Technical Papers
May 23, 2024

The Effect of Chloride Content on Corrosion of Steel Fibers in Chloride-Contaminated Simulated Concrete Pore Solutions

Publication: Journal of Materials in Civil Engineering
Volume 36, Issue 8

Abstract

The chloride content is a critical factor influencing the corrosion of steel fibers in concrete. This study focused on the corrosion behaviors of steel fibers exposed to simulated concrete pore solutions with different chloride contents. The corrosion rates of the steel fibers were calculated based on the changes in the diameter and ultimate tensile load. The electrochemical parameters for the corrosion of the steel fibers were continuously monitored for 62 days. In addition, the surface micromorphologies of the corroded steel fibers were observed using scanning electron microscopy (SEM). The results showed that based on the change in the diameter, the corrosion rate of the steel fibers increased almost linearly when the NaCl content in the simulated solution increased from 2% to 5%. However, based on the variation of the ultimate tensile load, the corrosion ratio of the steel fibers increased linearly with the increase in the exposure time when the NaCl content was less than 3%, while it increased exponentially when the NaCl content exceeded 3%. According to the open circuit potential, Tafel polarization curves, and electrochemical impedance spectroscopy (EIS), the corrosion tendency and corrosion rates of the steel fibers exposed to the simulated solutions increased significantly when the NaCl content increased from 2% to 5%. Additionally, the corrosion damage on the surfaces of the steel fibers increased notably, and after 180 days of exposure to the simulated solution with 5% NaCl, the steel fiber was almost broken. These findings will help to understand the durability of SFRC in a chloride environment.

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Data Availability Statement

All data generated or used during this study appear in the published article.

Acknowledgments

The authors gratefully acknowledge the financial support of the National Natural Science Foundation of China (No. 52078468) and the Natural Science Foundation of Henan Province (No. 222300420080).

References

Aal, E., S. Wanees, and A. Haleem. 2009. “Environmental factors affecting the corrosion behavior of reinforcing steel III. Measurement of pitting corrosion currents of steel in Ca(OH)2 solutions under natural corrosion conditions.” Corros. Sci. 51 (8): 1611–1618. https://doi.org/10.1016/j.corsci.2009.04.006.
Abbas, S., and M. L. Nehdi. 2018. “Mechanical behavior of RC and SFRC precast tunnel lining segments under chloride ions exposure.” J. Mater. Civ. Eng. 30 (4): 04018047. https://doi.org/10.1061/(ASCE)MT.1943-5533.0002217.
Abbas, S., A. M. Soliman, and M. L. Nehdi. 2015. “Exploring mechanical and durability properties of ultra-high performance concrete incorporating various steel fiber lengths and dosages.” Constr. Build. Mater. 75 (Jan): 429–441. https://doi.org/10.1016/j.conbuildmat.2014.11.017.
Abbas, Y. M., L. A. Hussain, and M. I. Khan. 2021. “Constitutive compressive stress–strain behavior of hybrid steel-PVA high-performance fiber-reinforced concrete.” J. Mater. Civ. Eng. 34 (1): 04021401. https://doi.org/10.1061/(ASCE)MT.1943-5533.0004041.
Abbass, W., and M. I. Khan. 2022. “Experimental and numerical investigation of flexural behavior of hybrid fiber reinforced high strength incorporating binary and ternary blend of ultra fines.” Structures 42 (Aug): 53–64. https://doi.org/10.1016/j.istruc.2022.05.116.
Aisheh, Y. I. A., D. S. Atrushi, M. H. Akeed, S. Qaidi, and B. A. Tayeh. 2022. “Influence of steel fibers and microsilica on the mechanical properties of ultra-high-performance geopolymer concrete (UHP-GPC).” Case Stud. Constr. Mater. 17 (Dec): e01245. https://doi.org/10.1016/j.cscm.2022.e01245.
Angst, U., A. Rønnquist, B. Elsener, C. K. Larsen, and O. Vennesland. 2011. “Probabilistic considerations on the effect of specimen size on the critical chloride content in reinforced concrete.” Corros. Sci. 53 (1): 177–187. https://doi.org/10.1016/j.corsci.2010.09.017.
Angst, U., and O. Vennesland. 2009. “Critical chloride content in reinforced concrete: A review.” Cem. Concr. Res. 39 (12): 1122–1138. https://doi.org/10.1016/j.cemconres.2009.08.006.
Ann, K. Y., and H. W. Song. 2007. “Chloride threshold level for corrosion of steel in concrete.” Corros. Sci. 49 (11): 4113–4133. https://doi.org/10.1016/j.corsci.2007.05.007.
Balouch, S. U., J. P. Forth, and J. L. Granju. 2010. “Surface corrosion of steel fibre reinforced concrete.” Cem. Concr. Res. 40 (3): 410–414. https://doi.org/10.1016/j.cemconres.2009.10.001.
Beglarigale, A., and H. Yazici. 2017. “Electrochemical corrosion monitoring of steel fiber embedded in cement based composites.” Cem. Concr. Compos. 83 (Oct): 427–446. https://doi.org/10.1016/j.cemconcomp.2017.08.004.
Berrocal, C. G., K. Lundgren, and I. Lofgren. 2016. “Corrosion of steel bars embedded in fibre reinforced concrete under chloride attack: State of the art.” Cem. Concr. Res. 80 (Feb): 69–85. https://doi.org/10.1016/j.cemconres.2015.10.006.
Cao, K., G. Liu, H. Li, and Z. Huang. 2022. “Mechanical properties and microstructures of Steel-basalt hybrid fibers reinforced Cement-based composites exposed to high temperatures.” Constr. Build. Mater. 341 (Jul): 127730. https://doi.org/10.1016/j.conbuildmat.2022.127730.
Chang, H. 2017. “Chloride binding capacity of pastes influenced by carbonation under three conditions.” Cem. Concr. Compos. 84 (Nov): 1–9. https://doi.org/10.1016/j.cemconcomp.2017.08.011.
Chang, H., X. Wang, Y. Wang, S. Li, J. Wang, J. Liu, and P. Feng. 2022. “Influence of Low Vacuum Condition on Mechanical Performance and Microstructure of Hardened Cement Paste at Early Age.” Constr. Build. Mater. 346 (Sep): 128358. https://doi.org/10.1016/j.conbuildmat.2022.128358.
Duffó, G. S., and S. B. Farina. 2016. “Electrochemical behaviour of steel in mortar and in simulated pore solutions: Analogies and differences.” Cem. Concr. Res. 88 (Oct): 211–216. https://doi.org/10.1016/j.cemconres.2016.07.007.
Frazão, C., J. Barros, A. Camoes, A. C. Alves, and L. Rocha. 2016. “Corrosion effects on pullout behavior of hooked steel fibers in self-compacting concrete.” Cem. Concr. Res. 79 (Jan): 112–122. https://doi.org/10.1016/j.cemconres.2015.09.005.
Gao, D., Y. Tai, L. Yang, Z. Zhang, G. Liu, and P. You. 2022. “Corrosion of steel fibers in chloride-contaminated simulated concrete pore solutions.” J. Mater. Civ. Eng. 35 (2): 04022429. https://doi.org/10.1061/(ASCE)MT.1943-5533.0004591.
Granju, J. L., and S. U. Balouch. 2005. “Corrosion of steel fibre reinforced concrete from the cracks.” Cem. Concr. Res. 35 (3): 572–577. https://doi.org/10.1016/j.cemconres.2004.06.032.
Guo, L., B. Yang, B. Chen, and C. Ding. 2015. “Critical chloride ion concentration of steel fiber corrosion in simulated concrete pore solution.” J. Water Resour. Archit. Eng. 13 (6): 16–18.
Hou, D., T. Li, and P. Wang. 2018. “Molecular dynamics study on the structure and dynamics of nacl solution transport in the nanometer channel of CASH gel.” ACS Sustainable Chem. Eng. 6 (7): 9498–9509. https://doi.org/10.1021/acssuschemeng.8b02126.
Hu, X., and C. S. Poon. 2022. “Chloride-related steel corrosion initiation in cement paste prepared with the incorporation of blast-furnace slag.” Cem. Concr. Compos. 126 (Feb): 104349. https://doi.org/10.1016/j.cemconcomp.2021.104349.
Huang, J., Y. Zhou, X. Yang, Y. Dong, M. Jin, and J. Liu. 2022. “A multi-scale study of enhancing mechanical property in ultra-high performance concrete by steel-fiber@Nano-silica.” Constr. Build. Mater. 342 (Part B): 128069. https://doi.org/10.1016/j.conbuildmat.2022.128069.
Hwang, J. P., M. S. Jung, M. Kim, and K. Y. Ann. 2015. “Corrosion risk of steel fibre in concrete.” Constr. Build. Mater. 101 (Part 1): 239–245. https://doi.org/10.1016/j.conbuildmat.2015.10.072.
Jang, Y. S., and D. Y. Yoo. 2022. “Combined chelating and corrosion effects of steel fiber on the interfacial bond and tensile behaviors of ultra-high-performance concrete.” Cem. Concr. Compos. 129 (May): 104505. https://doi.org/10.1016/j.cemconcomp.2022.104505.
Karahan, O., E. Ozbay, C. D. Atis, M. Lachemi, and K. M. A. Hossain. 2016. “Effects of milled cut steel fibers on the properties of concrete.” KSCE J. Civ. Eng. 20 (7): 2783–2789. https://doi.org/10.1007/s12205-016-0577-3.
Khan, M. I., G. Fares, and Y. M. Abbas. 2021a. “Behavior of non-shear-strengthened UHPC beams under flexural loading: Influence of reinforcement depth.” Appl. Sci. 11 (23): 11168. https://doi.org/10.3390/app112311168.
Khan, M. I., G. Fares, Y. M. Abbas, and F. K. Alqahtani. 2021b. “Behavior of non-shear-strengthened UHPC beams under flexural loading: Influence of reinforcement percentage.” Appl. Sci. 11 (23): 11346. https://doi.org/10.3390/app112311346.
Kosa, K., and A. E. Naaman. 1990. “Corrosion of steel fiber reinforced concrete.” ACI Mater. J. 87 (1): 27–37. https://doi.org/10.14359/2337.
Leporace-Guimil, B., A. Conforti, R. Zerbino, and G. A. Plizzari. 2021. “Chloride-induced corrosion in reinforced concrete and fiber reinforced concrete elements under tensile service loads.” Cem. Concr. Compos. 124 (Nov): 104245. https://doi.org/10.1016/j.cemconcomp.2021.104245.
Li, D., R. Wei, L. Li, X. Guan, and X. Mi. 2019. “Pitting corrosion of reinforcing steel bars in chloride contaminated concrete.” Constr. Build. Mater. 199 (Feb): 359–368. https://doi.org/10.1016/j.conbuildmat.2018.12.003.
Liu, G., Y. Zhang, Z. Ni, and R. Huang. 2016. “Corrosion behavior of steel submitted to chloride and sulphate ions in simulated concrete pore solution.” Constr. Build. Mater. 115 (Jul): 1–5. https://doi.org/10.1016/j.conbuildmat.2016.03.213.
Liu, G., Y. Zhang, M. Wu, and R. Huang. 2017. “Study of depassivation of carbon steel in simulated concrete pore solution using different equivalent circuits.” Constr. Build. Mater. 157 (Dec): 357–362. https://doi.org/10.1016/j.conbuildmat.2017.09.104.
Liu, Q. F., Z. Hu, X. E. Wang, H. Zhao, K. Qian, L. J. Li, and Z. Meng. 2022. “Numerical study on cracking and its effect on chloride transport in concrete subjected to external load.” Constr. Build. Mater. 325 (Mar): 126797. https://doi.org/10.1016/j.conbuildmat.2022.126797.
Liu, Z., R. Qian, S. Gao, Y. Wang, J. Jiang, and Y. Zhang. 2023. “Modelling of damage spatiotemporal distribution in saturated cementitious materials and its chloride transport evolution.” J. Adv. Concr. Technol. 21 (4): 248–261. https://doi.org/10.3151/jact.21.248.
Meng, Z., Q. F. Liu, J. Xia, Y. Cai, X. Zhu, Y. Zhou, and L. Pel. 2022. ““Mechanical-transport-chemical modelling of electrochemical repair methods for corrosion-induced cracking in marine concrete.” Comput.-Aided Civ. Infrastruct. Eng. 37 (14): 1854–1874. https://doi.org/10.1111/mice.12827.
Ming, M., S. Zheng, Y. Zhang, Y. Zheng, S. Yang, and M. Song. 2021. “Experimental study on the bond-slip behavior and stress transfer mechanism between shaped steel and high-performance fiber-reinforced concrete.” Structures 34 (Dec): 5013–5028. https://doi.org/10.1016/j.istruc.2021.09.014.
Mundra, S., M. Criado, S. A. Bernal, and J. L. Provis. 2017. “Chloride-induced corrosion of steel rebars in simulated pore solutions of alkali-activated concretes.” Cem. Concr. Res. 100 (Oct): 385–397. https://doi.org/10.1016/j.cemconres.2017.08.006.
Ngo, T. T., N. T. Tran, D. J. Kim, and T. C. Pham. 2021. “Effects of corrosion level and inhibitor on pullout behavior of deformed steel fiber embedded in high performance concrete.” Constr. Build. Mater. 280 (Apr): 122449. https://doi.org/10.1016/j.conbuildmat.2021.122449.
Nguyen, W., J. F. Duncan, T. M. Devine, and C. P. Ostertag. 2018a. “Electrochemical polarization and impedance of reinforced concrete and hybrid fiber-reinforced concrete under cracked matrix conditions.” Electrochem. Acta 271 (May): 319–336. https://doi.org/10.1016/j.electacta.2018.03.134.
Nguyen, W., J. F. Duncan, G. Jen, and C. P. Ostertag. 2018b. “Influence of matrix cracking and hybrid fiber reinforcement on the corrosion initiation and propagation behaviors of reinforced concrete.” Corros. Sci. 140 (Aug): 168–181. https://doi.org/10.1016/j.corsci.2018.06.004.
Pyo, S., T. Koh, M. Tafesse, and H. K. Kim. 2019. “Chloride-induced corrosion of steel fiber near the surface of ultra-high performance concrete and its effect on flexural behavior with various thickness.” Constr. Build. Mater. 224 (Nov): 206–213. https://doi.org/10.1016/j.conbuildmat.2019.07.063.
Pyo, S., M. Tafesse, H. Kim, and H. K. Kim. 2017. “Effect of chloride content on mechanical properties of ultra high performance concrete.” Cem. Concr. Res. 84 (Nov): 175–187. https://doi.org/10.1016/j.cemconcomp.2017.09.006.
Raupach M., C. Dauberschmidt, and T. Eichler. 2004. “Corrosion behaviour of steel fibres in concrete containing chlorides.” In Proc., EUROCORR 2004-European Corrosion Conf. Bruxelles, Belgium: European Federation of Corrosion.
Sato, N. 1990. “An overview on the passivity of metals.” Corros. Sci. 31: 1–19. https://doi.org/10.1016/0010-938X(90)90086-K.
Shagn, S., A. Bautista, J. Donaire, M. Torres-Carrasco, D. M. Bastidas, and F. Velasco. 2022. “Chloride-induced corrosion of steel reinforcement in mortars manufactured with alternative environmentally-friendly binders.” Cem. Concr. Compos. 130 (Jul): 104557. https://doi.org/10.1016/j.cemconcomp.2022.104557.
Shi, J., J. Ming, Y. Zhang, and J. Jiang. 2018. “Corrosion products and corrosion-induced cracks of low-alloy steel and low-carbon steel in concrete.” Cem. Concr. Compos. 88 (Apr): 121–129. https://doi.org/10.1016/j.cemconcomp.2018.02.002.
Song, G. 2000. “Theoretical analysis of the measurement of polarisation resistance in reinforced concrete.” Cem. Concr. Compos. 22 (6): 407–415. https://doi.org/10.1016/S0958-9465(00)00040-8.
Tang, K. 2019. “Stray alternating current (AC) induced corrosion of steel fibre reinforced concrete.” Corros. Sci. 152 (May): 153–171. https://doi.org/10.1016/j.corsci.2019.02.006.
Tran, N. T., S. Pyo, and D. J. Kim. 2015. “Corrosion resistance of strain-hardening steel-fiber-reinforced cementitious composites.” Cem. Concr. Compos. 63 (Oct): 17–29. https://doi.org/10.1016/j.cemconcomp.2015.07.006.
Vincler, J. P., T. Sanchez, V. Turgeon, D. Conciatori, and L. Sorelli. 2019. “A modified accelerated chloride migration tests for UHPC and UHPFRC with PVA and steel fibers.” Cem. Concr. Res. 117 (Mar): 38–44. https://doi.org/10.1016/j.cemconres.2018.12.006.
Wei, A., M. Tan, Y. C. Koay, X. Hu, and R. Al-Ameri. 2021. “Effect of carbon fiber waste on steel corrosion of reinforced concrete structures exposed to the marine environment.” J. Cleaner Prod. 316 (Sep): 128356. https://doi.org/10.1016/j.jclepro.2021.128356.
Wei, J., R. Chen, W. Huang, X. Bian, and B. Chen. 2022. “Effect of endogenous chloride ion content and mineral admixtures on the passivation behavior of reinforcement embedded in sea-sand ultra-high performance concrete matrix.” Constr. Build. Mater. 321 (Feb): 126402. https://doi.org/10.1016/j.conbuildmat.2022.126402.
Wen, C., Y. Tian, Z. Mai, J. Hu, and G. Wang. 2022. “Effect of macropores at the steel-concrete interface on localized corrosion behaviour of steel reinforcement.” Cem. Concr. Compos. 129 (May): 104510. https://doi.org/10.1016/j.cemconcomp.2022.104510.
Yang, L., Z. Zhang, D. Gao, J. Tang, H. Chang, and G. Liu. 2022. “Mechanical property evolution and chloride transport of steel fiber-reinforced concrete exposed to simulated marine environments.” Mater. Struct. 55 (4): 130. https://doi.org/10.1617/s11527-021-01806-7.
Yoo, D. Y., J. Y. Gim, and B. Chun. 2020. “Effects of rust layer and corrosion degree on the pullout behavior of steel fibers from ultra-high-performance concrete.” J. Mater. Res. Technol. 9 (3): 3632–3648. https://doi.org/10.1016/j.jmrt.2020.01.101.

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Go to Journal of Materials in Civil Engineering
Journal of Materials in Civil Engineering
Volume 36Issue 8August 2024

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Received: Aug 10, 2023
Accepted: Jan 23, 2024
Published online: May 23, 2024
Published in print: Aug 1, 2024
Discussion open until: Oct 23, 2024

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Professor, School of Water Conservancy and Transportation, Zhengzhou Univ., Zhengzhou 450001, China. ORCID: https://orcid.org/0000-0002-6910-2596. Email: [email protected]
Yangyang Tai [email protected]
Ph.D. Student, School of Water Conservancy and Transportation, Zhengzhou Univ., Zhengzhou 450001, China. Email: [email protected]
Danying Gao [email protected]
Professor, School of Water Conservancy and Transportation, Zhengzhou Univ., Zhengzhou 450001, China (corresponding author). Email: [email protected]
Zhenqing Zhang [email protected]
Ph.D. Student, School of Civil Engineering, Central South Univ., Changsha 410075, Hunan, China. Email: [email protected]
Xiaoting Fu [email protected]
School of Chemical Engineering, Zhengzhou Univ., Zhengzhou 450001, China. Email: [email protected]
Lecturer, Henan Key Laboratory of Intelligent Manufacturing of Mechanical Equipment, Zhengzhou Univ. of Light Industry, Zhengzhou 450002, China. Email: [email protected]
Professor, School of Materials Science and Engineering, Shijiazhuang Tiedao Univ., Shijiazhuang 050043, China. Email: [email protected]

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