the single edge notched beam (SENB) test. The results indicated that the incorporation of CSPCM decreased the thermal conductivity and thermal diffusivity of SBS- and SBS/CR-modified asphalt binders but increased their specific heat capacity. CSPCM can be stably present in modified asphalt and still have good phase change properties in the phase change temperature range, as well as the temperature regulation effect of PCAMs is excellent. The melting enthalpy for the PCAMs was as high as . Compared to the modified asphalts, the heating time of the PCAMs increased by up to 34.1% as the dosage of CSPCM gradually increased. The incorporation of CSPCM enhanced the viscous components of modified asphalt binders, improved intermediate-temperature fatigue resistance and low-temperature fracture resistance, and reduced high-temperature permanent deformation resistance.
Get full access to this article
View all available purchase options and get full access to this article.
Data Availability Statement
All data, models, and code generated or used during the study appear in the published article.
Acknowledgments
This work was supported by the National Second Qinghai-Tibet Scientific Expedition Special Project of China (Grant No. 2021QZKK0205), the National Natural Science Foundation of China (Grant Nos. 52278447 and U20A20315), and the Outstanding Youth Fund of Heilongjiang Province (Grant No. YQ2021E032). The authors gratefully acknowledge their financial support.
References
Anupam, B. R., U. C. Sahoo, and P. Rath. 2020. “Phase change materials for pavement applications: A review.” Constr. Build. Mater. 247 (Jun): 118553. https://doi.org/10.1016/j.conbuildmat.2020.118553.
Anupam, B. R., U. C. Sahoo, and P. Rath. 2023. “Effect of two organic phase change materials on the thermal performance of asphalt pavements.” Int. J. Pavement Eng. 24 (1): 2215900. https://doi.org/10.1080/10298436.2023.2215900.
ASTM. 2013. Standard test method for penetration of bituminous materials. ASTM D5/D5 M-13. West Conshohocken, PA: ASTM.
ASTM. 2014. Standard test method for softening point of bitumen (ring-and-ball apparatus). ASTM D36/D36 M-14el. West Conshohocken, PA: ASTM.
ASTM. 2017. Standard test method for ductility of asphalt materials. ASTM D113-17. West Conshohocken, PA: ASTM.
Bai, C., Y. Jiang, Y. Yi, K. Yuan, J. Fan, T. Tian, and Y. Tan. 2023. “Evaluation of spraying technique for heat-reflective coating on asphalt pavements.” Int. J. Pavement Eng. 24 (2): 2290076. https://doi.org/10.1080/10298436.2023.2290076.
Bueno, M., M. R. Kakar, Z. Refaa, J. Worlitschek, A. Stamatiou, and M. N. Partl. 2019. “Modification of asphalt mixtures for cold regions using microencapsulated phase change materials.” Sci. Rep. 9 (1): 20342. https://doi.org/10.1038/s41598-019-56808-x.
Dehdezi, P. K., M. R. Hall, A. R. Dawson, and S. P. Casey. 2013. “Thermal, mechanical and microstructural analysis of concrete containing microencapsulated phase change materials.” Int. J. Pavement Eng. 14 (5): 449–462. https://doi.org/10.1080/10298436.2012.716837.
Ding, B., X. Zou, Z. Peng, and X. Liu. 2018. “Evaluation of fracture resistance of asphalt mixtures using the single-edge notched beams.” Adv. Mater. Sci. Eng. 2018 (Apr): 8026798. https://doi.org/10.1155/2018/8026798.
Fan, J., Y. Jiang, Y. Yi, T. Tian, K. Yuan, and J. Xue. 2022. “Effects of load and environment on the durability and anti-skid performance of road heat-reflective coating.” Constr. Build. Mater. 346 (Sep): 128520. https://doi.org/10.1016/j.conbuildmat.2022.128520.
Farnam, Y., H. S. Esmaeeli, P. D. Zavattieri, J. Haddock, and J. Weiss. 2017. “Incorporating phase change materials in concrete pavement to melt snow and ice.” Cem. Concr. Compos. 84 (Nov): 134–145. https://doi.org/10.1016/j.cemconcomp.2017.09.002.
Huang, Z., J. Wei, Q. Fu, Y. Zhou, M. Lei, Z. Pan, and X. Zhang. 2023. “Preparation and experimental study of phase change materials for asphalt pavement.” Materials 16 (17): 6002. https://doi.org/10.3390/ma16176002.
Kakar, M. R., Z. Refaa, M. Bueno, J. Worlitschek, A. Stamatiou, and M. N. Partl. 2020. “Investigating bitumen’s direct interaction with tetradecane as potential phase change material for low temperature applications.” Road Mater. Pavement 21 (8): 2356–2363. https://doi.org/10.1080/14680629.2019.1601127.
Li, H., X. Zhang, L. Tian, M. Jia, N. Xie, Y. Han, and S. Qian. 2023. “Experimental investigation on performance of composite thermochromic and ice-melting coatings for dynamic pavement temperature control.” Constr. Build. Mater. 409 (Dec): 133787. https://doi.org/10.1016/j.conbuildmat.2023.133787.
Lushinga, N., L. Cao, and Z. Dong. 2019. “Effect of silicone oil on dispersion and low-temperature fracture performance of crumb rubber asphalt.” Adv. Mater. Sci. Eng. 2019 (Oct): 1–12. https://doi.org/10.1155/2019/8602562.
Ma, B., S. Adhikari, Y. Chang, J. Ren, J. Liu, and Z. You. 2013. “Preparation of composite shape-stabilized phase change materials for highway pavements.” Constr. Build. Mater. 42 (May): 114–121. https://doi.org/10.1016/j.conbuildmat.2012.12.027.
Ma, B., X. Zhou, J. Liu, Z. You, K. Wei, and X. Huang. 2016. “Determination of specific heat capacity on composite shape-stabilized phase change materials and asphalt mixtures by heat exchange system.” Materials 9 (5): 389. https://doi.org/10.3390/ma9050389.
Montoya, M. A., D. Betancourt, R. Rahbar-Rastegar, J. Youngblood, C. Martinez, and J. E. Haddock. 2022. “Environmentally tuning asphalt pavements using microencapsulated phase change materials.” Transp. Res. Rec. 2676 (5): 158–175. https://doi.org/10.1177/03611981211068366.
Montoya, M. A., R. Rahbar-Rastegar, and J. E. Haddock. 2023. “Incorporating phase change materials in asphalt pavements to melt snow and ice.” Int. J. Pavement Eng. 24 (2): 2041195. https://doi.org/10.1080/10298436.2022.2041195.
Pinheiro, C., et al. 2023. “Advancements in phase change materials in asphalt pavements for mitigation of urban heat island effect: Bibliometric analysis and systematic review.” Sensors 23 (18): 7741. https://doi.org/10.3390/s23187741.
Rahman, T., M. Irawan, A. Tajudin, M. Amrozi, and I. Widyatmoko. 2023. “Knowledge mapping of cool pavement technologies for urban heat island mitigation: A systematic bibliometric analysis.” Energy Build. 291 (Jul): 113133. https://doi.org/10.1016/j.enbuild.2023.113133.
Ryms, M., H. Denda, and P. Jaskula. 2017. “Thermal stabilization and permanent deformation resistance of LWA/PCM-modified asphalt road surfaces.” Constr. Build. Mater. 142 (Jul): 328–341. https://doi.org/10.1016/j.conbuildmat.2017.03.050.
Shamsaei, M., A. Carter, and M. Vaillancourt. 2022. “A review on the heat transfer in asphalt pavements and urban heat island mitigation methods.” Constr. Build. Mater. 359 (Dec): 129350. https://doi.org/10.1016/j.conbuildmat.2022.129350.
Sharifi, N. P., S. Askarinejad, and K. C. Mahboub. 2022. “Fracture performance of a PCM-rich concrete pavement under thermal stresses.” Int. J. Pavement Eng. 23 (2): 221–230. https://doi.org/10.1080/10298436.2020.1738436.
Shi, C., Y. Wu, T. Wang, Y. Yu, H. Wang, and J. Yang. 2023. “Rheological properties and polymer phase structure characterization of SBS/CR composite modified asphalt (CMA) binders.” Mater. Struct. 56 (2): 33. https://doi.org/10.1617/s11527-023-02122-y.
Wang, H., Y. Huang, K. Jin, and Z. Zhou. 2022. “Properties and mechanism of SBS/crumb rubber composite high viscosity modified asphalt.” J. Cleaner Prod. 378 (Dec): 134534. https://doi.org/10.1016/j.jclepro.2022.134534.
Wang, H., G. Pan, L. He, and L. Zou. 2023a. “Effects of polyethylene glycol/porous silica form-stabilized phase change materials on the performance of asphalt binders.” Materials 16 (15): 5293. https://doi.org/10.3390/ma16155293.
Wang, X., B. Ma, S. Li, W. Si, K. Wei, H. Zhang, and W. Shi. 2023b. “Review on application of phase change materials in asphalt pavement.” J. Traffic. Transp. Eng. 10 (2): 185–229. https://doi.org/10.1016/j.jtte.2022.12.001.
Wei, K., B. Ma, and S. Y. Duan. 2019. “Preparation and properties of bitumen-modified polyurethane solid-solid phase change materials.” J. Mater. Civ. Eng. 31 (8): 04019139. https://doi.org/10.1061/(ASCE)MT.1943-5533.0002795.
Xing, C., B. Liu, H. D. Liu, L. Zhang, H. N. Xu, and Y. Q. Tan. Forthcoming. “Topological characterization and typical topologies of disruption aggregates in asphalt mixture.” J. Mater. Civil. Eng. https://doi.org/10.1061/JMCEE7/MTENG-17276.
Zhang, D., W. Bu, Q. Wang, P. Liu, Z. Shao, X. Liu, and Y. Zhou. 2023a. “A review of recent developments and challenges of using phase change materials for thermoregulation in asphalt pavements.” Constr. Build. Mater. 400 (Oct): 132669. https://doi.org/10.1016/j.conbuildmat.2023.132669.
Zhang, D., M. Chen, S. Wu, and P. Liu. 2021. “Effect of expanded graphite/polyethylene glycol composite phase change material (EP-CPCM) on thermal and pavement performance of asphalt mixture.” Constr. Build. Mater. 277 (Mar): 122270. https://doi.org/10.1016/j.conbuildmat.2021.122270.
Zhang, D., M. Chen, S. Wu, M. Riara, J. Wan, and Y. Li. 2019. “Thermal and rheological performance of asphalt binders modified with expanded graphite/polyethylene glycol composite phase change material (EP-CPCM).” Constr. Build. Mater. 194 (Jan): 83–91. https://doi.org/10.1016/j.conbuildmat.2018.11.011.
Zhang, J., Z. Dong, G. Sun, Y. Qi, X. Zhu, and Y. Li. 2023b. “Roles of phase change materials on the morphological, physical, rheological and temperature regulating performances of high-viscosity modified asphalt.” Sci. Total Environ. 875 (Jun): 162632. https://doi.org/10.1016/j.scitotenv.2023.162632.
Zhang, L., M. Shan, C. Xing, Y. Cui, P. Wang, and M. Liu. 2023c. “Mechanism of physical hardening on the fracture characteristics of polymer-modified asphalt binder.” Constr. Build. Mater. 409 (Dec): 134091. https://doi.org/10.1016/j.conbuildmat.2023.134091.
Zheng, W., Y. Yang, Y. Chen, Y. Yu, N. Hossiney, and G. Tebaldi. 2022. “Low temperature performance evaluation of asphalt binders and mastics based on relaxation characteristics.” Mater. Struct. 55 (7): 204. https://doi.org/10.1617/s11527-022-02039-y.
Zhou, J., X. Chen, G. Xu, and Q. Fu. 2019. “Evaluation of low temperature performance for SBS/CR compound modified asphalt binders based on fractional viscoelastic model.” Constr. Build. Mater. 214 (Jul): 326–336. https://doi.org/10.1016/j.conbuildmat.2019.04.064.
Information & Authors
Information
Published In
Copyright
© 2024 American Society of Civil Engineers.
History
Received: Sep 28, 2023
Accepted: Jan 23, 2024
Published online: May 23, 2024
Published in print: Aug 1, 2024
Discussion open until: Oct 23, 2024
ASCE Technical Topics:
- Binders (material)
- Building materials
- Composite materials
- Engineering fundamentals
- Engineering materials (by type)
- Engineering mechanics
- Material mechanics
- Material properties
- Materials engineering
- Measurement (by type)
- Mechanical properties
- Mortars
- Temperature (by type)
- Temperature effects
- Temperature measurement
- Thermal properties
- Thermodynamics
Authors
Metrics & Citations
Metrics
Citations
Download citation
If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download.