Investigating the Interaction of Limestone Calcined Clay and OPC-Based Systems with a Methyl Hydroxyethyl Cellulose-Based Viscosity Modifier Used for 3D Printable Concrete
Publication: Journal of Materials in Civil Engineering
Volume 36, Issue 10
Abstract
Cellulose-ether-based viscosity-modifying admixtures (VMAs), such as methyl hydroxyethyl cellulose (MHEC), are commonly used for improving the printability of 3D printed concrete. For ordinary portland cement (OPC)–based systems, it is established that MHEC prolongs the dormant period and reduces the rate of calcium silicate hydrate (C─ S─ H) precipitation while reducing the early and later age strength. However, such an investigation is absent for limestone calcined clay (LC2)–based systems. The LC2-based 3D printable mixes are reported to require a smaller amount of VMA for improving the extrudability and buildability. The study aims to understand the interaction of MHEC with the binder system containing OPC and LC2. MHEC increases the water retention capacity of the mix while absorbing water and forming leaflike structures at lower dosages and wool-ball-like structures at higher dosages. Moreover, for a 45% LC2 content in binder, the hydration kinetics is not affected by 0.03% dosage, but an alteration of phase composition of carboaluminates is observed. For higher dosages of 0.06%, the hydration kinetics as well as phase composition are affected. In contrast, the connected porosity and pore size distribution measured as an indication of microstructure, using mercury intrusion porosimetry, water porosity, and formation factor, remain unaffected by the addition of MHEC. The reduction in porosity due to the addition of MHEC may not be observed due to the deposition of the agglomerated MHECs as weak inclusions in the pores. The change in the replacement percentage of LC2 is observed to affect the hydration kinetics of OPC-MHEC systems. For 100% OPC, the MHEC increases the dormant time and reduces the rate of C─ S─ H precipitation. However, for higher LC2 content mixes, the dormant period and C─ S─ H precipitation rate are not influenced, but calcium aluminosulfate formation (second peak) is delayed due to a change in the dissolution mechanism. However, for all the replacement percentages of LC2, the compressive strength is reduced with the addition of MHEC.
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Data Availability Statement
Some or all data, models, or code that support the findings of this study are available from the corresponding author upon reasonable request.
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Published In
Journal of Materials in Civil Engineering
Volume 36 • Issue 10 • October 2024
Copyright
© 2024 American Society of Civil Engineers.
History
Received: Sep 27, 2023
Accepted: Mar 19, 2024
Published online: Jul 30, 2024
Published in print: Oct 1, 2024
Discussion open until: Dec 30, 2024
ASCE Technical Topics:
- Clays
- Climates
- Continuum mechanics
- Dynamics (solid mechanics)
- Engineering materials (by type)
- Engineering mechanics
- Environmental engineering
- Fluid mechanics
- Geomechanics
- Geotechnical engineering
- Hydration
- Hydraulic engineering
- Hydrologic engineering
- Kinetics
- Laminating
- Limestone
- Material mechanics
- Material properties
- Materials engineering
- Materials processing
- Meteorology
- Porosity
- Precipitation
- Soil mechanics
- Soils (by type)
- Solid mechanics
- Stones
- Viscosity
- Water and water resources
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