Chapter
May 12, 2022
Chapter 13

Electro-Oxidation Processes: Criteria and Considerations for Full-Scale Applications

Publication: Electro-Coagulation and Electro-Oxidation in Water and Wastewater Treatment

Abstract

In recent decades, electro-oxidation (EO) has gained increasing interest for treatment of water and wastewaters, mainly because of its high efficiency in the removal of biorefractory substances. EO has been employed to treat the wastewater generated in various industries. This chapter provides an overview of fundamental aspects of EO in wastewater treatment and the scale-up of this technology in the context of essential design parameters. The EO mechanism and EO design criteria are summarized. Some coupled systems employed for EO-based wastewater treatment are described. The remediation of several types of wastewaters by EO is then explored, with a focus on the different contaminates. Finally, critical challenges pertinent to EO and recommendations to surmount the implementations are presented.

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Nomenclature

BDD
Boron-doped diamond
BOD
Biological oxygen demand
CD
Current density
CNT
Carbon nanotube
COD
Chemical oxygen demand
EC
Electro-coagulation
EO
Electro-oxidation
EPA
Environmental protection agency
POP
Persistent organic pollutant
UF
Ultrafiltratio

References

Anglada, A., A. Urtiaga, and I. Ortiz. 2009. “Contributions of electrochemical oxidation to waste-water treatment: Fundamentals and review of applications.” J. Chem. Technol. Biotechnol. 84 (12): 1747–1755.
Azarian, G., M. Miri, and D. Nematollahi. 2018. “Combined electrocoagulation/electrooxidation process for the COD removal and recovery of tannery industry wastewater.” Environ. Prog. Sustainable Energy 37 (2): 637–644.
Cañizares, P., R. Paz, J. Lobato, C. Sáez, and M. Rodrigo. 2006. “Electrochemical treatment of the effluent of a fine chemical manufacturing plant.” J. Hazard. Mater. 138 (1): 173–181.
Chaplin, B. P. 2018. “Advantages, disadvantages, and future challenges of the use of electrochemical technologies for water and wastewater treatment.” In Electrochemical water and wastewater treatment, edited by C. A. Martínez-Huitle, M. A. Rodrigo, and O. Scialdone, 451–494. Amsterdam, Netherlands: Elsevier.
Chen, G. 2004. “Electrochemical technologies in wastewater treatment.” Sep. Purif. Technol. 38 (1): 11–41.
Chiang, L.-C., J.-E. Chang, and T.-C. Wen. 1995. “Indirect oxidation effect in electrochemical oxidation treatment of landfill leachate.” Water Res. 29 (2): 671–678.
Cong, V. H., Y. Sakakibara, M. Komori, N. Kishimoto, T. Watanabe, I. Mishima, et al. 2016. “Recent developments in electrochemical technology for water and wastewater treatments.” J. Water Environ. Technol. 14 (2): 25–36.
Cotillas, S., J. Llanos, P. Cañizares, D. Clematis, G. Cerisola, M. A. Rodrigo, et al. 2018. “Removal of Procion Red MX-5B dye from wastewater by conductive-diamond electrochemical oxidation.” Electrochim. Acta 263: 1–7.
Dietrich, M., M. Franke, M. Stelter, and P. Braeutigam. 2017. “Degradation of endocrine disruptor bisphenol A by ultrasound-assisted electrochemical oxidation in water.” Ultrason. Sonochem. 39: 741–749.
Drogui, P., J.-F. Blais, and G. Mercier. 2007. “Review of electrochemical technologies for environmental applications.” Recent Pat. Eng. 1 (3): 257–272.
El-Ashtoukhy, E., Y. El-Taweel, O. Abdelwahab, and E. Nassef. 2013. “Treatment of petrochemical wastewater containing phenolic compounds by electrocoagulation using a fixed bed electrochemical reactor.” Int. J. Electrochem. Sci. 8 (1): 1534–1550.
Eljarrat, E., and D. Barcelo. 2003. “Priority lists for persistent organic pollutants and emerging contaminants based on their relative toxic potency in environmental samples.” TrAC, Trends Anal. Chem. 22 (10): 655–665.
Feki, F., F. Aloui, M. Feki, and S. Sayadi. 2009. “Electrochemical oxidation post-treatment of landfill leachates treated with membrane bioreactor.” Chemosphere 75 (2): 256–260.
Fontmorin, J.-M., J. Siguié, F. Fourcade, F. Geneste, D. Floner, I. Soutrel, et al. 2014. “Combined electrochemical treatment/biological process for the removal of a commercial herbicide solution, U46D.” Sep. Purif. Technol. 132: 704–711.
Fryda, M., T. Matthée, S. Mulcahy, M. Hofer, L. Schafer, and I. Troster. 2003. “Applications of DIACHEM electrodes in electrolytic water treatment.” Interface 12 (1): 40–44.
García, E. A., M. Agulló-Barceló, P. Bond, J. Keller, W. Gernjak, and J. Radjenovic. 2018. “Hybrid electrochemical-granular activated carbon system for the treatment of greywater.” Chem. Eng. J. 352: 405–411.
García-Morales, M., G. Roa-Morales, C. Barrera-Díaz, B. Bilyeu, and M. Rodrigo. 2013. “Synergy of electrochemical oxidation using boron-doped diamond (BDD) electrodes and ozone (O3) in industrial wastewater treatment.” Electrochem. Commun. 27: 34–37.
Garcia-Segura, S., J. D. Ocon, and M. N. Chong. 2018. “Electrochemical oxidation remediation of real wastewater effluents—A review.” Process Saf. Environ. Prot. 113: 48–67.
Gargouri, B., O. D. Gargouri, B. Gargouri, S. K. Trabelsi, R. Abdelhedi, and M. Bouaziz. 2014. “Application of electrochemical technology for removing petroleum hydrocarbons from produced water using lead dioxide and boron-doped diamond electrodes.” Chemosphere 117: 309–315.
Ghime, D., and P. Ghosh. 2019. “Removal of organic compounds found in the wastewater through electrochemical advanced oxidation processes: A review.” Russ. J. Electrochem. 55 (7): 591–620.
Ghimire, U., M. Jang, S. P. Jung, D. Park, S. J. Park, H. Yu, et al. 2019. “Electrochemical removal of ammonium nitrogen and cod of domestic wastewater using platinum coated titanium as an anode electrode.” Energies 12 (5): 883.
Gutiérrez, M., and M. Crespi. 1999. “A review of electrochemical treatments for colour elimination.” Color. Technol. 115 (11): 342–345.
HealthCareWithoutHarm. 2018. “Pharmaceutical pollution.” https://noharm-europe.org/.
Hermosilla, D., N. Merayo, A. Gascó, and Á. Blanco. 2015. “The application of advanced oxidation technologies to the treatment of effluents from the pulp and paper industry: A review.” Environ. Sci. Pollut. Res. 22 (1): 168–191.
Isik, Z., E. B. Arikan, Y. Ozay, H. D. Bouras, and N. Dizge. 2020. “Electrocoagulation and electrooxidation pre-treatment effect on fungal treatment of pistachio processing wastewater.” Chemosphere 244: 125383.
Kalra, S. S., S. Mohan, A. Sinha, and G. Singh. 2011. “Advanced oxidation processes for treatment of textile and dye wastewater: A review.” In Proc., 2nd Int. Conf. on Environmental Science and Development, 271–275. Singapore: IACSIT Press.
Klamklang, S., H. Vergnes, K. Pruksathorn, and S. Damronglerd. 2012. Electrochemical incineration of organic pollutants for wastewater treatment: Past, present and prospect. London: INTECH.
Li, T., X. Li, J. Chen, G. Zhang, and H. Wang. 2007. “Treatment of landfill leachate by electrochemical oxidation and anaerobic process.” Water Environ. Res. 79 (5): 514–520.
Li, W., Q. Zhou, and T. Hua. 2010. “Removal of organic matter from landfill leachate by advanced oxidation processes: A review.” Int. J. Chem. Eng. 2010: 270532.
Ling, Y., J. Hu, Z. Qian, L. Zhu, and X. Chen. 2016. “Continuous treatment of biologically treated textile effluent using a multi-cell electrochemical reactor.” Chem. Eng. J. 286: 571–577.
Loos, G., T. Scheers, K. Van Eyck, A. Van Schepdael, E. Adams, B. Van der Bruggen, et al. 2018. “Electrochemical oxidation of key pharmaceuticals using a boron doped diamond electrode.” Sep. Purif. Technol. 195: 184–191.
Mandal, P., B. K. Dubey, and A. K. Gupta. 2017. “Review on landfill leachate treatment by electrochemical oxidation: Drawbacks, challenges and future scope.” Waste Manage. 69: 250–273.
Mantzavinos, D., and E. Psillakis. 2004. “Enhancement of biodegradability of industrial wastewaters by chemical oxidation pre-treatment.” J. Chem. Technol. Biotechnol. 79 (5): 431–454.
Martínez-Huitle, C. A., and E. Brillas. 2009. “Decontamination of wastewaters containing synthetic organic dyes by electrochemical methods: A general review.” Appl. Catal. B 87 (3–4): 105–145.
Martínez-Huitle, C. A., E. V. dos Santos, D. M. de Araújo, and M. Panizza. 2012. “Applicability of diamond electrode/anode to the electrochemical treatment of a real textile effluent.” J. Electroanal. Chem. 674: 103–107.
Mostafazadeh, A. K., A. T. Benguit, A. Carabin, P. Drogui, and E. Brien. 2019. “Development of combined membrane filtration, electrochemical technologies, and adsorption processes for treatment and reuse of laundry wastewater and removal of nonylphenol ethoxylates as surfactants.” J. Water Process Eng. 28: 277–292.
Panizza, M., and G. Cerisola. 2010. “Applicability of electrochemical methods to carwash wastewaters for reuse. Part 2: Electrocoagulation and anodic oxidation integrated process.” J. Electroanal. Chem. 638 (2): 236–240.
Radjenovic, J., and D. L. Sedlak. 2015. “Challenges and opportunities for electrochemical processes as next-generation technologies for the treatment of contaminated water.” Environ. Sci. Technol. 49 (19): 11292–11302.
Rajeshwar, K., and J. G. Ibanez. 1997. Environmental electrochemistry: Fundamentals and applications in pollution sensors and abatement. Amsterdam, Netherlands: Elsevier.
Ren, Q., C. Yin, Z. Chen, M. Cheng, Y. Ren, X. Xie, et al. 2019. “Efficient sonoelectrochemical decomposition of chlorpyrifos in aqueous solution.” Microchem. J. 145: 146–153.
Sala, M., and M. C. Gutiérrez-Bouzán. 2012. “Electrochemical techniques in textile processes and wastewater treatment.” Int. J. Photoenergy 2012: 629103.
Särkkä, H., A. Bhatnagar, and M. Sillanpää. 2015. “Recent developments of electro-oxidation in water treatment—A review.” J. Electroanal. Chem. 754: 46–56.
Sartaj, S., N. Ali, A. Khan, S. Malik, M. Bilal, M. Khan, et al. 2020. “Performance evaluation of photolytic and electrochemical oxidation processes for enhanced degradation of food dyes laden wastewater.” Water Sci. Technol. 81 (5): 971–984.
Scialdone, O., S. Randazzo, A. Galia, and G. Silvestri. 2009. “Electrochemical oxidation of organics in water: Role of operative parameters in the absence and in the presence of NaCl.” Water Res. 43 (8): 2260–2272.
Senthilkumar, S., C. A. Basha, M. Perumalsamy, and H. J. Prabhu. 2012. “Electrochemical oxidation and aerobic biodegradation with isolated bacterial strains for dye wastewater: Combined and integrated approach.” Electrochim. Acta 77: 171–178.
Sirés, I., E. Brillas, M. A. Oturan, M. A. Rodrigo, and M. Panizza. 2014. “Electrochemical advanced oxidation processes: Today and tomorrow. A review.” Environ. Sci. Pollut. Res. 21 (14): 8336–8367.
Solano, A. M. S., C. K. C. de Araújo, J. V. de Melo, J. M. Peralta-Hernandez, D. R. da Silva, and C. A. Martínez-Huitle. 2013. “Decontamination of real textile industrial effluent by strong oxidant species electrogenerated on diamond electrode: Viability and disadvantages of this electrochemical technology.” Appl. Catal., B 130–131: 112–120.
Song, L.-J., N.-W. Zhu, H.-P. Yuan, Y. Hong, and J. Ding. 2010. “Enhancement of waste activated sludge aerobic digestion by electrochemical pre-treatment.” Water Res. 44 (15): 4371–4378.
Szpyrkowicz, L., S. N. Kaul, and R. N. Neti. 2005. “Tannery wastewater treatment by electro-oxidation coupled with a biological process.” J. Appl. Electrochem. 35 (4): 381–390.
Thokchom, B., K. Kim, J. Park, and J. Khim. 2015. “Ultrasonically enhanced electrochemical oxidation of ibuprofen.” Ultrason. Sonochem. 22: 429–436.
Un, U. T., U. Altay, A. S. Koparal, and U. B. Ogutveren. 2008. “Complete treatment of olive mill wastewaters by electrooxidation.” Chem. Eng. J. 139 (3): 445–452.
Walsh, F. 2001. “Electrochemical technology for environmental treatment and clean energy conversion.” Pure Appl. Chem. 73 (12): 1819–1837.
Wendt, H., and G. Kreysa. 1999. Electrochemical engineering: Science and technology in chemical and other industries. Berlin: Springer.
Woisetschläger, D., B. Humpl, M. Koncar, and M. Siebenhofer. 2013. “Electrochemical oxidation of wastewater —Opportunities and drawbacks.” Water Sci. Technol. 68 (5): 1173–1179.
Workgroup, O. O. E. C. (2008). “Aquatic life criteria for contaminants of emerging concern: General challenges and recommendations.” US Environmental Protection Agency Duluth, MN.
Xu, F., L. Chang, X. Duan, W. Bai, X. Sui, and X. Zhao. 2019. “A novel layer-by-layer CNT/PbO2 anode for high-efficiency removal of PCP-Na through combining adsorption/electrosorption and electrocatalysis.” Electrochim. Acta 300: 53–66.
Yan, L., H. Ma, B. Wang, Y. Wang, and Y. Chen. 2011. “Electrochemical treatment of petroleum refinery wastewater with three-dimensional multi-phase electrode.” Desalination 276 (1–3): 397–402.
Zhang, C., Y. Jiang, Y. Li, Z. Hu, L. Zhou, and M. Zhou. 2013. “Three-dimensional electrochemical process for wastewater treatment: A general review.” Chem. Eng. J. 228: 455–467.
Zhong, C., W. B. Hu, and Y. F. Cheng. 2013. “Recent advances in electrocatalysts for electro-oxidation of ammonia.” J. Mater. Chem. A 1 (10): 3216–3238.

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Go to Electro-Coagulation and Electro-Oxidation in Water and Wastewater
                Treatment
Electro-Coagulation and Electro-Oxidation in Water and Wastewater Treatment
Pages: 359 - 382
Editors: Patrick Drogui, Ph.D., Université du Québec, R. D. Tyagi, Ph.D., Université du Québec, Rao Y. Surampalli, Ph.D., Global Institute for Energy, Environment and Sustainability, Tian C. Zhang, Ph.D., University of Nebraska-Lincoln, Song Yan, Ph.D., Université du Québec, and Xiaolei Zhang, Ph.D., Harbin Institute of Technology (Shenzhen)
ISBN (Print): 978-0-7844-1602-0
ISBN (Online): 978-0-7844-8399-2

History

Published online: May 12, 2022
Published in print: May 27, 2022

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Ali Khosravanipour Mostafazadeh

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