Technical Papers
May 26, 2015

Time-Dependent Strength and Mineralogy of Lime-GGBS Treated Naturally Occurring Acid Sulfate Soils

This article has been corrected.
VIEW CORRECTION
This article is a reply.
VIEW THE ORIGINAL ARTICLE
Publication: Journal of Materials in Civil Engineering
Volume 28, Issue 1

Abstract

This study investigates the effect of time-dependent mineralogical changes on the unconfined compressive strength (UCS) behavior of lime–ground granulated blast furnace slag (GGBS) treated naturally occurring acid sulfate soils (ASS) containing various proportions of pyrite. Pyrite (0, 2, 4% by weight), GGBS (5, 10, 15, 20% by weight), a fixed lime content of 15% by weight and curing periods up to 365 days were investigated. Mineralogical control on the strength of treated ASS samples was investigated using UCS analyses, X-ray diffraction (XRD), and scanning electron microscopy (SEM). Quantitative phase analysis using XRD data and the Rietveld method was carried out to quantify mineralogical changes. Results show a decrease of UCS values after 180 days curing for ASS containing 4% by weight additional pyrite and treated with 20% by weight GGBS. XRD and SEM analyses suggest that a decline in the abundance of cementitious mineral phases coincides with possible formation of thaumasite-ettringite and the degradation of strength in treated ASS.

Get full access to this article

View all available purchase options and get full access to this article.

References

Ahnberg, H., Johansson, S. E., Phil, H., and Carlson, T. (2003). “Stabilizing effects of different binders in some Swedish soils.” Ground Improv., 7(1), 9–23.
Alonso, E. E., and Ramon, A. (2013). “Massive sulfate attack to cement-treated railway embankments.” Geotechnique, 63(10), 857–870.
Bensted, J. (2000). “Mechanism of thaumasite sulfate attack in cements, mortars and concretes.” Zement-Kalk-Gips Int., 53(12), 704–709.
Bish, D. L., and Howard, S. A. (1988). “Quantitative phase analysis using the Rietveld method.” J. Appl. Cryst., 21(2), 86–91.
Blanco-Varela, M. T., Aguilera, J., and Martinez-Ramirez, S. (2006). “Effect of cement C3A content, temperature and storage medium on thaumasite of formation in carbonated mortars.” Cem. Concr. Res., 36(4), 707–715.
Bruker, A. X. S. (2004). Topaz V. 3.0: “General profile and structure analysis software for powder diffraction data, Karlsruhe, Germany.
BS. (1990). “Stabilized materials for civil engineering purpose. Methods of test for cement-stabilized and lime-stabilized materials.” BS 1924-2, British Standard Institution, London, U.K.
Cheary, R. W., and Coelho, A. A. (1992). “A fundamental parameters approach to X-ray line-profile fitting.” J. Appl. Cryst., 25(2), 109–121.
Chrysochoou, M. (2014). “Investigation of the mineral dissolution rate and strength development in stabilized soils using quantitative X-ray diffraction.” J. Mater. Civ. Eng., 26(2), 288–295.
Collepardi, M. (1999). “Thaumasite formation and deterioration in historic building.” Cem. Concr. Compos., 21(2), 147–154.
Crammond, N. J. (2003). “The thaumasite form of sulfate attack in the U.K.” Cem. Concr. Compos., 25(8), 809–818.
DIFFRACplus EVA [Computer software]. Karlsruhe, Germany, Bruker AXS.
Eades, J. E., and Grim, R. E. (1963). “A quick rest to determine lime requirements for lime stabilization.”, Highway Research Board, National Research Council, Washington, DC, 61–72.
Fitzpatrick, R. W., Davies, P. G., Thomas, B. P., Merry, R. H., Fotheringham, D. G., and Hicks, W. S. (2002). “Properties and distribution of South Australian coastal acid sulfate soils and their environmental hazards.” Proc., 5th Int. Acid Sulfate Soils Conf., Tweed Heads, NSW.
Gregory, O., and Jones, D. (2005). “World of iron and steel—A construction materials perspective.” Australasian Slag (Iron & Steel) Association, Wollongong, Australia, 〈http://www.researchgate.net/publication/222394294_Development_of_large_scale_reuses_of_inorganic_by-products_in_Australia_The_case_study_of_Kwinana_Western_Australia〉 (Jan. 5, 2015).
Higgins, D. D. (2005). Soil stabilisation with ground granulated blastfurnace slag, Cementitious Slag Makers Association, U.K.
Hill, R. J., and Howard, C. J. (1987). “Quantitative phase analysis from neutron powder diffraction data using the Rietveld method.” J. Appl. Cryst., 20(6), 467–474.
Ingles, O. G., and Metcalf, J. B. (1972). Soil stabilization: Principles and practice, Butterworths, Sydney, Australia.
Islam, S., Chowdhury, B., and Haque, A. (2012). “On the sustainable ground improvement aspects of pyrite bearing clay using lime activated slag.” Geotechnical Special Publication, ASCE, Reston, VA, 228, 1781–1788.
Islam, S., Haque, A., and Wilson, S. (2014a). “Effects of curing environment on the strength and mineralogy of lime-GGBS-treated acid sulphate soils.” J. Mater. Civ. Eng., 1003–1008.
Islam, S., Haque, A., Wilson, S., and Ranjith, P. G. (2014b). “Improvement of acid sulfate soils using lime-activated slag.” Proc. Inst. Civ. Eng. Ground Improv., 167(4), 235–248.
James, R., Kamruzzaman, A. H. M., Haque, A., and Wilkinson, A. (2008). “Behaviour of lime slag treated soils.” Proc. Inst. Civ. Eng. Ground Improv., 161(4), 207–216.
Justnes, H. (2003). “Thaumasite formed by sulfate attack on mortar with limestone filler.” Cem. Concr. Compos., 25(8), 955–959.
Karim, N. J., Manu, S., and Menashi, D. C. (2003). “Stability and reactivity of thaumasite at different pH levels.” Cem. Concr. Res., 33(3), 433–437.
Kwang, S. P. (2003). “Laboratory investigation on the improvement of strength and compressibility characterisitcs of coode island silt by soil mixing.” M.Sc. thesis, Monash Univ., Melbourne, Australia.
Little, D. N., Nair, S., and Herbert, B. (2010). “Addressing sulfate-induced heave in lime treated soils.” J. Geotechnol. Geoenviron. Eng., 110–118.
Locat, J., Berube, M. A., and Choquette, M. (1990). “Laboratory investigations on the lime stabilization of sensitive clays: Shear strength development.” Can. Geotech. J., 27(3), 294–304.
Mitchell, J., and Kelly, R. (2013). “Addressing some current challenges in ground improvement.” Proc. Inst. Civ. Eng. Ground Improv., 166(3), 127–137.
National Working Party on Acid Sulfate Soils. (2000). “National strategy for the management of coastal acid sulfate soils.” NSW agriculture, Wollongbar Agricultural Institute, Wollongbar, NSW, Australia.
Nidzam, R. M., and Kinuthia, J. M. (2010). “Sustainable soil stabilization with blastfurnace slag,” Proc. Inst. Civ. Eng. Constr. Mater., 163(3), 157–165.
NIST DTSA-II [Computer software]. MD, National Institute of Standard and Technology.
Porbaha, A., Shibuya, S., and Kishida, T. (2000). “State of the art in deep mixing technology. Part III: Geomaterial characterization.” Ground Improv., 4(3), 91–110.
Rex, S., Chapman, M., Haque, A., Kamruzzaman, A. H. M., and Wilkinson, A. (2008). “Strength and compressibility behaviour of lime-slag treated Coode Island Silt.” Aust. Geomech., 43(4), 31–40.
Rieltveld, H. M. (1969). “A profile refimenet method for nuclear and magnetic structure.” J. Appl. Cryst., 2(2), 65–71.
Stanley, B. (2011). “Engineering and microstructural behavior of lime-slag treated sulphide bearing Coode island silt.” M.Sc. thesis, Monash Univ., Australia.
Stanley, B., Chowdhury, B., and Haque, A. (2010). “Discussion of” addressing sulfate-induced heave in lime treated soils.” J. Geotech. Geoenviron. Eng., 812–813.
Thomas, B. I. (2001). “Stabilisation of sulphide rich soil: Problems and solutions.” Ph.D. thesis, Univ. of Glamorgan, Pontypridd, U.K.
Topas version 3 [Computer software]. Karlsruhe, Germany, Bruker AXS.
Torres, S. M., Kirk, C. A., Lynsdale, C. J., Swamy, R. N., and Sharp, J. H. (2004). “Thaumasite-ettringite solid solutions in degraded mortars.” Cem. Concr. Res., 34(8), 1297–1305.
Veith, H. V. (2000). “Engineering properties of sulfate-bearing clay soils stabilized with lime-activated ground granulated blast furnace slag (slag).” Ph.D. thesis, Univ. of Glamorgan, Pontypridd, U.K.
Wild, S., Kinuthia, J. M., Jones, G. I., and Higgins, D. D. (1998). “Effects of partial substitution of lime with ground granulated blast furnace slag (SLAG) on the strength properties of lime-stabilised sulfate-bearing clay soils.” Eng. Geol., 51(1), 37–53.
Wilkinson, A., Haque, A., and Kodikara, J. (2010a). “Stabilisation of clayey soils with industrial by-products: Part A.” Proc. Inst. Civ. Eng. Ground Improv., 163(3), 149–163.
Wilkinson, A., Haque, A., and Kodikara, J. (2010b). “Stabilisation of clayey soils with industrial by-products: Part B.” Proc. Inst. Civ. Eng. Ground Improv., 163(3), 165–172.
Wilson, S. A., Raudsepp, M., and Dipple, G. M. (2006). “Verifying and quantifying carbon fixation in minerals from serpentine-rich mine tailings using the Rietveld method with X-ray powder diffraction data.” Am. Mineral., 91(8–9), 1331–1341.
Wilson, S. A., Raudsepp, M., and Dipple, G. M. (2009). “Quantifying carbon fixation in trace minerals from processed kimberlite: A comparative study of quantitative methods using X-ray powder diffraction data with applications to the Diavik Diamond Mine, Northwest Territories, Canada.” Appl. Geochem., 24(12), 2312–2331.

Information & Authors

Information

Published In

Go to Journal of Materials in Civil Engineering
Journal of Materials in Civil Engineering
Volume 28Issue 1January 2016

History

Received: Dec 3, 2013
Accepted: Mar 12, 2015
Published online: May 26, 2015
Discussion open until: Oct 26, 2015
Published in print: Jan 1, 2016

Permissions

Request permissions for this article.

Authors

Affiliations

Shahidul Islam
Ph.D. Candidate, Dept. of Civil Engineering, Monash Univ., 23 College Walk, VIC 3800, Australia.
Asadul Haque [email protected]
Senior Lecturer, Dept. of Civil Engineering, Monash Univ., 23 College Walk, VIC 3800, Australia (corresponding author). E-mail: [email protected]
Sasha Wilson
Lecturer, School of Earth, Atmosphere and Environment, Monash Univ., 9 Rainforest Walk, VIC 3800, Australia.
P. G. Ranjith, F.ASCE
Professor, Dept. of Civil Engineering, Monash Univ., 23 College Walk, VIC 3800, Australia.

Metrics & Citations

Metrics

Citations

Download citation

If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download.

Cited by

View Options

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Media

Figures

Other

Tables

Share

Share

Copy the content Link

Share with email

Email a colleague

Share