Chapter
May 12, 2022
Chapter 4

Mathematical Modeling of Electro-Coagulation Process

Publication: Electro-Coagulation and Electro-Oxidation in Water and Wastewater Treatment

Abstract

Several modeling techniques have recently evolved that can accurately simulate and predict the outcome of the electrocoagulation (EC) process. This chapter details some modeling techniques applied to EC processes using various computational tools. The modeling techniques used include artificial neural network (ANN), response surface methodology (RSM), adsorption-based models, and mathematical kinetic equation-based models. The distinct core concepts of these techniques are identified with respect to modeling EC processes; each one has been successfully applied to outcome prediction. Details are also provided on the various critical elements of ANN design.

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References

Aber, S., A. R. Amani-Ghadim, and V. Mirzajani. 2009. “Removal of Cr(VI) from polluted solutions by electrocoagulation: Modeling of experimental results using artificial neural network.” J. Hazard. Mater. 171 (1–3): 484–490.
Alinsafi, A., M. Khemis, M. N. Pons, J. P. Leclerc, A. Yaacoubi, A. Benhammou, et al. 2005. “Electro-coagulation of reactive textile dyes and textile wastewater.” Chem. Eng. Process. 44 (4): 461–470.
Amani-Ghadim, A. R., S. Aber, A. Olad, and H. Ashassi-Sorkhabi. 2013. “Optimization of electrocoagulation process for removal of an azo dye using response surface methodology and investigation on the occurrence of destructive side reactions.” Chem. Eng. Process. 64: 68–78.
Arulmurugan, A., C. Kumaran, T. Ramamurthy, and B. Subramanian. 2007. “Degradation of textile effluent by electro coagulation technique.” Bull. Electrochem. 23: 247–252.
Balasubramanian, N., T. Kojima, and C. Srinivasakannan. 2009. “Arsenic removal through electrocoagulation: Kinetic and statistical modeling.” Chem. Eng. J. 155 (1–2): 76–82.
Behbahani, M., M. R. A. Moghaddam, and M. Arami. 2011. “Techno-economical evaluation of fluoride removal by electrocoagulation process: Optimization through response surface methodology.” Desalination 271 (1–3): 209–218.
Behloul, M., H. Grib, N. Drouiche, N. Abdi, H. Lounici, and N. Mameri. 2013. “Removal of malathion pesticide from polluted solutions by electrocoagulation: Modeling of experimental results using response surface methodology.” Sep. Sci. Technol. 48 (4): 664–672.
Bezerra, M. A., R. E. Santelli, E. P. Oliveira, L. S. Villar, and L. A. Escaleira. 2008. “Response surface methodology (RSM) as a tool for optimization in analytical chemistry.” Talanta 76 (5): 965–977.
Bhatti, M. S., D. Kapoor, R. K. Kalia, A. S. Reddy, and A. K. Thukral. 2011a. “RSM and ANN modeling for electrocoagulation of copper from simulated wastewater: Multi objective optimization using genetic algorithm approach.” Desalination 274 (1–3): 74–80.
Bhatti, M. S., A. S. Reddy, R. K. Kalia, and A. K. Thukral. 2011b. “Modeling and optimization of voltage and treatment time for electrocoagulation removal of hexavalent chromium.” Desalination 269 (1–3): 157–162.
Bishop, C. M. 1995. Neural networks for pattern recognition. Oxford, UK: Oxford University Press.
Bushell, G., Y. Yan, D. Woodfield, J. Raper, and R. Amal. 2002. “On techniques for the measurement of the mass fractal dimension of aggregates.” Adv. Colloid Interface Sci. 95 (1): 1–50.
Butler, E., Y.-T. Hung, R. Y.-L. Yeh, and M. S. Al Ahmad. 2011. “Electrocoagulation in wastewater treatment.” Water 3 (4): 495–525.
Canizares, P., F. Martinez, M. Rodrigo, C. Jimenez, C. Saez, and J. Lobato. 2008a. “Modelling of wastewater electrocoagulation processes. Part I: General description and application to kaolin-polluted wastewaters.” Sep. Purif. Technol. 60 (2): 155–161.
Canizares, P., F. Martinez, M. Rodrigo, C. Jimenez, C. Saez, and J. Lobato. 2008b. “Modelling of wastewater electrocoagulation processes. Part II: Application to dye-polluted wastewaters and oil-in-water emulsions.” Sep. Purif. Technol. 60 (2): 147–154.
Cassettari, L., R. Mosca, R. Revetria, and F. Rolando. 2013. “Effectiveness and limits of response surface methodology in application to discrete and stochastic simulation of manufacturing plants.” Appl. Math. Sci. 7 (83): 4137–4172.
Chitra, K., and N. Balasubramanian. 2010. “Modeling electrocoagulation through adsorption kinetics.” J. Model. Simul. Syst. 1 (2): 124–130.
Chou, W. L., C. T. Wang, W. C. Chang, and S. Y. Chang. 2010. “Adsorption treatment of oxide chemical mechanical polishing wastewater from a semiconductor manufacturing plant by electrocoagulation.” J. Hazard. Mater. 180 (1–3): 217–224.
Curteanu, S., C. G. Piuleac, K. Godini, and G. Azaryan. 2011. “Modeling of electrolysis process in wastewater treatment using different types of neural networks.” Chem. Eng. J. 172 (1): 267–276.
Dalvand, A., M. Gholami, A. Joneidi, and N. M. Mahmoodi. 2011. “Dye removal, energy consumption and operating cost of electrocoagulation of textile wastewater as a clean process.” CLEAN—Soil, Air, Water 39 (7): 665–672.
Daneshvar, N., A. R. Khataee, and N. Djafarzadeh. 2006. “The use of artificial neural networks (ANN) for modeling of decolorization of textile dye solution containing C. I. Basic Yellow 28 by electrocoagulation process.” J. Hazard. Mater. 137 (3): 1788–1795.
Demuth, H., and M. Beale. 1993. Neural network toolbox for use with Matlab–User's guide version 3.0. Natick, MA: MathWorks.
Drouiche, N., S. Aoudj, H. Lounici, H. Mahmoudi, N. Ghaffour, and M. F. A. Goosen. 2012. “Development of an empirical model for fluoride removal from photovoltaic wastewater by electrocoagulation process.” Desalin. Water Treat. 29 (1–3): 96–102.
Elemen, S., E. P. Akçakoca Kumbasar, and S. Yapar. 2012. “Modeling the adsorption of textile dye on organoclay using an artificial neural network.” Dyes Pigm. 95 (1): 102–111.
Espinoza-Quinones, F. R., M. M. T. Fornari, A. N. Modenes, S. M. Palacio, D. E. Trigueros, F. H. Borba, et al. 2009. “Electrocoagulation efficiency of the tannery effluent treatment using aluminium electrodes.” Water Sci. Technol. 60 (8): 2173–2185.
Ferziger, J. H., and M. Peric. 2012. Computational methods for fluid dynamics. Berlin: Springer.
Forsyth, R. 1988. Machine learning: Principles and techniques. London: Chapman & Hall.
García-Lara, A. M., C. Montero-Ocampo, F. Equihua-Guillen, J. E. Camporredondo-Saucedo, R. Servin-Castaneda, and C. R. Muñiz-Valdes. 2014. “Arsenic removal from natural groundwater by electrocoagulation using response surface methodology.” J. Chem. 2014: 857625.
Garson, G. D. 1998. Neural networks: An introductory guide for social scientists. London: Sage.
Gengec, E., M. Kobya, E. Demirbas, A. Akyol, and K. Oktor. 2012. “Optimization of baker's yeast wastewater using response surface methodology by electrocoagulation.” Desalination 286: 200–209.
Güçlü, D. 2014. “Optimization of electrocoagulation of pistachio processing wastewaters using the response surface methodology.” Desalin. Water Treat. 54 (12): 3338–3347.
Hakizimana, J. N., B. Gourich, M. Chafi, Y. Stiriba, C. Vial, P. Drogui, et al. 2017. “Electrocoagulation process in water treatment: A review of electrocoagulation modeling approaches.” Desalination 404: 1–21.
Holt, P. K., G. W. Barton, and C. A. Mitchell. 2005. “The future for electrocoagulation as a localised water treatment technology.” Chemosphere 59 (3): 355–367.
Hu, C.-Y., S.-L. Lo, and W.-H. Kuan. 2007. “Simulation the kinetics of fluoride removal by electrocoagulation (EC) process using aluminum electrodes.” J. Hazard. Mater. 145 (1): 180–185.
Kabuk, H. A., F. İlhan, Y. Avsar, U. Kurt, O. Apaydin, and M. T. Gonullu. 2014. “Investigation of leachate treatment with electrocoagulation and optimization by response surface methodology.” CLEAN—Soil, Air, Water 42 (5): 571–577.
Karichappan, T., S. Venkatachalam, and P. M. Jeganathan. 2014. “Optimization of electrocoagulation process to treat grey wastewater in batch mode using response surface methodology.” J. Environ. Health Sci. Eng. 12 (1): 29.
Karichappan, T., S. Venkatachalam, P. M. Jeganathan, and K. Sengodan. 2013. “Treatment of rice mill wastewater using continuous electrocoagulation technique: Optimization and modelling.” J. Korean Chem. Soc. 57 (6): 761–768.
Khataee, A. R., and M. B. Kasiri. 2010. “Artificial neural networks modeling of contaminated water treatment processes by homogeneous and heterogeneous nanocatalysis.” J. Mol. Catal. A: Chem. 331 (1–2): 86–100.
Kobya, M., E. Demirbas, M. Bayramoglu, and M. T. Sensoy. 2010. “Optimization of electrocoagulation process for the treatment of metal cutting wastewaters with response surface methodology.” Water Air Soil Pollut. 215 (1–4): 399–410.
Kobya, M., E. Demirbas, U. Gebologlu, M. S. Oncel, and Y. Yildirim. 2013. “Optimization of arsenic removal from drinking water by electrocoagulation batch process using response surface methodology.” Desalin. Water Treat. 51 (34–36): 6676–6687.
Kobya, M., E. Gengec, M. T. Sensoy, and E. Demirbas. 2014. “Treatment of textile dyeing wastewater by electrocoagulation using Fe and Al electrodes: Optimisation of operating parameters using central composite design.” Color. Technol. 130 (3): 226–235.
Kuokkanen, V., T. Kuokkanen, J. Rämö, and U. Lassi. 2013. “Recent applications of electrocoagulation in treatment of water and wastewater—A review.” Green Sustainable Chem. 3 (2): 89–121.
Lacasa, E., P. Cañizares, C. Sáez, F. Martínez, and M. A. Rodrigo. 2013. “Modelling and cost evaluation of electro-coagulation processes for the removal of anions from water.” Sep. Purif. Technol. 107: 219–227.
Lakshmanan, D., D. A. Clifford, and G. Samanta. 2010. “Comparative study of arsenic removal by iron using electrocoagulation and chemical coagulation.” Water Res. 44 (19): 5641–5652.
Lakshmi, M., and P. Sivashanmugam. 2013. “Treatment of oil tanning effluent by electrocoagulation: Influence of ultrasound and hybrid electrode on COD removal.” Sep. Purif. Technol. 116: 378–384.
Li, L., C. M. van Genuchten, S. E. Addy, J. Yao, N. Gao, and A. J. Gadgil. 2012. “Modeling As(III) oxidation and removal with iron electrocoagulation in groundwater.” Environ. Sci. Technol. 46 (21): 12038–12045.
Lu, J., Z. Wang, X. Ma, Q. Tang, and Y. Li. 2017. “Modeling of the electrocoagulation process: A study on the mass transfer of electrolysis and hydrolysis products.” Chem. Eng. Sci. 165: 165–176.
Mameri, N., A. R. Yeddou, H. Lounici, D. Belhocine, H. Grib, and B. Bariou. 1998. “Defluoridation of septentrional Sahara water of North Africa by electrocoagulation process using bipolar aluminium electrodes.” Water Res. 32 (5): 1604–1612.
Mirsoleimani-Azizi, S. M., A. A. Amooey, S. Ghasemi, and S. Salkhordeh-Panbechouleh. 2015. “Modeling the removal of endosulfan from aqueous solution by electrocoagulation process using artificial neural network (ANN).” Ind. Eng. Chem. Res. 54 (40): 9844–9849.
Mollah, M. Y., P. Morkovsky, J. A. Gomes, M. Kesmez, J. Parga, and D. L. Cocke. 2004. “Fundamentals, present and future perspectives of electrocoagulation.” J. Hazard. Mater. 114 (1–3): 199–210.
Mollah, M. Y. A., R. Schennach, J. R. Parga, and D. L. Cocke. 2001. “Electrocoagulation(EC)-science and applications.” J. Hazard. Mater. 84 (1): 29–41.
Moulai-Mostefa, N., S. Ladjelat, H. Kermet-Said, M. Krea, and M. Tir. 2013. “Optimization of operational parameters in the pretreatment of surface water by electrocoagulation using a response surface method.” Desalin. Water Treat. 52 (13–15): 2382–2387.
Murugan, A. A., T. Ramamurthy, B. Subramanian, C. S. Kannan, and M. Ganesan. 2009. “Electrocoagulation of textile effluent: RSM and ANN modeling.” Int. J. Chem. Reactor Eng. 7 (1): A83.
Navarro, H., and L. Bennun. 2014. “Descriptive examples of the limitations of artificial neural networks applied to the analysis of independent stochastic data.” Int. J. Comput. Eng. Technol. 5 (5): 40–42.
Nourouzi, M. M., T. G. Chuah, and T. S. Choong. 2011. “Optimisation of reactive dye removal by sequential electrocoagulation-flocculation method: Comparing ANN and RSM prediction.” Water Sci. Technol. 63 (5): 984–994.
Ofir, E., Y. Oren, and A. Adin. 2007. “Modified equilibrium-solubility domains and a kinetic model of iron oxide and hydroxide colloids for electroflocculation.” Desalination 204 (1–3): 79–86.
Olmez-Hanci, T., Z. Kartal, and I. Arslan-Alaton. 2012. “Electrocoagulation of commercial naphthalene sulfonates: Process optimization and assessment of implementation potential.” J. Environ. Manage. 99: 44–51.
Orssatto, F., M. H. Ferreira Tavares, F. M. da Silva, E. Eyng, B. Farias Biassi, and L. Fleck. 2017. “Optimization of the pretreatment of wastewater from a slaughterhouse and packing plant through electrocoagulation in a batch reactor.” Environ. Technol. 38 (19): 2465–2475.
Ouaissa, Y. A., M. Chabani, A. Amrane, and A. Bensmaili. 2014. “Removal of tetracycline by electrocoagulation: Kinetic and isotherm modeling through adsorption.” J. Environ. Chem. Eng. 2 (1): 177–184.
Piuleac, C. G., S. Curteanu, M. A. Rodrigo, C. Sáez, and F. J. Fernández. 2013. “Optimization methodology based on neural networks and genetic algorithms applied to electro-coagulation processes.” Cent. Eur. J. Chem. 11: 1213–1224.
Ponselvan, F. I. A., M. Kumar, J. R. Malviya, V. C. Srivastava, and I. D. Mall. 2008. “Electrocoagulation studies on treatment of biodigester effluent using aluminum electrodes.” Water Air Soil Pollut. 199 (1–4): 371–379.
Secula, M. S., C. S. Stan, C. Cojocaru, B. Cagnon, and I. Cretescu. 2014. “Multi-objective optimization of indigo carmine removal by an electrocoagulation/GAC coupling process in a batch reactor.” Sep. Sci. Technol. 49 (6): 924–938.
Shankar, R., L. Singh, P. Mondal, and S. Chand. 2013. “Removal of COD, TOC, and color from pulp and paper industry wastewater through electrocoagulation.” Desalin. Water Treat. 52 (40–42): 7711–7722.
Sinha, K., P. D. Saha, and S. Datta. 2012. “Response surface optimization and artificial neural network modeling of microwave assisted natural dye extraction from pomegranate rind.” Ind. Crops Prod. 37 (1): 408–414.
Taheri, M., M. R. A. Moghaddam, and M. Arami. 2015. “Improvement of the /Taguchi/ design optimization using artificial intelligence in three acid azo dyes removal by electrocoagulation.” Environ. Prog. Sustainable Energy 34 (6): 1568–1575.
Temkin, M., and V. Pyzhev. 1940. “Kinetics of ammonia synthesis on promoted iron catalysts.” Acta Physiochim. URSS 12 (3): 217–222.
Thakur, L. S., and P. Mondal. 2016. “Techno-economic evaluation of simultaneous arsenic and fluoride removal from synthetic groundwater by electrocoagulation process: Optimization through response surface methodology.” Desalin. Water Treat. 57 (59): 28847–28863.
Thirugnanasambandham, K., V. Sivakumar, and J. P. Maran. 2014a. “Efficiency of electrocoagulation method to treat chicken processing industry wastewater—Modeling and optimization.” J. Taiwan Inst. Chem. Eng. 45 (5): 2427–2435.
Thirugnanasambandham, K., V. Sivakumar, and J. P. Maran. 2015. “Evaluation of an electrocoagulation process for the treatment of bagasse-based pulp and paper industry wastewater.” Environ. Prog. Sustainable Energy 34 (2): 411–419.
Thirugnanasambandham, K., V. Sivakumar, and M. Prakash. 2014b. “Optimization of electrocoagulation process to treat biologically pretreated bagasse effluent.” J. Serb. Chem. Soc. 79 (5): 613–626.
Thirugnanasambandham, K., V. Sivakumar, and K. Shine. 2016. “Studies on treatment of egg processing industry wastewater using electrocoagulation method: Optimization using response surface methodology.” Desalin. Water Treat. 57 (46): 21721–21729.
Thomas, D., S. Judd, and N. Fawcett. 1999. “Flocculation modelling: A review.” Water Res. 33 (7): 1579–1592.
Tipping, M. E. 2004. “Bayesian inference: An introduction to principles and practice in machine learning.” In Vol. 3176 of Advanced Lectures on Machine Learning. Lecture Notes in Computer Science, edited by O. Bousquet, U. von Luxburg, and G. Rätsch, 41–62. Berlin: Springer.
Turan, N. G., B. Mesci, and O. Ozgonenel. 2011. “The use of artificial neural networks (ANN) for modeling of adsorption of Cu(II) from industrial leachate by pumice.” Chem. Eng. J. 171 (3): 1091–1097.
Un, T. U., A. Kandemir, N. Erginel, and S. E. Ocal. 2014. “Continuous electrocoagulation of cheese whey wastewater: An application of response surface methodology.” J. Environ. Manage. 146: 245–250.
Vázquez, A., I. Rodríguez, and I. Lázaro. 2012. “Primary potential and current density distribution analysis: A first approach for designing electrocoagulation reactors.” Chem. Eng. J. 179: 253–261.
Verma, A. K., R. R. Dash, and P. Bhunia. 2012. “A review on chemical coagulation/flocculation technologies for removal of colour from textile wastewaters.” J. Environ. Manage. 93 (1): 154–168.
Yehya, T., M. Chafi, W. Balla, C. Vial, A. Essadki, and B. Gourich. 2014. “Experimental analysis and modeling of denitrification using electrocoagulation process.” Sep. Purif. Technol. 132: 644–654.
Zaroual, Z., H. Chaair, A. H. Essadki, K. El Ass, and M. Azzi. 2009. “Optimizing the removal of trivalent chromium by electrocoagulation using experimental design.” Chem. Eng. J. 148 (2–3): 488–495.
Zodi, S., O. Potier, F. Lapicque, and J.-P. Leclerc. 2010. “Treatment of the industrial wastewaters by electrocoagulation: Optimization of coupled electrochemical and sedimentation processes.” Desalination 261 (1–2): 186–190.

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Go to Electro-Coagulation and Electro-Oxidation in Water and Wastewater
                Treatment
Electro-Coagulation and Electro-Oxidation in Water and Wastewater Treatment
Pages: 79 - 117
Editors: Patrick Drogui, Ph.D., Université du Québec, R. D. Tyagi, Ph.D., Université du Québec, Rao Y. Surampalli, Ph.D., Global Institute for Energy, Environment and Sustainability, Tian C. Zhang, Ph.D., University of Nebraska-Lincoln, Song Yan, Ph.D., Université du Québec, and Xiaolei Zhang, Ph.D., Harbin Institute of Technology (Shenzhen)
ISBN (Print): 978-0-7844-1602-0
ISBN (Online): 978-0-7844-8399-2

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Published online: May 12, 2022

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