Technical Papers
Jan 28, 2022

Sustainable Development and Performance Assessment of Clay-Based Geopolymer Bricks Incorporating Fly Ash and Sugarcane Bagasse Ash

Publication: Journal of Materials in Civil Engineering
Volume 34, Issue 4

Abstract

Emission of carbon dioxide (CO2) either from the firing of clay bricks or from cement production, contributes considerably toward global warming. Conversely, the production of bricks is inevitable since a large number of bricks are needed to fulfill the housing sector demand. In this study, silty clay-based geopolymer bricks were produced incorporating fly ash and sugarcane bagasse ash. This was accomplished in two stages: the laboratory phase that comprised of production of cylindrical specimens, and the industrial phase whereby full-size bricks were produced based on the results obtained in the laboratory phase. The silty clay-based geopolymer bricks were developed with lesser energy input, i.e., forming pressure of 7 MPa with curing at ambient temperature. The whole set of mechanical and durability properties of the newly developed geopolymer brick yielded satisfactory results conforming to the standard codes. Scanning electron microscopy (SEM) and X-ray diffraction (XRD) results revealed the coexistence of sodium aluminosilicate gel (N─ A─ S─ H) and calcium aluminosilicate hydrate (C─ A─ S─ H), which led to a dense microstructure resulting in increased mechanical strength and ensuring enhanced durability of the brick structure. The environmental impact assessment confirmed the ecofriendly utilization of sugarcane bagasse ash in combination with fly ash in clay-based geopolymer bricks. The newly developed geopolymer can have a broad range of applications, including wall panel making, jet grouting, deep mixing, mortar for masonry constructions, canal lining, and grouting material used in backfill grouting during shield tunneling.

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Data Availability Statement

Some or all data, models, or code that support the findings of this study are available from the corresponding author upon reasonable request.

Acknowledgments

We are thankful to the team of M/S Punjab Tiles and Candide Global (Pvt. Ltd.) for supporting us by providing the required machinery, i.e., a brick pressing platform in their factory. We wholeheartedly acknowledge the help provided by Mr. Zahid Ullah, in the experimental phase of this research. We also appreciate the support provided by the staff of Concrete Laboratory, Earthquake Engineering Laboratory, Strength of Materials Laboratory and Geotechnical Engineering Laboratory, Civil Engineering Department, University of Engineering and Technology, Lahore, where we performed all kinds of testing involved in this research.

References

ASTM. 2007a. Standard test method for particle-size analysis of soils. ASTM D422–63. West Conshohocken, PA: ASTM.
ASTM. 2007b. Standard test methods for compressive strength of molded soil-cement cylinders. ASTM D1633. West Conshohocken, PA: ASTM.
ASTM. 2012. Standard specification for coal fly ash and raw or calcined natural pozzolan for use in concrete. ASTM C618. West Conshohocken, PA: ASTM.
ASTM. 2014. Standard specification for loadbearing concrete masonry units. ASTM C90. West Conshohocken, PA: ASTM.
ASTM. 2015. Standard test method for length change of hydraulic-cement mortars exposed to a sulfate solution. ASTM C1012/C1012M-15. West Conshohocken, PA: ASTM.
ASTM. 2019. Standard test methods for sampling and testing brick and structural clay tile. ASTM C67. West Conshohocken, PA: ASTM.
Azevedo, A. G. S., and K. Strecker. 2017. “Brazilian fly ash based inorganic polymers production using different alkali activator solutions.” Ceram. Int. 43 (12): 9012–9018. https://doi.org/10.1016/j.ceramint.2017.04.044.
Azevedo, A. G. S., K. Strecker, L. A. Barros, L. F. Tonholo, and C. T. Lombardi. 2019. “Effect of curing temperature, activator solution composition and particle size in Brazilian fly-ash based geopolymer production.” Supplement, Mater. Res. 22 (S1): 1–12. https://doi.org/10.1590/1980-5373-mr-2018-0842.
Bahurudeen, A., D. Kanraj, V. Gokul Dev, and M. Santhanam. 2015. “Performance evaluation of sugarcane bagasse ash blended cement in concrete.” Cem. Concr. Compos. 59 (May): 77–88. https://doi.org/10.1016/j.cemconcomp.2015.03.004.
Bondar, D., C. J. Lynsdale, N. B. Milestone, N. Hassani, and A. A. Ramezanianpour. 2011. “Effect of adding mineral additives to alkali-activated natural pozzolan paste.” Constr. Build. Mater. 25 (6): 2906–2910. https://doi.org/10.1016/j.conbuildmat.2010.12.031.
Chen, C., G. Habert, Y. Bouzidi, and A. Jullien. 2010. “Environmental impact of cement production: Detail of the different processes and cement plant variability evaluation.” J. Cleaner Prod. 18 (5): 478–485. https://doi.org/10.1016/j.jclepro.2009.12.014.
Chusilp, N., C. Jaturapitakkul, and K. Kiattikomol. 2009. “Utilization of bagasse ash as a pozzolanic material in concrete.” Constr. Build. Mater. 23 (11): 3352–3358. https://doi.org/10.1016/j.conbuildmat.2009.06.030.
Cordeiro, G. C., R. D. Toledo Filho, and E. M. R. Fairbairn. 2009a. “Effect of calcination temperature on the pozzolanic activity of sugar cane bagasse ash.” Constr. Build. Mater. 23 (10): 3301–3303. https://doi.org/10.1016/j.conbuildmat.2009.02.013.
Cordeiro, G. C., R. D. Toledo Filho, L. M. Tavares, and E. de Moraes Rego Fairbairn. 2009b. “Ultrafine grinding of sugar cane bagasse ash for application as pozzolanic admixture in concrete.” Cem. Concr. Res. 39 (2): 110–115. https://doi.org/10.1016/j.cemconres.2008.11.005.
Cordeiro, G. C., R. D. Toledo Filho, L. M. Tavares, E. D. M. R. Fairbairn, and S. Hempel. 2011. “Influence of particle size and specific surface area on the pozzolanic activity of residual rice husk ash.” Cem. Concr. Compos. 33 (5): 529–534. https://doi.org/10.1016/j.cemconcomp.2011.02.005.
Davidovits, J. 1994. “Properties of geopolymer cements.” In Vol. 1 of Proc., 1st Int. Conf. on Alkaline Cements and Concretes, 131–149. Kiev, Ukraine: Scientific Research Institute on Binders and Materials, Kiev State Technical Univ.
Davidovits, J. 1999. “Geopolymeric reactions in the economic future of cements and concretes: World-wide mitigation of carbon dioxide emission.” In Vol. 99 of Proc., 2nd Int. Conf. on Geopolymer, edited by J. Davidovits, R. Davidovits, and C. James, 111–121. Saint-Quentin, France: Geopolymer Institute.
Davidovits, J. 2008. Geopolymer chemistry and applications, 145–192. Saint-Quentin, France: Geopolymer Institute.
Deepika, S., G. Anand, A. Bahurudeen, and M. Santhanam. 2017. “Construction products with sugarcane bagasse ash binder.” J. Mater. Civ. Eng. 29 (10): 04017189. https://doi.org/10.1061/(ASCE)MT.1943-5533.0001999.
Delali, A. 2014. Durability of locally-produced burnt clay bricks. Kumasi, Ghana: Kwame Nkrumah Univ. of Science and Technology.
Faria, K. C. P., R. F. Gurgel, and J. N. F. Holanda. 2012. “Recycling of sugarcane bagasse ash waste in the production of clay bricks.” J. Environ. Manage. 101 (Jun): 7–12. https://doi.org/10.1016/j.jenvman.2012.01.032.
Frías, M., E. Villar, and H. Savastano. 2011. “Brazilian sugar cane bagasse ashes from the cogeneration industry as active pozzolans for cement manufacture.” Cem. Concr. Compos. 33 (4): 490–496. https://doi.org/10.1016/j.cemconcomp.2011.02.003.
Hardjito, D., and B. Rangan. 2005. Development and properties of low-calcium fly ash-based geopolymer concrete. Perth, Australia: Faculty of Engineering, Curtin Univ. of Technology.
Hardjito, D., S. E. Wallah, D. M. J. Sumajouw, and B. V. Rangan. 2004. “On the development of fly ash-based geopolymer concrete.” ACI Mater. J. 101 (6): 467–472.
Hegazy, B. E., H. A. Fouad, and A. M. Hassanain. 2012. “Incorporation of water sludge, silica fume, and rice husk ash in brick making.” Adv. Environ. Res. 1 (1): 83–96. https://doi.org/10.12989/aer.2012.1.1.083.
Hendriks, C. A., E. Worrell, D. De Jager, K. Blok, and P. Riemer. 2003. “Emission reduction of greenhouse gases from the cement industry.” In Proc., 4th Int. Conf. on Greenhouse Gas Control Technologies, 939–944. Interlaken, Austria: IEA GHG R&D Programme.
Islam, A., U. J. Alengaram, M. Z. Jumaat, and I. I. Bashar. 2014. “The development of compressive strength of ground granulated blast furnace slag-palm oil fuel ash-fly ash based geopolymer mortar.” Mater. Des. 56 (Apr): 833–841. https://doi.org/10.1016/j.matdes.2013.11.080.
Jiménez-Quero, V. G., F. M. León-Martínez, P. Montes-García, C. Gaona-Tiburcio, and J. G. Chacón-Nava. 2013. “Influence of sugar-cane bagasse ash and fly ash on the rheological behavior of cement pastes and mortars.” Constr. Build. Mater. 40 (Mar): 691–701. https://doi.org/10.1016/j.conbuildmat.2012.11.023.
Lima, S. A., H. Varum, A. Sales, and V. F. Neto. 2012. “Analysis of the mechanical properties of compressed earth block masonry using the sugarcane bagasse ash.” Constr. Build. Mater. 35 (Oct): 829–837. https://doi.org/10.1016/j.conbuildmat.2012.04.127.
Lingling, X., G. Wei, W. Tao, and Y. Nanru. 2005. “Study on fired bricks with replacing clay by fly ash in high volume ratio.” Constr. Build. Mater. 19 (3): 243–247. https://doi.org/10.1016/j.conbuildmat.2004.05.017.
Lippiatt, B. C. 2007. BEES 4.0: Building for environmental and economic sustainability technical manual and user guide. Gaithersburg, MD: NIST.
Liu, X. X., S. L. Shen, Y. S. Xu, and A. Zhou. 2021. “A diffusion model for backfill grout behind shield tunnel lining.” Int. J. Numer. Anal. Methods Geomech. 45 (4): 457–477. https://doi.org/10.1002/nag.3164.
Mehta, A., and R. Siddique. 2016. “An overview of geopolymers derived from industrial by-products.” Constr. Build. Mater. 127 (Nov): 183–198. https://doi.org/10.1016/j.conbuildmat.2016.09.136.
Messina, F., C. Ferone, A. Molino, G. Roviello, F. Colangelo, B. Molino, and R. Cioffi. 2017. “Synergistic recycling of calcined clayey sediments and water potabilization sludge as geopolymer precursors: Upscaling from binders to precast paving cement-free bricks.” Constr. Build. Mater. 133 (Feb): 14–26. https://doi.org/10.1016/j.conbuildmat.2016.12.039.
Mitra, D., and D. Valette. 2017. Environment, human labour, and animal welfare. Geneva: International Labour Office.
More, A. S., A. Tarade, and A. Anant. 2014. “Assessment of suitability of fly ash and rice husk ash burnt clay bricks.” Int. J. Sci. Res. 4 (7): 1–6.
Netinger, I., M. Vracevic, J. Ranogajec, and S. Vucetic. 2014. “Evaluation of brick resistance to freeze/thaw cycles according to indirect procedures.” Gradevinar 66 (3): 197–209. https://doi.org/10.14256/JCE.956.2013.
Nikola, T., S. Marinković, and A. Stojanović. 2017. “Sustainability of the concrete industry: Current trends and future outlook.” Tehnika 72 (1): 38–44. https://doi.org/10.5937/tehnika1701038T.
Panagiotopoulou, C., E. Kontori, T. Perraki, and G. Kakali. 2007. “Dissolution of aluminosilicate minerals and by-products in alkaline media.” J. Mater. Sci. 42 (9): 2967–2973. https://doi.org/10.1007/s10853-006-0531-8.
Phoo-ngernkham, T., P. Chindaprasirt, V. Sata, S. Hanjitsuwan, and S. Hatanaka. 2014. “The effect of adding nano-SiO2 and nano-Al2O3 on properties of high calcium fly ash geopolymer cured at ambient temperature.” Mater. Des. 55 (Mar): 58–65. https://doi.org/10.1016/j.matdes.2013.09.049.
Reddy, B. V. V., and K. S. Jagadish. 2003. “Embodied energy of common and alternative building materials and technologies.” Energy Build. 35 (2): 129–137. https://doi.org/10.1016/S0378-7788(01)00141-4.
Seismic Provisions. 2007. Building code of Pakistan, 303. Islamabad, Pakistan: Ministry of Housing and Works, Government of Pakistan.
Shabaan, W. M., K. Elbaz, J. Yang, B. S. Thomas, X. Shen, L. Li, Y. Du, J. Xie, and L. Li. 2021. “Effect of pozzolan slurries on recycled aggregate concrete: Mechanical and durability performance.” Constr. Build. Mater. 276 (Mar): 121940. https://doi.org/10.1016/j.conbuildmat.2020.121940.
Shen, S. L., P. G. A. Njock, A. Zhou, and H. M. Lyu. 2021. “Dynamic prediction of jet grouted column diameter in soft soil using Bi-LSTM deep learning.” Acta Geotech. 16 (1): 303–315. https://doi.org/10.1007/s11440-020-01005-8.
Shen, S. L., Z. F. Wang, and W. C. Cheng. 2017. “Estimation of lateral displacement induced by jet grouting in clayey soils.” Géotechnique 67 (7): 621–630. https://doi.org/10.1680/jgeot.16.P.159.
Sukmak, P., S. Horpibulsuk, and S. L. Shen. 2013a. “Strength development in clay-fly ash geopolymer.” Constr. Build. Mater. 40 (Mar): 566–574. https://doi.org/10.1016/j.conbuildmat.2012.11.015.
Sukmak, P., S. Horpibulsuk, S. L. Shen, P. Chindaprasirt, and C. Suksiripattanapong. 2013b. “Factors influencing strength development in clay-fly ash geopolymer.” Constr. Build. Mater. 47 (Oct): 1125–1136. https://doi.org/10.1016/j.conbuildmat.2013.05.104.
Temuujin, L., A. Van Riessen, and K. J. D. MacKenzie. 2010. “Preparation and characterisation of fly ash based geopolymer mortars.” Constr. Build. Mater. 24 (10): 1906–1910. https://doi.org/10.1016/j.conbuildmat.2010.04.012.
Torres-Carrasco, M., and F. Puertas. 2015. “Waste glass in the geopolymer preparation. Mechanical and microstructural characterisation.” J. Cleaner Prod. 90 (Mar): 397–408. https://doi.org/10.1016/j.jclepro.2014.11.074.
Turner, L. K., and F. G. Collins. 2013. “Carbon dioxide equivalent (CO2-e) emissions: A comparison between geopolymer and OPC cement concrete.” Constr. Build. Mater. 43 (Jun): 125–130. https://doi.org/10.1016/j.conbuildmat.2013.01.023.
Velasco, P. M., M. P. M. Ortíz, M. A. M. Giró, and L. M. Velasco. 2014. “Fired clay bricks manufactured by adding wastes as sustainable construction material—A review.” Constr. Build. Mater. 63 (Jul): 97–107. https://doi.org/10.1016/j.conbuildmat.2014.03.045.
Wang, Z. F., S. L. Shen, G. Modoni, and A. Zhou. 2020. “Excess pore water pressure caused by the installation of jet grouting columns in clay.” Comput. Geotech. 125 (Sep): 103667. https://doi.org/10.1016/j.compgeo.2020.103667.
Xiao, R., Y. Ma, X. Jiang, M. Zhang, Y. Zhang, Y. Wang, H. Baoshan, and H. Qiang. 2020. “Strength, microstructure, efflorescence behavior and environmental impacts of waste glass geopolymers cured at ambient temperature.” J. Cleaner Prod. 252 (Apr): 119610. https://doi.org/10.1016/j.jclepro.2019.119610.
Xu, H., and J. S. J. Van Deventer. 2000. “Ab initio calculations on the five-membered alumino-silicate framework rings model: Implications for dissolution in alkaline solutions.” Comput. Chem. 24 (3–4): 391–404. https://doi.org/10.1016/S0097-8485(99)00080-7.
Xu, H., and J. S. J. Van Deventer. 2003. “The effect of alkali metals on the formation of geopolymeric gels from alkali-feldspars.” Colloids Surf., A 216 (1–3): 27–44. https://doi.org/10.1016/S0927-7757(02)00499-5.
Yang, J., W. M. K. ShabanElbaz, K. Elbaz, B. S. Thomas, J. Xie, and L. Li. 2020. “Properties of concrete containing strengthened crushed brick aggregate by pozzolan slurry.” Constr. Build. Mater. 247 (Jun): 118612. https://doi.org/10.1016/j.conbuildmat.2020.118612.
Yip, C. K., G. C. Lukey, and J. S. J. Van Deventer. 2005. “The coexistence of geopolymeric gel and calcium silicate hydrate at the early stage of alkaline activation.” Cem. Concr. Res. 35 (9): 1688–1697. https://doi.org/10.1016/j.cemconres.2004.10.042.
Youssef, N., A. Z. Rabenantoandro, Z. Dakhli, F. Hage Chehade, and Z. Lafhaj. 2019. “Environmental evaluation of geopolymer bricks.” In Vol. 281 of Proc., MATEC Web Conf., 03005. Les Ulis, France: Édition Diffusion Presse Sciences.
Zhang, L. 2013. “Production of bricks from waste materials—A review.” Constr. Build. Mater. 47 (Oct): 643–655. https://doi.org/10.1016/j.conbuildmat.2013.05.043.

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Go to Journal of Materials in Civil Engineering
Journal of Materials in Civil Engineering
Volume 34Issue 4April 2022

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Received: Apr 24, 2021
Accepted: Aug 23, 2021
Published online: Jan 28, 2022
Published in print: Apr 1, 2022
Discussion open until: Jun 28, 2022

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Noor Yaseen [email protected]
Graduate Assistant and M.Sc. Student, Dept. of Civil Engineering, Univ. of Engineering and Technology Lahore, Lahore 54890, Pakistan. Email: [email protected]
Associate Professor, Dept. of Civil Engineering, Univ. of Engineering and Technology Lahore, Lahore 54890, Pakistan (corresponding author). ORCID: https://orcid.org/0000-0002-5970-6927. Email: [email protected]
M.Sc. Engineering, Dept. of Civil Engineering, Univ. of Engineering and Technology Lahore, Lahore 54890, Pakistan. ORCID: https://orcid.org/0000-0002-0763-8635. Email: [email protected]
Syed. Ali Rizwan, Ph.D., M.ASCE [email protected]
Professor, Dean School of Engineering, Univ. of Management and Technology, Lahore 54700, Pakistan; formerly, Professor, FAST-NUCES, National Univ. of Computer and Emerging Sciences, Lahore, Pakistan. Email: [email protected]
Muhammad Afzal [email protected]
M.Sc. Engineering, Director Technical/Research, Candide Global (Pvt.) Ltd., New Garden Town, Lahore 54000, Pakistan. Email: [email protected]

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