Numerical Simulation of Low-Temperature Thermal Management of Lithium-Ion Batteries Based on Composite Phase Change Material
Publication: Journal of Energy Engineering
Volume 150, Issue 3
Abstract
Phase change materials (PCMs) have attracted greater attention in battery thermal management systems (BTMS) applications due to their compact structure and excellent thermal storage performance. This work developed a BTMS model based on composite phase change material (CPCM) for a cylindrical lithium-ion battery pack. The initial state of the CPCM was set as a liquid phase, and the insulating performance of the BTMS was investigated numerically, considering the CPCM solidifying from liquid phase to solid phase in a low-temperature environment. The numerical model was built, and calculations were performed using Ansys Fluent 19.2. The research results showed that a CPCM effectively can extend the time that the battery pack remains above 0°C by releasing a large amount of latent heat during the solidification process in a low-temperature environment. As the convective heat transfer coefficient increased, the insulation effect provided by CPCM to lithium-ion battery packs decreased, exacerbating the temperature inhomogeneity inside the low-temperature thermal management system. Increasing the thermal conductivity of the CPCM ensured that the maximum temperature difference of the battery pack during operation remained within a safe range. Finally, the simulation results indicated that adding different thicknesses of insulation materials at the periphery of the low-temperature thermal management system effectively can improve the insulation effect. However, it also is necessary to select the appropriate thickness of insulation materials in combination with the actual demand.
Practical Applications
This paper establishes a model based on CPCM for the low-temperature thermal management system of cylindrical lithium-ion batteries. The thermal insulation and temperature homogenization performance of the CPCM-based BTMS were analyzed under various conditions, including different ambient temperatures, convective heat transfer coefficients, and thermophysical properties of materials, as well as the addition of insulation layers, considering time-dependent variations. Based on this analysis, the physical requirements of CPCM and the package structure for BTMS under different operating conditions were determined. The simulation results demonstrate that the liquid-phase CPCM solidifies and releases the stored heat through latent heat to warm and insulate the battery when the discharging process is stopped at lower temperatures. This effectively extends the battery’s holding time in the high-temperature domain and above 0°C. As the external convective heat transfer coefficient increases, the effectiveness of CPCM in insulating the battery decreases, exacerbating the temperature nonuniformity within the low-temperature thermal management system. Increasing the thermal conductivity of the CPCM ensures that the maximum temperature difference during battery operation remains within safe limits. In addition, the results indicate that the insulation effect can be improved significantly by adding an appropriate thickness of insulation material to the periphery of the thermal management system, based on specific requirements. This study provides a valuable reference for the design and optimization of thermal management systems for batteries operating in a wide temperature range.
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Data Availability Statement
All data, models, and code generated or used during the study appear in the published paper.
Acknowledgments
This work was financially supported by Innovation Fund for Small and Medium-size Enterprises of Gansu Province (22CX3GA017).
References
An, Z., H. Chen, X. Du, T. Shi, and D. Zhang. 2022. “Preparation and performance analysis of form-stable composite phase change materials with different EG particle sizes and mass fractions for thermal energy storage.” ACS Omega 7 (38): 34436–34448. https://doi.org/10.1021/acsomega.2c04101.
An, Z., L. Jia, X. Li, and Y. Ding. 2017. “Experimental investigation on lithium-ion battery thermal management based on flow boiling in mini-channel.” Appl. Therm. Eng. 117 (May): 534–543. https://doi.org/10.1016/j.applthermaleng.2017.02.053.
Babu Sanker, S., and R. Baby. 2022. “Phase change material based thermal management of lithium ion batteries: A review on thermal performance of various thermal conductivity enhancers.” J. Storage Mater. 50 (Jun): 104606. https://doi.org/10.1016/j.est.2022.104606.
Bernardi, D., E. Pawlikowski, and J. Newman. 1985. “A general energy balance for battery systems.” Electrochem. Soc. 132 (1): 5–12. https://doi.org/10.1149/1.2113792.
Bose, P., and V. A. Amirtham. 2016. “A review on thermal conductivity enhancement of paraffinwax as latent heat energy storage material.” Renewable Sustainable Energy Rev. 65 (Nov): 81–100. https://doi.org/10.1016/j.rser.2016.06.071.
Chen, Y., F. Zhao, M. Ge, Z. Wang, and Z. Gao. 2020. “Numerical simulation of heat retention in a lithium battery using phase change materials.” [In Chinese.] J. Beijing Univ. Chem. Technol. 47 (6): 107–114. https://doi.org/10.13543/j.bhxbzr.2020.06.014.
Cheng, G., Z. Wang, X. Wang, and Y. He. 2022. “All-climate thermal management structure for batteries based on expanded graphite/polymer composite phase change material with a high thermal and electrical conductivity.” Appl. Energy 322 (Sep): 119509. https://doi.org/10.1016/j.apenergy.2022.119509.
Fan, Y., Y. Bao, C. Ling, Y. Chu, X. Tan, and S. Yang. 2019. “Experimental study on the thermal management performance of air cooling for high energy density cylindrical lithium-ion batteries.” Appl. Therm. Eng. 155 (Jun): 96–109. https://doi.org/10.1016/j.applthermaleng.2019.03.157.
Gao, H., M. Chen, J. Hong, Y. Song, and Y. Yan. 2021. “Investigation on battery thermal management based on phase change energy storage technology.” Heat Mass Transfer 2021 (May): 1–14. https://doi.org/10.1007/s00231-021-03061-6.
Huang, Q., X. Li, G. Zhang, J. Weng, Y. Wang, and J. Deng. 2022. “Innovative thermal management and thermal runaway suppression for battery module with flame retardant flexible composite phase change material.” J. Cleaner Prod. 330 (Jan): 129718. https://doi.org/10.1016/j.jclepro.2021.129718.
Huo, J. H., Z.-G. Peng, and Q. Feng. 2019. “Synthesis and properties of microencapsulated phase change material with a urea–formaldehyde resin shell and paraffin wax core.” J. Appl. Polym. Sci. 137 (16): 48578. https://doi.org/10.1002/app.48578.
Kim, J., J. Oh, and H. Lee. 2019. “Review on battery thermal management system for electric vehicles.” Appl. Therm. Eng. 149 (Feb): 192–212. https://doi.org/10.1016/j.applthermaleng.2018.12.020.
Kirad, K., and M. Chaudhari. 2021. “Design of cell spacing in lithium-ion battery module for improvement in cooling performance of the battery thermal management system.” J. Power Sources 481 (Jan): 229016. https://doi.org/10.1016/j.jpowsour.2020.229016.
Kizilel, R., R. Sabbah, J. R. Selman, and S. Al-Hallaj. 2009. “An alternative cooling system to enhance the safety of Li-ion battery packs.” J. Power Sources 194 (2): 1105–1112. https://doi.org/10.1016/j.jpowsour.2009.06.074.
Ling, Z., X. Wen, Z. Zhang, X. Fang, and T. Xu. 2016. “Warming-up effects of phase change materials on lithium-ion batteries operated at low temperatures.” Energy Technol. 4 (9): 1071–1076. https://doi.org/10.1002/ente.201600083.
Liu, H. X. W., Y. Y. Li, W. H. Shao, and F. X. He. 2022. “Decay mechanism and capacity prediction of lithium-ion batteries under low-temperature near-adiabatic condition.” Inorg. Chem. Commun. 137 (Mar): 109151. https://doi.org/10.1016/j.inoche.2021.109151.
Liu, J., Y. Fan, and Q. Xie. 2021. “Temperature mitigation effect of phase change material on overcharging lithium-ion batteries: An experimental study.” J. Therm. Anal. Calorim. 147 (8): 5153–5163. https://doi.org/10.1007/s10973-021-10875-3.
Liu, Z., H. Wang, C. Yang, and J. Zhao. 2020. “Simulation study of lithium-ion battery thermal management system based on a variable flow velocity method with liquid metal.” Appl. Therm. Eng. 179 (Oct): 115578. https://doi.org/10.1016/j.applthermaleng.2020.115578.
Luo, J., D. Zou, Y. Wang, S. Wang, and L. Huang. 2022. “Battery thermal management systems (BTMs) based on phase change material (PCM): A comprehensive review.” Chem. Eng. J. 430 (Feb): 132741. https://doi.org/10.1016/j.cej.2021.132741.
Pang, X., B. An, S. Zheng, and B. Wang. 2022. “Cathode materials of metal-ion batteries for low-temperature applications.” J. Alloys Compd. 912 (Aug): 165142. https://doi.org/10.1016/j.jallcom.2022.165142.
Rao, Z. H., S. F. Wang, and Y. L. Zhang. 2014. “Thermal management with phase change material for a power battery under cold temperatures.” Energy Sources Part A 36 (20): 2287–2295. https://doi.org/10.1080/15567036.2011.576411.
Sasmito, A. P., T. Shamim, and A. S. Mujumdar. 2013. “Passive thermal management for PEM fuel cell stack under cold weather condition using phase change materials (PCM).” Appl. Therm. Eng. 58 (Jun): 615–625. https://doi.org/10.1016/j.applthermaleng.2013.04.064.
Shi, T., Z. An, X. Du, and D. Zhang. 2023. “Performance analysis of an innovative PCM-Based internal cooling design for cylindrical lithium-ion battery considering compact structure and uniform temperature.” J. Energy Eng. 149 (3): 04023006. https://doi.org/10.1061/jleed9.Eyeng-4740.
Singh, L. K., A. K. Gupta, and A. K. Sharma. 2022. “Hybrid thermal management system for a lithium-ion battery module: Effect of cell arrangement, discharge rate, phase change material thickness and air velocity.” J. Storage Mater. 52 (Aug): 104907. https://doi.org/10.1016/j.est.2022.104907.
Singh, L. K., R. Kumar, A. K. Gupta, A. K. Sharma, and S. Panchal. 2023. “Computational study on hybrid air-PCM cooling inside lithium-ion battery packs with varying number of cells.” J. Storage Mater. 67 (Sep): 107649. https://doi.org/10.1016/j.est.2023.107649.
Tang, Z., R. Feng, P. Huang, Z. Bai, and Q. Wang. 2022. “Modeling analysis on the cooling efficiency of composite phase change material-heat pipe coupling system in battery pack.” J. Loss Prev. Process Ind. 78 (Aug): 104829. https://doi.org/10.1016/j.jlp.2022.104829.
Tian, D., W. Liu, S. Zhang, and Y. Liu. 2021. “Simulation of a set of lithium-ion batteries with composite phase change materials and heating films thermal management system at low temperature.” Therm. Sci. Eng. Appl. 13 (Apr): 011002. https://doi.org/10.1115/1.4046983.
Wang, Q., P. Ping, X. Zhao, G. Chu, J. Sun, and C. Chen. 2012. “Thermal runaway caused fire and explosion of lithium ion battery.” J. Power Sources 208 (Jun): 210–224. https://doi.org/10.1016/j.jpowsour.2012.02.038.
Wang, S., et al. 2023. “Numerical optimization for a phase change material based lithium-ion battery thermal management system.” Appl. Therm. Eng. 222 (Mar): 119839. https://doi.org/10.1016/j.applthermaleng.2022.119839.
Wang, Y., Z. Wang, H. Min, H. Li, and Q. Li. 2021. “Performance investigation of a passive battery thermal management system applied with phase change material.” J. Storage Mater. 35 (Mar): 102279. https://doi.org/10.1016/j.est.2021.102279.
Wu, W., W. Wu, and S. Wang. 2019. “Form-stable and thermally induced flexible composite phase change material for thermal energy storage and thermal management applications.” Appl. Energy 236 (Feb): 10–21. https://doi.org/10.1016/j.apenergy.2018.11.071.
Wu, W., Q. Yuan, and X. Xu. 2022. “Effect of battery thermal management system on temperature distribution and uniformity.” J. Energy Eng. 148 (5): 04022028. https://doi.org/10.1061/(asce)ey.1943-7897.0000852.
Xie, Y., H. Li, W. Li, Y. Zhang, M. Fowler, M. K. Tran, X. Zhang, B. Chen, and S. Deng. 2022. “Improving thermal performance of battery at high current rate by using embedded heat pipe system.” J. Storage Mater. 46 (Feb): 103809. https://doi.org/10.1016/j.est.2021.103809.
Xie, Y., J. Tang, S. Shi, Y. Xing, H. Wu, Z. Hu, and D. Wen. 2017. “Experimental and numerical investigation on integrated thermal management for lithium-ion battery pack with composite phase change materials.” Energy Convers. Manage. 154 (Dec): 562–575. https://doi.org/10.1016/j.enconman.2017.11.046.
Zhang, D., J. Sun, and Q. Wang. 2020a. “Effect of module structure on performance of phase change material based Li-ion battery thermal management system.” Energy Storage Sci. Technol. 9 (5): 1526–1538. https://doi.org/10.19799/j.cnki.2095-4239.2020.0124.
Zhang, D., C. Tan, T. Ou, S. Zhang, L. Li, and X. Ji. 2022a. “Constructing advanced electrode materials for low-temperature lithium-ion batteries: A review.” Energy Rep. 8 (Nov): 4525–4534. https://doi.org/10.1016/j.egyr.2022.03.130.
Zhang, G., Y. Sun, C. Wu, X. Yan, W. Zhao, and C. Peng. 2023. “Low-cost and highly thermally conductive lauric acid–paraffin–expanded graphite multifunctional composite phase change materials for quenching thermal runaway of lithium-ion battery.” Energy Rep. 9 (Dec): 2538–2547. https://doi.org/10.1016/j.egyr.2023.01.102.
Zhang, J., X. Li, G. Zhang, Y. Wang, J. Guo, Y. Wang, Q. Huang, C. Xiao, and Z. Zhong. 2020b. “Characterization and experimental investigation of aluminum nitride-based composite phase change materials for battery thermal management.” Energy Convers. Manage. 204 (Jan): 112319. https://doi.org/10.1016/j.enconman.2019.112319.
Zhang, Q. Z., Y. Zhao, and T. Liu. 2022b. “Effects of state of charge and battery layout on thermal runaway propagation in lithium-ion batteries.” [In Chinese.] Energy Storage Sci. Technol. 11 (8): 2519–2525. https://doi.org/10.19799/j.cnki.2095-4239.2022.0177.
Zhang, Z., T. Hu, Q. Sun, Y. Chen, Q. Yang, and Y. Li. 2020c. “The optimized based electrolytes for anode in lithium ion batteries with an excellent low temperature performance.” J. Power Sources 453 (Mar): 227908. https://doi.org/10.1016/j.jpowsour.2020.227908.
Zhou, H., F. Zhou, L. Xu, J. Kong, and Q. Yang. 2019. “Thermal performance of cylindrical Lithium-ion battery thermal management system based on air distribution pipe.” Int. J. Heat Mass Trans. 131 (Mar): 984–998. https://doi.org/10.1016/j.ijheatmasstransfer.2018.11.116.
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Published In
Journal of Energy Engineering
Volume 150 • Issue 3 • June 2024
Copyright
© 2024 American Society of Civil Engineers.
History
Received: Aug 6, 2023
Accepted: Jan 10, 2024
Published online: Apr 15, 2024
Published in print: Jun 1, 2024
Discussion open until: Sep 15, 2024
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