Gamma Rays as Modifiers of the Compressive and Flexural Properties of Polyester Polymer Concrete
Publication: Journal of Materials in Civil Engineering
Volume 35, Issue 6
Abstract
To improve the mechanical and thermal properties of materials, alternative posttreatments have been proposed. One of these posttreatments is based on the use of ionizing radiation. This work studied the effects of gamma rays on the mechanical and thermal properties of polymer concrete (PC) produced with 80% silica sand and 20% polyester resin. High gamma irradiation doses (100–500 kGy) were used. Mechanical properties (compressive and flexural strength), and thermal properties (thermal conductivity, specific heat, and thermal diffusivity) were analyzed. The results show that the highest values of compressive and flexural strength and elasticity modulus occur when polymer concrete is irradiated at 400 kGy. The compressive strength of the reference concrete was 51 MPa; this resistance increased to 62 MPa (23% higher) when polymer concrete was irradiated at 400 kGy. The modulus of elasticity increased 12%, from 2.17 to 2.44 GPa, whereas the flexural strength increased from 16.2 to 17.7 MPa (9%). Changes in the thermal properties (mainly the specific heat) were obtained at 100 and 200 kGy doses. The results were related to the surface modifications produced in the irradiated polyester resin (analyzed by scanning electron microscopy) and its chemical structure (studied by Fourier-transform infrared and Raman spectroscopies).
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Data Availability Statement
All data, models, and code generated or used during the study appear in the published article.
References
Abdel-Hakim, A., E. H. Awad, K. F. El-Nemr, and T. M. El-Basheer. 2021. “Impact of gamma radiation and multi-walled carbon nanotubes on the mechanical and acoustical properties of reinforced sisal fiber/polyester resin composites.” Radiat. Phys. Chem. 189 (Dec): 109768. https://doi.org/10.1016/j.radphyschem.2021.109768.
Abdul Motaleb, K. Z. M., R. Milašius, and A. Ahad. 2020. “Influence of gamma radiation on mechanical properties of jute fabric-reinforced polymer composites.” Fibers 8 (9): 1–11. https://doi.org/10.3390/fib8090058.
Ajji, Z. 2005. “Preparation of polyester/gypsum/composite using gamma radiation, and its radiation stability.” Radiat. Phys. Chem. 73 (3): 183–187. https://doi.org/10.1016/j.radphyschem.2004.08.004.
Asdollah-Tabar, M., M. Heidari-Rarani, and M. R. M. Aliha. 2021. “The effect of recycled PET bottles on the fracture toughness of polymer concrete.” Compos. Commun. 25 (Jun): 100684. https://doi.org/10.1016/j.coco.2021.100684.
ASTM. 2016. Standard test method for measurement of thermal effusivity of fabrics using a modified transient plane source (MTPS) instrument. ASTM D7984-16. West Conshohocken, PA: ASTM.
ASTM. 2017. Standard test method for compressive strength of cylindrical concrete specimens. ASTM C39/C39M-01. West Conshohocken, PA: ASTM.
Ataabadi, H. S., A. Zare, H. Rahmani, A. Sedaghatdoost, and E. Mirzaei. 2021. “Lightweight dense polymer concrete exposed to chemical condition and various temperatures: An experimental investigation.” J. Build. Eng. 34 (Feb): 101878. https://doi.org/10.1016/j.jobe.2020.101878.
Baccaro, S., C. Casieri, A. Cemmi, M. Chiarini, V. D’Aiuto, and M. Tortora. 2017. “Characterization of -radiation induced polymerization in ethyl methacrylate and methyl acrylate monomers solutions.” Radiat. Phys. Chem. 141 (Dec): 131–137. https://doi.org/10.1016/j.radphyschem.2017.06.017.
Chen, R. S., M. H. Ab Ghani, S. Ahmad, M. A. Tarawneh, and S. Gan. 2021. “Tensile, thermal degradation and water diffusion behaviour of gamma-radiation induced recycled polymer blend/rice husk composites: Experimental and statistical analysis.” Compos. Sci. Technol. 207 (May): 108748. https://doi.org/10.1016/j.compscitech.2021.108748.
Ferry, M., and Y. Ngono. 2021. “Energy transfer in polymers submitted to ionizing radiation: A review.” Radiat. Phys. Chem. 180 (Mar): 109320. https://doi.org/10.1016/j.radphyschem.2020.109320.
Gagandeep. 2021. “Experimental study on strength characteristics of polymer concrete with epoxy resin.” Mater. Today: Proc. 37 (2): 2886–2889. https://doi.org/10.1016/j.matpr.2020.08.665.
Gao, Y., P. Romero, H. Zhang, M. Huang, and F. Lai. 2019. “Unsaturated polyester resin concrete: A review.” Constr. Build. Mater. 228 (Dec): 116709. https://doi.org/10.1016/j.conbuildmat.2019.116709.
Hammodat, W. W. 2021. “Investigate road performance using polymer modified concrete.” Mater. Today: Proc. 42 (Jan): 2089–2094. https://doi.org/10.1016/j.matpr.2020.12.290.
Jurkin, T., and I. Pucić. 2006. “Post-irradiation crosslinking of partially cured unsaturated polyester resin.” Radiat. Phys. Chem. 75 (9): 1060–1068. https://doi.org/10.1016/j.radphyschem.2006.04.001.
Khattab, M. M. 2014. “Effect of gamma irradiation on polymer modified white sand cement mortar composites.” J. Ind. Eng. Chem. 20 (1): 1–8. https://doi.org/10.1016/j.jiec.2013.04.001.
Kiruthika, C., S. Lavanya Prabha, and M. Neelamegam. 2021. “Different aspects of polyester polymer concrete for sustainable construction.” Mater. Today: Proc. 43 (Jan): 1622–1625. https://doi.org/10.1016/j.matpr.2020.09.766.
Liu, B., J. Shi, M. Sun, Z. He, H. Xu, and J. Tan. 2020. “Mechanical and permeability properties of polymer-modified concrete using hydrophobic agent.” J. Build. Eng. 31 (Sep): 101337. https://doi.org/10.1016/j.jobe.2020.101337.
Martínez-López, M., G. Martínez-Barrera, C. Barrera-Díaz, F. Ureña-Núñez, and J. M. Laredo dos Reis. 2016. “Waste Tetra Pak particles from beverage containers as reinforcements in polymer mortar: Effect of gamma irradiation as an interfacial coupling factor.” Constr. Build. Mater. 121 (Sep): 1–8. https://doi.org/10.1016/j.conbuildmat.2016.05.153.
McKeen, L. W. 2020. “Effect of radiation on the properties of polyester polymers.” In Plastics design library, 93–128. Norwich, Nueva York: William Andrew. https://doi.org/10.1016/B978-0-12-819729-5.00004-9.
Oliveira da Silva, A., K. G. de Castro Monsores, S. S. A. Oliveira, R. Pondé Weber, S. Neves Monteiro, and H. de Carvalho Vital. 2020. “Influence of gamma and ultraviolet radiation on the mechanical behavior of a hybrid polyester composite reinforced with curaua mat and aramid fabric.” J. Mater. Sci. Technol. 9 (1): 394–403. https://doi.org/10.1016/j.jmrt.2019.10.068.
Rao, V. 2009. “Radiation processing of polymers.” In Advances in polymer processing, 402–437. Sawston, UK: Woodhead. https://doi.org/10.1533/9781845696429.3.402.
Singh, P., J. Ram, V. Chauhan, P. M. G. Nambissan, S. K. Gupta, S. Kumar, S. K. Sharma, P. D. Sahare, and R. Kumar. 2020. “High dose gamma radiation exposure upon Kapton-H polymer for modifications of optical, free volume, structural and chemical properties.” Optik 205 (Mar): 164244. https://doi.org/10.1016/j.ijleo.2020.164244.
Sosoi, G., M. Barbuta, A. A. Serbanoiu, D. Babor, and A. Burlacu. 2018. “Wastes as aggregate substitution in polymer concrete.” Procedia Manuf. 22 (Jan): 347–351. https://doi.org/10.1016/j.promfg.2018.03.052.
Szajerski, P., J. Celinska, A. Gasiorowski, R. Anyszka, R. Walendziak, and M. Lewandowski. 2020. “Radiation induced strength enhancement of sulfur polymer concrete composites based on waste and residue fillers.” J. Cleaner Prod. 271 (Oct): 122563. https://doi.org/10.1016/j.jclepro.2020.122563.
Tabatabaeian, M., A. Khaloo, and H. Khaloo. 2019. “An innovative high performance pervious concrete with polyester and epoxy resins.” Constr. Build. Mater. 228 (Dec): 116820. https://doi.org/10.1016/j.conbuildmat.2019.116820.
TC (Techincal Committee). 1995. Method of test for flexural strength and deflection of polymer-modified mortar. TC 113. Paris: RILEM.
Venkata Ramana, M., P. R. Thyla, N. Mahendrakumar, and K. Praveena. 2021. “Selection of resin and aggregates for particulate polymer concrete machine tool structures—A review.” Mater. Today: Proc. 46 (Jan): 8621–8628. https://doi.org/10.1016/j.matpr.2021.03.595.
Wunderlich, B. 2002. “Heat capacity of polymers.” In Vol. 3 of Handbook of Thermal Analysis and Calorimetry, 1–47. Amsterdam, Netherlands: Elsevier. https://doi.org/10.1016/S1573-4374(02)80004-8.
Yao, X., Z.-X. Guo, S. H. Basha, and Q. Huang. 2021. “Innovative seismic strengthening of historic masonry walls using polymer mortar and steel strips.” Eng. Struct. 228 (Feb): 111507. https://doi.org/10.1016/j.engstruct.2020.111507.
Zhang, X., M. Du, H. Fang, M. Shi, C. Zhang, and F. Wang. 2021. “Polymer-modified cement mortars: Their enhanced properties, applications, prospects, and challenges.” Constr. Build. Mater. 299 (Sep): 124290. https://doi.org/10.1016/j.conbuildmat.2021.124290.
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Published In
Journal of Materials in Civil Engineering
Volume 35 • Issue 6 • June 2023
Copyright
© 2023 American Society of Civil Engineers.
History
Received: May 17, 2022
Accepted: Oct 11, 2022
Published online: Mar 29, 2023
Published in print: Jun 1, 2023
Discussion open until: Aug 29, 2023
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