Hydraulic Performance of Alginate-Based Bentonite
Publication: Geo-Congress 2022
ABSTRACT
Bentonite clay is widely used as a hydraulic barrier in geosynthetic clay liners and cut-off walls. The interaction of the clay with divalent electrolytic solutions such as Ca2+ or Mg2+ deteriorates its sealing properties. The treatment of bentonite with polymers has improved its hydraulic properties; however, sustainability concerns have led to the discovery of an alternate polymer. Sodium alginate was used to prepare a new, more sustainable polymerized bentonite clay. The alginate was selected due to its recent laboratory extraction from wastewater. This paper presents the performance of the alginate polymer-based bentonite clay in terms of swelling and hydraulic conductivity. Overall, the preliminary results were optimistic towards the use of alginate in polymerized clay. In short, the clay has the potential to be used as an effective hydraulic barrier in the construction industry, which would promote sustainable development.
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REFERENCES
Aksu, I., Bazilevskaya, E., and Karpyn, Z. (2015). “Swelling of clay minerals in unconsolidated porous media and its impact on permeability.” GeoResJ, 7, 1–13.
Chen, J., Salihoglu, H., Benson, C. H., Likos, W. J., and Edil, T. B. (2019). “Hydraulic conductivity of bentonite–polymer composite geosynthetic clay liners permeated with coal combustion product leachates.” Journal of Geotechnical and Geoenvironmental Engineering, 145(9), 04019038.
De Camillis, M., Di Emidio, G., Bezuijen, A., Flores, D. V., Van Stappen, J., and Cnudde, V. (2017). “Effect of wet-dry cycles on polymer treated bentonite in seawater: swelling ability, hydraulic conductivity and crack analysis.” Applied Clay Science, 142, 52–59.
Di Emidio, G. (2010). Hydraulic and chemico-osmotic performance of polymer treated clays. Ghent University.
Di Emidio, G., Mazzieri, F., Verastegui-Flores, R.-D., Van Impe, W., and Bezuijen, A. (2015). “Polymer-treated bentonite clay for chemical-resistant geosynthetic clay liners.” Geosynthetics International, 22(1), 125–137.
Di Emidio, G., Van Impe, W., and Mazzieri, F. “A polymer enhanced clay for impermeable geosynthetic clay liners.” Proc., 6th International congress on Environmental Geotechnics (6ICEG), Tata McGraw Hill Education, 964–967.
Di Emidio, G., Verastegui-Flores, R. D., Mazzieri, F., and Dominijanni, A. (2017). “Modified clays for barriers: a review.” Innovative Infrastructure Solutions, 2(1), 1–13.
Foroughi, F., Rezvani Ghomi, E., Morshedi Dehaghi, F., Borayek, R., and Ramakrishna, S. (2021). “A review on the life cycle assessment of cellulose: From properties to the potential of making it a low carbon material.” Materials, 14(4), 714.
Gustitus, S. A., and Benson, C. H. (2021). “Flow-Swell Index as an Indicator of Chemical Compatibility of BentonitePolymer Composite Geosynthetic Clay Liners.” Geosynthetics Conference 2021.
Homayouni, A., Ehsani, M. R., Azizi, A., Yarmand, M. S., and Razavi, H. (2007). “Effect of lecithin and calcium chloride solution on the microencapsulation process yield of calcium alginate beads.”
Jlassi, K., Chehimi, M. M., and Thomas, S. (2017). Clay-polymer nanocomposites, Elsevier.
Katsumi, T., Ishimori, H., Onikata, M., and Fukagawa, R. (2008). “Long-term barrier performance of modified bentonite materials against sodium and calcium permeant solutions.” Geotextiles and Geomembranes, 26(1), 14–30.
Kolstad, D. C., Benson, C. H., and Edil, T. B. (2004). “Hydraulic conductivity and swell of nonprehydrated geosynthetic clay liners permeated with multispecies inorganic solutions.” Journal of Geotechnical and Geoenvironmental Engineering, 130(12), 1236–1249.
Li, Q., Chen, J., Benson, C. H., and Peng, D. (2021). “Hydraulic conductivity of bentonite-polymer composite geosynthetic clay liners permeated with bauxite liquor.” Geotextiles and Geomembranes, 49(2), 420–429.
Mazzieri, F., and Emidio, G. D. (2015). “Hydraulic conductivity of a dense prehydrated geosynthetic clay liner.” Geosynthetics International, 22(1), 138–148.
Mazzieri, F., and Pasqualini, E. “Effect of dry/wet cycles and cation exchange on the permeability of a dense prehydrated GCL.” Proc., Proceedings of the Fourth International Conference on Geosynthetics-Eurogeo4.
Mitchell, J. K., and Soga, K. (2005). Fundamentals of soil behavior, John Wiley & Sons New York.
Petrescu, L., Fermeglia, M., and Cormos, C.-C. (2016). “Life Cycle Analysis applied to acrylic acid production process with different fuels for steam generation.” Journal of Cleaner Production, 133, 294–303.
Qiu, H., and Yu, J. (2008). “Polyacrylate/(carboxymethylcellulose modified montmorillonite) superabsorbent nanocomposite: preparation and water absorbency.” J. Appl. Polym. Sci., 107(1), 118–123.
Scalia, J., IV, Benson, C. H., Bohnhoff, G. L., Edil, T. B., and Shackelford, C. D. (2014). “Long-term hydraulic conductivity of a bentonite-polymer composite permeated with aggressive inorganic solutions.” Journal of Geotechnical and Geoenvironmental Engineering, 140(3), 04013025.
Tian, K., Likos, W. J., and Benson, C. H. (2019). “Polymer elution and hydraulic conductivity of bentonite–polymer composite geosynthetic clay liners.” Journal of Geotechnical and Geoenvironmental Engineering, 145(10), 04019071.
TuDelft. (2016). “New factory to extract alginate-like raw material from waste water.” <tudelft.nl/en/2016/tnw/new-factory-to-extract-alginate-like-raw-material-from-waste-water/>.
Wang, H., Wei, J., and Simon, G. P. (2014). “Response to osmotic pressure versus swelling pressure: comment on “bifunctional polymer hydrogel layers as forward osmosis draw agents for continuous production of fresh water using solar energy”.” Environ. Sci. Technol., 48(7), 4214–4215.
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Published online: Mar 17, 2022
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