Durability against Wetting–Drying Cycles of Water Treatment Sludge–Fly Ash Geopolymer and Water Treatment Sludge–Cement and Silty Clay–Cement Systems
Publication: Journal of Materials in Civil Engineering
Volume 28, Issue 1
Abstract
The viability of using two waste materials, water treatment sludge (WTS) and fly ash (FA), for developing sustainable masonry units has been previously investigated in terms of strength but the important aspect of durability against wetting–drying (w–d) cycles has yet to be studied. A study on durability against w–d cycles, an important parameter for service life design of the sustainable masonry units, is investigated in this paper. The liquid alkaline activator (L) was a mixture of sodium silicate () and sodium hydroxide (NaOH), and a high calcium fly ash (FA) was used as a precursor. The results of cyclic w–d test indicate that the WTS–FA geopolymer manufactured with an optimum ingredient (, ) and at an optimum heat condition of 85°C for 72 h can be used as durable bearing masonry units; i.e., the compressive strength is greater than 12 MPa after 12 w–d cycles. For this optimum ingredient, the w–d cycle strength, at heat temperatures between 65 and 95°C and durations between 24 and 120 h was found to be mainly dependent upon the initial soaked (without w–d cycle) strength , and the normalized strength versus number of w–d cycles relationship expresses as a logarithm function. This relationship facilitates a mix design to attain the required strength at a target service life, which is very useful for civil engineering practitioners and researchers alike. It is evident from this research that portland cement is not a suitable cementing agent to manufacture WTS masonry units because alum in WTS retards the cement hydration, unlike a geopolymer binder, which was proven to be suitable. Compared with a traditional clay–cement sample at the same initial soaked strength, the WTS–FA geopolymer sample exhibits higher durability. This indicates that the WTS–FA geopolymer masonry units have a longer service life than clay–cement masonry units, which is typically used in many countries. This research enables WTS traditionally destined for landfill to be used in a sustainable manner as an aggregate in geopolymer masonry units, which is significant from engineering, economical, and environmental perspectives.
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Acknowledgments
This work was financially supported by Metropolitan Waterworks Authority of Thailand in the fiscal year 2013, the Thailand Research Fund under the TRF Senior Research Scholar program Grant No. RTA5680002, the Office of Higher Education Commission under NRU project of Thailand, and Suranaree University of Technology.
References
Akbulut, H., and Gurer, C. (2007). “Use of aggregates produced from marble quarry waste in asphalt pavements.” Build. Environ., 42(5), 1921–1930.
Arulrajah, A., Ali, M. M. Y., Disfani, M. M., and Horpibulsuk, S. (2014a). “Recycled glass blends in pavement base/subbase applications: laboratory and field evaluation.” J. Mater. Civ. Eng., 26(7), 1–12.
Arulrajah, A., Piratheepan, J., Disfani, M. M., and Bo, M. W. (2013). “Geotechnical and geoenvironmental properties of recycled construction and demolition materials in pavement subbase applications.” J. Mater. Civ. Eng., 1077–1088.
Arulrajah, A., Disfani, M. M., Horpibulsuk, S., Suksiripattanapong, C., and Prongmanee, N. (2014b). “Physical properties and shear strength response of recycled construction and demolition materials in unbound pavement base/subbase pavement.” Constr. Build. Mater., 58, 245–257.
Arulrajah, A., Disfani, M. M., Suthagaran, V., and Imteaz, M. (2011). “Select chemical and engineering properties of wastewater biosolids.” Waste Manage., 31(12), 2522–2526.
Arulrajah, A., Maghoolpilehrood, F., Disfani, M. M., and Horpibulsuk, S. (2014c). “Spent coffee grounds as a non-structural embankment fill material: Engineering and environmental considerations.” J. Cleaner Prod., 72, 181–186.
ASTM. (2000). “Standard test methods for compressive strength of molded soil-cement cylinders.” C1633, West Conshohcken, PA.
ASTM. (2003). “Standard test methods for wetting and drying compacted soil-cement mixtures.” C599-03, West Conshohcken, PA.
ASTM. (2005). “Standard test methods for liquid limit, plastic limit, and plasticity index of soils.”, West Conshohcken, PA.
ASTM. (2012a). “Standard Specification for coal fly ash and raw or calcined natural pozzolan for use in concrete.” C618-12a, West Conshohcken, PA.
ASTM. (2012b). “Standard test methods for laboratory compaction characteristics of soil using modified effort [ ()].” D1557, West Conshohcken, PA.
Buchwald, A., and Kaps, Ch. (2002). “Property controlling influences on the generation of geopolymeric binders based on clay.” Geopolymer 2002, Melbourne, Australia.
Chindaprasirt, C., Chareerat, T., and Sirivivatnanon, V. (2007). “Workability and strength of coarse high calcium fly ash geopolymer.” Cem. Concr. Compos., 29(3), 224–229.
Davidovits, J. (1991). “Geopolymers.” J. Therm. Anal. Calorim., 37(8), 1633–1656.
Davidovits, J., Buzzi, L., Rocher, R., Gimeno, D., Marini, C., and Tocco, S. (1999). “Geopolymeric cenment based on low cost geologic material results from the European Researh project GEOCIS-TEM.” Proc., 2nd Int. Conf. Geopolymer, 83–96.
Disfani, M. M., Arulrajah, A., Bo, M. W., and Suthagaran, V. (2012). “Environmental risks of using recycled crushed glass in road applications.” J. Cleaner Prod., 20(1), 170–179.
Du, Y. J., Jiang, N. J., Shen, S. L., and Jin, F. (2012). “Experimental investigation of influence of acid rain on leaching and hydraulic characteristics of cement-based solidified/stabilized lead contaminated clay.” J. Hazard. Mater., 225, 195–201.
Du, Y. J., Li, S. L, and Hayashi, S. (1999). “Swelling-shrinkage properties and soil improvement of compacted expansive soil, Ning-Lian Highway, China.” Eng. Geol., 53(3–4), 351–358.
Du, Y. J., Wei, M. L., and Jin, F. (2013). “Laboratory investigation on strength properties of cement stabilized zinc-contaminated clay.” Eng. Geol., 167(17), 20–26.
Grubb, D. G., Gallagher, P. M., Wartman, J., Liu, Y., and Carnivale, M. C. (2006). “Laboratory evaluation of crushed glass-dredged material blends.” J. Geotech. Geoenviron. Eng., 562–576.
Horpibulsuk, S., Katkan, W., and Apichatvullop, A. (2008). “An approach for assessment of compaction curves of fine-grained soils at various energies using a one point test.” Soils Found., 48(1), 115–125.
Horpibulsuk, S., Katkan, W., and Naramitkornburee, A. (2009). “Modified Ohio’s curves: A rapid estimation of compaction curves for coarse- and fine-grained soils.” Geotech. Test. J., 32(1), 64–75.
Horpibulsuk, S., Munsrakest, V., Udomchai, A., Chinkulkijniwat, A., and Arulrajah, A. (2014). “Strength of sustainable non-bearing masonry unit manufacturing from calcium carbide residue and fly ash.” Constr. Build. Mater., 71, 210–215.
Horpibulsuk, S., Phetchuay, C., and Chinkulkijniwat, A. (2012). “Soil stabilization by calcium carbide residue and fly ash.” J. Mater. Civ. Eng., 184–193.
Horpibulsuk, S., Shibuya, S., Fuenkajorn, K., and Katkan, W. (2007). “Assessment of engineering properties of Bangkok clay.” Can. Geotech. J., 44(2), 173–187.
Huang, W. L., Lin, D. H., Chang, N. B., and Lin, K. S. (2002). “Recycling of construction and demolition waste via a mechanical sorting process.” Resour. Conserv. Recycl., 37(1), 23–37.
Kampala, A., and Horpibulsuk, S. (2013). “Engineering properties of calcium carbide residue stabilized silty clay.” J. Mater. Civ. Eng., 632–644.
Kampala, A., Horpibulsuk, S., Prongmanee, N., and Chinkulkijniwat, A. (2014). “Influence of wet-dry cycles on compressive strength of calcium carbide residue-fly ash stabilized clay.” J. Mater. Civ. Eng., 633–643.
Landris, T. L. (2007). “Recycled glass and dredged materials.”, U.S. Army Corps of Engineers, Engineer Research and Development Center.
Mohapatra, R., and Rao, J. R. (2001). “Some aspects of characterisation, utilisation and environmental effects of fly ash.” J. Chem. Technol. Biotech., 76(1), 9–26.
Neramitkornburi, A., Horpibulsuk, S., Shen, S. L., Chinkulkijniwat, A., Arulrajah, A., and Disfani, M. M. (2015). “Durability against wetting-drying cycles of sustainable lightweight cellular cemented construction material comprising clay and fly ash wastes.” Constr. Build. Mater., 77, 41–49.
Phetchuay, C., Horpibulsuk, S., Suksiripattanpong, C., Chinkulkijniwat, A., Arulrajah, A., and Disfani, M. M. (2014). “Calcium carbide residue: Alkaline activator for clay-fly ash geopolymer.” Constr. Build. Mater., 69, 285–294.
Prakash, K., and Sridharan, A. (2004). “Free swell ratio and clay mineralogy of fine grained soils.” Geotech. Test. J., 27(2), 220–225.
Puppala, A. J., Hoyos, L. R., and Potturi, A. K. (2011). “Resilient moduli response of moderately cement-treated reclaimed asphalt pavement aggregates.” J. Mater. Civ. Eng., 990–998.
Reddy, K. R., Hettiarachchi, H., Parakalla, N. S., Gangathulasi, J., and Bogner, J. E. (2009). “Geotechnical properties of fresh municipal solid waste at Orchard Hills Landfill, USA.” Waste Manage., 29(2), 952–959.
Rickard, W. D. A., Temuujin, J., and van Riessen, A. (2012). “Thermal analysis of geopolymer pastes synthesised from five fly ashes of variable composition.” J. Non-Cryst. Solids, 358(15), 1830–1839.
Rickard, W. D. A., Williams, R., Temuujin, J., and van Riessen, A. (2011). “Assessing the suitability of three Australian fly ashes as an aluminosilicate source for geopolymer in high temperature applications.” Mater. Sci. Eng., 528(9), 3390–3397.
Sata, V., Sathonsaowaphak, A., and Chindaprasirt, P. (2012). “Resistance of lignite bottom ash geopolymer mortar to sulfate and sulfuric acid attack.” Cem. Concr. Compos., 34(5), 700–708.
Sukmak, P., Horppibulsuk, S., and Shen, S. L. (2013a). “Strength development in clay-fly ash geopolymer.” Constr. Build. Mater., 40, 566–574.
Sukmak, P., Horppibulsuk, S., Shen, S. L., Chindaprasirt, P., and Suksiripattqanapong, C. (2013b). “Factors influencing strength development in clay-fly ash geopolymer.” Constr. Build. Mater., 47, 1125–1136.
Sukmak, P., Silva, P.-D., Horpibulsuk, S., and Chindaprasirt, P. (2014). “Sulphate resistance of clay-Portland cement and clay-high calcium fly ash geopolymer.” J. Mater. Civ. Eng., 04014158.
Suksiripattanapong, C., Horpibulsuk, S., Chanprasert, P., Sukmak, P., and Arulrajah, A. (2015). “Compressive strength development in geopolymer masonsy units manufactured from water treatment sludge.” Constr. Build. Mater., 82, 20–30.
Taha, R., Al-Harthy, A., Al-Shamsi, K., and Al-Zubeidi, M. (2002). “Cement stabilization of reclaimed asphalt pavement aggregate for road bases and subbases.” J. Mater. Civ. Eng., 239–245.
TIS. (1987). “Standard for hollow non-load bearing concrete mansonry unit.” TIS 57-2530, Thai Industrial Standards Institute.
Van Jaarsveld, J., Van Deventer, J., and Lorenzen, L. (1998). “Factors affecting the immobilization of metals in geopolymerized fly ash.” Metall. Mater. Trans. B, 29(1), 283–291.
Wartman, J., Grubb, D. G., and Nasim, A. S. M. (2004). “Select engineering characteristics of crushed glass.” J. Mater. Civ. Eng., 526–539.
Wongpa, J., Kiattikomol, K., Jaturapitakkul, C., and Chindaprasirt, P. (2010). “Compressive strength, modulus of elasticity, and water permeability of inorganic polymer concrete.” Mater. Des., 31(10), 4748–4754.
Zekkos, D. P., Bray, J. D., Kavazanjian, E., Jr., Matasovic, N., Rathje, E. M., and Riemer, M. F. (2006). “Unit weight of municipal solid waste.” J. Geotech. Geoenviron. Eng., 1250–1261.
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Received: Jan 5, 2015
Accepted: Apr 7, 2015
Published online: May 26, 2015
Discussion open until: Oct 26, 2015
Published in print: Jan 1, 2016
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