Study of the Properties of Waterborne Epoxy Resin Emulsified Asphalt and Its Modification Mechanism
Publication: Journal of Materials in Civil Engineering
Volume 35, Issue 6
Abstract
Waterborne epoxy resin (WER) emulsified asphalt (WEREA) has the advantages of high viscosity and strength of epoxy asphalt, as well as a simple construction process, so it is used widely in asphalt pavement maintenance and repair projects. This paper investigated the comprehensive properties, the microstructure, the modification mechanism, and the strength formation mechanism of WEREA. The results of bond strength tests, adhesion tests between emulsified asphalt and coarse aggregate, conventional performance tests, and multistress creep recovery (MSCR) tests showed that with the increase of WER content, the adhesive properties and creep recovery properties at high temperature of the WEREA gradually improved, and gradually became the properties of brittle materials. When the WER content was 15%, the irrecoverable creep compliance of the WEREA stabilized and it met heavy traffic demand. In addition, fluorescence microscopy (FM) and scanning electron microscopy (SEM) showed that WER changed from having an island structure to having an epoxy skeleton structure in the WEREA. The results of Fourier-transform infrared (FTIR) testing showed that during the modification of the emulsified asphalt by the WER, no new substances were generated, which indicated that the sample possessed the mechanism of intermolecular physical blending. The test results were used to analyze the strength formation process of WEREA, which provides theoretical guidance for other researchers to study WEREA.
Get full access to this article
View all available purchase options and get full access to this article.
Data Availability Statement
Some or all data, models, or code generated or used during the study are available from the corresponding author by request.
Acknowledgments
The work is supported by Chongqing Science and Technology Commission project (Grant No. cstc2019jcyj-msxmX0763) and the Construction Science and Technology Project of Ministry of Transport (Program No. 2014318346140). That sponsorship and interest are gratefully acknowledged.
References
AASHTO. 2007. Standard method of test for multiple stress creep recovery (MSCR) test of asphalt binder using a dynamic shear rheometer (DSR). AASHTO TP 70-07. Washington, DC: AASHTO.
Al-Khateeb, G. G., and K. Z. Ramadan. 2014. “Investigation of the effect of rubber on rheological properties of asphalt binders using superpave DSR.” KSCE J. Civ. Eng. 19 (1): 127–135. https://doi.org/10.1007/s12205-012-0629-2.
ASTM. 2014. Standard test method for softening point of bitumen (ring-and-ball apparatus). ASTM D36/D36M-14. West Conshohocken, PA: ASTM.
ASTM. 2017. Standard test method for ductility of asphalt materials. ASTM D113-17. West Conshohocken, PA: ASTM.
ASTM. 2020. Standard test method for penetration of bituminous materials. ASTM D5/D5M-20. West Conshohocken, PA: ASTM.
Bi, Y., R. Li, S. Han, J. Pei, and J. Zhang. 2020. “Development and performance evaluation of cold-patching materials uising waterborne epoxy-emulsified asphalt mixtures.” Materials 13 (5): 1224. https://doi.org/10.3390/ma13051224.
Cai, X., W. Huang, J. Liang, and K. Wu. 2020. “Study of pavement performance of thin-coat waterborne epoxy emulsified asphalt mixture.” Front. Mater. 7 (Apr): 00088. https://doi.org/10.3389/fmats.2020.00088.
Chen, Q., Y. Lu, C. Wang, B. Han, and H. Fu. 2020. “Effect of raw material composition on the working performance of waterborne epoxy resin for road.” Int. J. Pavement Eng. 23 (7): 2380–2391. https://doi.org/10.1080/10298436.2020.1856842.
D’Angelo, J., R. Kluttz, R. N. Dongre, K. Stephens, and L. Zanzotto. 2007. “Revision of the Superpave high temperature binder specification: The multiple stress creep recovery test.” Asphalt Paving Technol. Assoc. Asphalt Paving Technol.-Proc. Tech. Sess. 76 (Mar): 123–162.
DuBois, E., D. Y. Mehta, and A. Nolan. 2014. “Correlation between multiple stress creep recovery (MSCR) results and polymer modification of binder.” Constr. Build. Mater. 65 (Aug): 184–190. https://doi.org/10.1080/10298436.2021.1932878.
Fu, H., C. Wang, L. Niu, G. Yang, and L. Liu. 2021a. “Composition optimisation and performance evaluation of waterborne epoxy resin emulsified asphalt tack coat binder for pavement.” Int. J. Pavement Eng. 2021 (May): 1–11. https://doi.org/10.1080/10298436.2021.2005057.
Fu, H., C. Wang, G. Yu, Q. Chen, and L. Liu. 2021b. “Design optimization and performance evaluation of the open-graded friction course with small particle size aggregate.” Adv. Civ. Eng. 2021 (Feb): 1–11. https://doi.org/10.1155/2021/6668378.
Gu, Y., B. Tang, L. He, F. Yang, H. Wang, and J. Ling. 2019. “Compatibility of cured phase-inversion waterborne epoxy resin emulsified asphalt.” Constr. Build. Mater. 229 (Dec): 116942. https://doi.org/10.1016/j.conbuildmat.2019.116942.
Han, S., T. Yao, X. Han, H. Zhang, and X. Yang. 2020. “Performance evaluation of waterborne epoxy resin modified hydrophobic emulsified asphalt micro-surfacing mixture.” Constr. Build. Mater. 249 (Jul): 118835. https://doi.org/10.1016/j.conbuildmat.2020.118835.
Hu, C., R. Li, J. Zhao, Z. Leng, and W. Lin. 2020. “Performance of waterborne epoxy emulsion sand fog seal as a preventive pavement maintenance method: From laboratory to field.” Adv. Mater. Sci. Eng. 2020 (Sep): 1–9. https://doi.org/10.1155/2020/6425817.
Hu, C., J. Zhao, Z. Leng, M. N. Partl, and R. Li. 2019. “Laboratory evaluation of waterborne epoxy bitumen emulsion for pavement preventative maintenance application.” Constr. Build. Mater. 197 (Feb): 220–227. https://doi.org/10.1016/j.conbuildmat.2018.11.223.
Ji, J., H. Yao, W. Zheng, Z. Suo, Y. Xu, S. Han, S. Xu, and Z. You. 2020. “Preparation and properties of waterborne epoxy–modified emulsified asphalt binder (WEMEAB).” J. Test. Eval. 48 (4): 3172–3187. https://doi.org/10.1520/JTE20160572.
Joni, H. H. 2018. “Studying the effect of emulsified asphalt type on cold emulsified asphalt mixtures properties.” Mater. Sci. Eng. 433 (1): 012038. https://doi.org/10.1088/1757-899X/433/1/012038.
Li, R., Z. Leng, M. N. Partl, and C. Raab. 2021. “Characterization and modelling of creep and recovery behaviour of waterborne epoxy resin modified bitumen emulsion.” Mater. Struct. 54 (8): 1–12. https://doi.org/10.1617/s11527-020-01594-6.
Li, X., et al. 2020. “Preparation and performance of colored ultra-thin overlay for preventive maintenance.” Constr. Build. Mater. 249 (Jul): 118619. https://doi.org/10.1016/j.conbuildmat.2020.118619.
Liu, F., M. Zheng, X. Fan, H. Li, and F. Wang. 2021a. “Performance evaluation of waterborne epoxy resin-SBR compound modified emulsified asphalt micro-surfacing.” Constr. Build. Mater. 295 (Aug): 123588. https://doi.org/10.1016/j.conbuildmat.2021.123588.
Liu, F., M. Zheng, X. Fan, H. Li, F. Wang, and X. Lin. 2021b. “Properties and mechanism of waterborne epoxy resin-SBR composite modified emulsified asphalt.” Constr. Build. Mater. 274 (Mar): 122059. https://doi.org/10.1016/j.conbuildmat.2020.122059.
Liu, F., M. Zheng, X. Liu, X. Ding, F. Wang, and Q. Wang. 2021c. “Performance evaluation of waterborne epoxy resin-SBR composite modified emulsified asphalt fog seal.” Constr. Build. Mater. 301 (Sep): 124106. https://doi.org/10.1016/j.conbuildmat.2021.124106.
Liu, M., S. Han, J. Pan, and W. Ren. 2018. “Study on cohesion performance of waterborne epoxy resin emulsified asphalt as interlayer materials.” Constr. Build. Mater. 177 (Jul): 72–82. https://doi.org/10.1016/j.conbuildmat.2018.05.043.
Liu, M., S. Han, Z. Wang, W. Ren, and W. Li. 2019. “Performance evaluation of new waterborne epoxy resin modified emulsified asphalt micro-surfacing.” Constr. Build. Mater. 214 (Jul): 93–100. https://doi.org/10.1016/j.conbuildmat.2019.04.107.
Lu, Q., and J. Bors. 2015. “Alternate uses of epoxy asphalt on bridge decks and roadways.” Constr. Build. Mater. 78 (Mar): 18–25. https://doi.org/10.1016/j.conbuildmat.2014.12.125.
Luo, S., Q. Lu, and Z. Qian. 2015. “Performance evaluation of epoxy modified open-graded porous asphalt concrete.” Constr. Build. Mater. 76 (Feb): 97–102. https://doi.org/10.1016/j.conbuildmat.2014.11.057.
Pang, H., S. Zhao, Z. Wang, W. Zhang, S. Zhang, and J. Li. 2020. “Development of soy protein-based adhesive with high water resistance and bonding strength by waterborne epoxy crosslinking strategy.” Int. J. Adhes. Adhes. 100 (25): 102600. https://doi.org/10.1016/j.ijadhadh.2020.102600.
Shen, F., M. Zhao, J. Lu, and Q. Ding. 2015. “Research on microstructure structure formation mechanism of cement-emulsifying asphalt and waterborne epoxy cementing materials.” Appl. Mech. Mater. 713–715 (Jan): 2830–2833. https://doi.org/10.4028/www.scientific.net/AMM.713-715.2830.
Shirodkar, P., Y. Mehta, A. Nolan, K. Dahm, R. Dusseau, and L. McCarthy. 2012. “Characterization of creep and recovery curve of polymer modified binder.” Constr. Build. Mater. 34 (Sep): 504–511. https://doi.org/10.1016/j.conbuildmat.2012.02.018.
Tian, T., Y. Jiang, J. Fan, Y. Yi, and C. Deng. 2021. “Development and performance evaluation of a high-permeability and high-bonding fog-sealing adhesive material.” Materials 14 (13): 3599. https://doi.org/10.3390/ma14133599.
Wang, C., Z. Fan, C. Shu, and X. Han. 2020. “Preparation and performance of conductive tack coat on asphalt pavement.” Constr. Build. Mater. 251 (Aug): 118949. https://doi.org/10.1016/j.conbuildmat.2020.118949.
Xiang, Q., and F. Xiao. 2020. “Applications of epoxy materials in pavement engineering.” Constr. Build. Mater. 235 (Feb): 117529. https://doi.org/10.1016/j.conbuildmat.2019.117529.
Yang, G., C. Wang, H. Fu, Z. Yan, and W. Yin. 2019. “Waterborne epoxy resin-polyurethane-emulsified asphalt: Preparation and properties.” J. Mater. Civ. Eng. 31 (11): 04019265. https://doi.org/10.1061/(ASCE)MT.1943-5533.0002904.
Yang, G., C. Wang, P. Wen, and W. Yin. 2020. “Performance characteristics of cold-mixed porous friction course with composite-modified emulsified asphalt.” J. Mater. Civ. Eng. 32 (3): 04019372. https://doi.org/10.1061/(ASCE)MT.1943-5533.0003047.
Zhang, Q., Y. Xu, and Z. Wen. 2017. “Influence of water-borne epoxy resin content on performance of waterborne epoxy resin compound SBR modified emulsified asphalt for tack coat.” Constr. Build. Mater. 153 (Oct): 774–784. https://doi.org/10.1016/j.conbuildmat.2017.07.148.
Zhang, Y., W. Wu, H. Cao, L. Zhao, Y. Zhang, B. Liu, Y. Li, and D. Cao. 2020a. “Investigation and evaluation of the emulsified asphalt with waterborne epoxy resin.” Key Eng. Mater. 842 (May): 337–345. https://doi.org/10.4028/www.scientific.net/KEM.842.337.
Zhang, Z., J. Li, Z. Wang, S. Long, S. Jiang, and G. Liu. 2020b. “Preparation and performance characterization of a novel high-performance epoxy resin modified reactive liquid asphalt.” Constr. Build. Mater. 263 (Dec): 120113. https://doi.org/10.1016/j.conbuildmat.2020.120113.
Zhang, Z., S. Wang, and G. Lu. 2019. “Properties of new cold patch asphalt liquid and mixture modified with waterborne epoxy resin.” Int. J. Pavement Eng. 21 (13): 1606–1616. https://doi.org/10.1080/10298436.2018.1559314.
Information & Authors
Information
Published In
Copyright
© 2023 American Society of Civil Engineers.
History
Received: Apr 1, 2022
Accepted: Oct 20, 2022
Published online: Mar 31, 2023
Published in print: Jun 1, 2023
Discussion open until: Aug 31, 2023
Authors
Metrics & Citations
Metrics
Citations
Download citation
If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download.