Technical Papers
Jul 19, 2022

Effect of Different Lime-Anhydrite Ratios on the Hydration Process of Sulfoaluminate Cement

Publication: Journal of Materials in Civil Engineering
Volume 34, Issue 10

Abstract

In this paper, the influence of lime-anhydrite (L/A) ratio on the strength development, cement hydration, and setting time of calcium sulfoaluminate cement (CSA) is systemically investigated. Based on Raman spectroscopy and Thermogravimetric and differential thermal analysis (TG-DTA), the results showed that the hydration rate and the amounts and proportion of hydration products [monosulfate ettringe (AFm), ettringite (AFt), and AH3] were strongly influenced by L/A. When L/A was 1:3, the AFt formation was present by the fastest rate and accounted for the largest proportion of the whole hydration products, further resulting in the highest strength. When L/A13, the process of cement hydration can be divided into induction, the formation of AFt and AFm, interconversion between AFm and AFt, and stabilization stage, respectively. However, when L/A>13, there was no induction stage, and hydration process directly went into the accelerated period.

Get full access to this article

View all available purchase options and get full access to this article.

Data Availability Statement

No data, models, or code were generated or used during the study.

Acknowledgments

The authors would like to acknowledge the financial support provided by the National Key R&D Projects of China Grant (No. 2017YFC0603004), National Natural Science Foundation of China (No. 52078192), Key Fund of the National Natural Science Foundation of China (No. U1905216), the Natural Science Foundation of Henan Province in China (Nos. 182300410207 and 212300410043), and the Education Department of Henan Province Basic Research Program, China (No. 21A430018).

References

Beltagui, H., G. Jen, M. Whittaker, and M. S. Imbabi. 2017. “The influence of variable gypsum and water content on the strength and hydration of a belite-calcium sulphoaluminate cement.” Adv. Appl. Ceram. 116 (4): 199–206. https://doi.org/10.1080/17436753.2017.1289722.
Berger, S., C. C. D. Coumes, P. Le Bescop, and D. Damidot. 2010. “Influence of a thermal cycle at early age on the hydration of calcium sulphoaluminate cements with variable gypsum contents.” Cem. Concr. Res. 41 (2): 149–160. https://doi.org/10.1016/j.cemconres.2010.10.001.
Burris, L. E., and K. E. Kurtis. 2018. “Influence of set retarding admixtures on calcium sulfoaluminate cement hydration and property development.” Cem. Concr. Res. 104 (Feb): 105–113. https://doi.org/10.1016/j.cemconres.2017.11.005.
Canbek, O., and S. T. Erdoğan. 2020. “Influence of production parameters on calcium sulfoaluminate cements.” Constr. Build. Mater. 239 (Apr): 117866. https://doi.org/10.1016/j.conbuildmat.2019.117866.
Chinese Standard. 2011. Standard consistency water consumption, setting time and test methods for settling strength. GB/T 1346-2011. Beijing: Chinese Standard.
Gartner, E. 2004. “Industrially interesting approaches to “low-CO2 ”cements.” Cem. Concr. Res. 34 (9): 1489–1498. https://doi.org/10.1016/j.cemconres.2004.01.021.
Hu, C., D. Hou, and Z. Li. 2017. “Micro-mechanical properties of calcium sulfoaluminate cement and the correlation with microstructures.” Cem. Concr. Compos. 80 (Jul): 10–16. https://doi.org/10.1016/j.cemconcomp.2017.02.005.
Hu, Y., W. Li, S. Ma, and X. Shen. 2017. “Influence of borax and citric acid on the hydration of calcium sulfoaluminate cement.” Chem. Pap. 71 (10): 1909–1919. https://doi.org/10.1007/s11696-017-0185-9.
Huang, G., D. Pudasainee, R. Gupta, and W. V. Liu. 2020. “Utilization and performance evaluation of molasses as a retarder and plasticizer for calcium sulfoaluminate cement-based mortar.” Constr. Build. Mater. 243 (May): 118201. https://doi.org/10.1016/j.conbuildmat.2020.118201.
Jin, Z., B. Ma, Y. Su, W. Lu, H. Qi, and P. Hu. 2020. “Effect of calcium sulphoaluminate cement on mechanical strength and waterproof properties of beta-hemihydrate phosphogypsum.” Constr. Build. Mater. 242 (May): 118198. https://doi.org/10.1016/j.conbuildmat.2020.118198.
Jun, Z., K. Guoju, and Y. Liu. 2021. “Early hydration heat of calcium sulfoaluminate cement with influences of supplementary cementitious materials and water to binder ratio.” Materials 14 (3): 642. https://doi.org/10.3390/ma14030642.
Ke, G., J. Zhang, S. Xie, and T. Pei. 2020. “Rheological behavior of calcium sulfoaluminate cement paste with supplementary cementitious materials.” Constr. Build. Mater. 243 (May): 118234. https://doi.org/10.1016/j.conbuildmat.2020.118234.
Ma, J., Z. Yu, C. Ni, H. Shi, and X. Shen. 2019. “Effects of limestone powder on the hydration and microstructure development of calcium sulphoaluminate cement under long-term curing.” Constr. Build. Mater. 199 (Feb): 688–695. https://doi.org/10.1016/j.conbuildmat.2018.12.054.
Peiran, L., G. Xiaojian, K. Wang, V. W. Tam, and W. Li. 2019. “Hydration mechanism and early frost resistance of calcium sulfoaluminate cement concrete.” [In Chinese.] Constr. Build. Mater. 239 (Apr): 117862.
Popescu, C. D., M. Muntean, and J. H. Sharp. 2003. “Industrial trial production of low energy belite cement.” Cem. Concr. Compos. 25 (7): 689–693. https://doi.org/10.1016/S0958-9465(02)00097-5.
Qiu, J. L., and W. Guo. 2021. “Effect of retarder and high efficiency water reducing agent compounding on the performance of sulphate aluminate cement.” [In Chinese.] New Build. Mater. 48 (6): 64–68.
Rachid, B., G. Alexandre, and P. Grosseau. 2021. “Influence of polycarboxylate superplasticizer, citric acid and their combination on the hydration and workability of calcium sulfoaluminate cement.” [In Chinese.] Cem. Concr. Res. 147 (Sep): 106513.
Sahu, S., and J. Majiling. 1993. “Phase compatibility in the system CaO-SiO2-Al2O3-Fe2O3-SO3 referred to sulphoaluminate belite cement clinker.” [In Chinese.] Pergamon 23 (6): 1331–1339.
Sanfelix, S. G., J. D. Zea-García, D. Londono-Zuluaga, I. Santacruz, G. Angeles, and A. L. Kjøniksen. 2020. “Hydration development and thermal performance of calcium sulphoaluminate cements containing microencapsulated phase change materials.” Cem. Concr. Res. 132 (Jun): 106039. https://doi.org/10.1016/j.cemconres.2020.106039.
Tambara, L. U. D., M. Cheriaf, J. C. Rocha, A. Palomo, and A. Fernández-Jiménez. 2020. “Effect of alkalis content on calcium sulfoaluminate (CSA) cement hydration.” Cem. Concr. Res. 128 (Feb): 105953. https://doi.org/10.1016/j.cemconres.2019.105953.
Tan, H., Y. Guo, F. Zou, S. Jian, B. Ma, and Z. Zhi. 2017. “Effect of borax on rheology of calcium sulphoaluminate cement paste in the presence of polycarboxylate superplasticizer.” Constr. Build. Mater. 139 (May): 277–285. https://doi.org/10.1016/j.conbuildmat.2017.02.005.
Tang, R., Z. Wang, M. Lan, and S. Cui. 2021. “Compounding effects of citric acid and polycarboxylic acid water reducing agents in high berylite sulfoaluminate cements.” [In Chinese.] J. Chinese Cer. Soc. 49 (5): 1–8.
Thomas, R. J., M. Maguire, A. D. Sorensen, and I. Quezada. 2018. “Calcium sulfoaluminate cement.” [In Chinese.] Concr. Int. 40 (4): 65–69.
Tian, L., H. Fangmei, L. Li, J. Zhu, X. Jiang, and Y. Huang. 2020. “Preparation and properties of sulphoaluminate cement-based foamed concrete with high performance.” [In Chinese.] Constr. Build. Mater. 263 (Dec): 120945.
Wang, P., N. Li, and L. Xu. 2017. “Hydration evolution and compressive strength of calcium sulphoaluminate cement constantly cured over the temperature range of 0 to 80°C.” Cem. Concr. Res. 100 (Oct): 203–213. https://doi.org/10.1016/j.cemconres.2017.05.025.
Wang, Q., S. Li, S. Pan, and X. Kong. 2020. “Influence and mechanism of different retarders on the performance of high belite sulphoaluminate cement.” [In Chinese.] J. Build. Mater. 23 (2): 239–254.
Wang, Y., J. Yu, J. Wang, and X. Guang. 2019. “Effects of aluminum sulfate and quicklime/fluorgypsum ratio on the properties of calcium sulfoaluminate (CSA) cement-based double liquid grouting materials.” Materials 12 (8): 1222. https://doi.org/10.3390/ma12081222.
Xu, L., S. Liu, N. Li, Y. Peng, K. Wu, and P. Wang. 2018. “Retardation effect of elevated temperature on the setting of calcium sulfoaluminate cement clinker.” [In Chinese.] Constr. Build. Mater. 178 (Jul): 112–119.
Xu, L. L., and X. Y. Zhou. 2017. “Effect of gypsum on the hydration characteristics of sulfoaluminate cement.” [In Chinese.] J. Tongji Univ. 45 (6): 885–890.
Zajac, M., J. Skocek, F. Bullerjahn, and M. B. Haha. 2016. “Effect of retarders on the early hydration of calcium-sulpho-aluminate (CSA) type cements.” Cem. Concr. Res. 84 (Jun): 62–75. https://doi.org/10.1016/j.cemconres.2016.02.014.
Zhang, H., R. Zhou, S. Liu, Y. Zhu, S. Wang, J. Wang, and X. Guan. 2021. “Enhanced toughness of ultra-fine sulphoaluminate cement-based hybrid grouting materials by incorporating in-situ polymerization of acrylamide.” Constr. Build. Mater. 292 (Jul): 123421. https://doi.org/10.1016/j.conbuildmat.2021.123421.
Zhang, J., X. Guan, H. Li, and X. Liu. 2017. “Performance and hydration study of ultra-fine sulfoaluminate cement-based double liquid grouting material.” Constr. Build. Mater. 132 (Feb): 262–270. https://doi.org/10.1016/j.conbuildmat.2016.11.135.
Zhang, W. 2020. “Effect of coagulant on properties of sulphoaluminate cement.” [In Chinese.] M.S. thesis, Dept. of Civil Engineering, Yangzhou Univ.
Zhou, H., J. Liu, J. Liu, and C. Li. 2012. “Hydration kinetics process of low alkalinity sulphoaluminate cement and its thermodynamical properties.” Procedia Eng. 27 (Jan): 323–331. https://doi.org/10.1016/j.proeng.2011.12.459.
Zou, D., Z. Zhang, and D. Wang. 2020. “Influence of citric acid and sodium gluconate on hydration of calcium sulfoaluminate cement at various temperatures.” Constr. Build. Mater. 263 (Dec): 120247. https://doi.org/10.1016/j.conbuildmat.2020.120247.

Information & Authors

Information

Published In

Go to Journal of Materials in Civil Engineering
Journal of Materials in Civil Engineering
Volume 34Issue 10October 2022

History

Received: Sep 14, 2021
Accepted: Jan 26, 2022
Published online: Jul 19, 2022
Published in print: Oct 1, 2022
Discussion open until: Dec 19, 2022

Permissions

Request permissions for this article.

Authors

Affiliations

M.S. Candidate, Henan Key Laboratory of Materials on Deep-Earth Engineering, School of Materials Science and Engineering, Henan Polytechnic Univ., Jiaozuo, Henan 454000, China. Email: [email protected]
Haibo Zhang [email protected]
Professor, Henan Key Laboratory of Materials on Deep-Earth Engineering, School of Materials Science and Engineering, Henan Polytechnic Univ., Jiaozuo, Henan 454000, China. Email: [email protected]
M.S. Candidate, Henan Key Laboratory of Materials on Deep-Earth Engineering, School of Materials Science and Engineering, Henan Polytechnic Univ., Jiaozuo, Henan 454000, China. Email: [email protected]
Associate Professor, Henan Key Laboratory of Materials on Deep-Earth Engineering, School of Materials Science and Engineering, Henan Polytechnic Univ., Jiaozuo, Henan 454000, China (corresponding author). ORCID: https://orcid.org/0000-0003-2204-0946. Email: [email protected]

Metrics & Citations

Metrics

Citations

Download citation

If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download.

View Options

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Media

Figures

Other

Tables

Share

Share

Copy the content Link

Share with email

Email a colleague

Share