Preparation and Performance of Polyphosphoric Acid/Bio-Oil Composite–Modified Asphalt Containing a High Content Bio-Oil
Publication: Journal of Materials in Civil Engineering
Volume 34, Issue 3
Abstract
As an important ecofriendly material in pavement engineering, bioasphalt has received more and more attention recently. However, the negative high-temperature behavior of bioasphalt limits its extensive application. With the purpose of enhancing the bioasphalt high-temperature behavior, polyphosphoric acid (PPA) was used to modify bioasphalt. The PPA/bio-oil composite–modified asphalt’s high-temperature behavior was investigated by the dynamic shear rheometer (DSR) test. The low-temperature behavior was evaluated by using the bending beam rheometer (BBR) test. Finally, the modification mechanism of modified asphalt was analyzed by carrying out a Fourier-transform infrared reflection (FTIR) test. The results indicated that compared with the neat asphalt, the rutting index of PPA/bio-oil composite–modified asphalt was significantly improved. Also, it had excellent low-temperature crack resistance. As the bio-oil and PPA contents in respect to the weight of neat asphalt were 15% and 5%, respectively, PPA/bio-oil composite–modified asphalt performance was optimal. Shear time and shear rate did not have a remarkable effect on PPA/bio-oil composite–modified asphalt performance. Moreover, bio-oil did not affect the chemical structure of the neat asphalt. But, PPA generated new chemical functional groups with neat asphalt and produced chemical modification. This research makes pavement engineering greener, more economical, and environmentally friendly.
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Data Availability Statement
Some or all data, models, or code that support the findings of this study are available from the corresponding author upon reasonable request.
Acknowledgments
This work was supported by the National Natural Science Foundation of China (52078063), the Postgraduate Scientific Research Innovation Project of Hunan Province (CX20200822), the science and technology innovation project of Shanghai Chengtou (group) Co., Ltd (CTKY-PTRC-2018-003), and the Project of Shenzhen Municipal Engineering Corporation(2020zkhx387).
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Published In
Journal of Materials in Civil Engineering
Volume 34 • Issue 3 • March 2022
Copyright
© 2021 American Society of Civil Engineers.
History
Received: Jan 29, 2021
Accepted: Jul 22, 2021
Published online: Dec 28, 2021
Published in print: Mar 1, 2022
Discussion open until: May 28, 2022
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