Investigation of Aging Behavior of Asphalt under Multiple Environmental Conditions
Publication: Journal of Materials in Civil Engineering
Volume 34, Issue 2
Abstract
This work investigated the effects of the aging process on the performance of asphalt binder under multiple environmental conditions based on multitechnique experimental results. The aging process of matrix asphalt binder with the increase of temperature for 96 h, 192 h, and 288 h was simulated by an aging oven. Fourier transform infrared spectroscopy (FTIR) and differential scanning calorimetry (DSC) were used to quantify the microcosmic characteristics of asphalt after aging. The results showed that the aging process of asphalt is an oxidation process, and the oxygen-containing functional groups (C═O and S═O) increased with aging. At the macroscopic level, the changes of adhesion properties and bond strength of asphalt were studied by testing the changes in three major indexes. The penetration and ductility of asphalt decreased, and the softening point increased with aging. The changes of rheological performance were tested by dynamic shear rheometer (DSR) and Brookfield viscometer. Mutual transformation of aromatic phenol, colloid, and asphaltene led to an increase in asphalt viscosity and decrease in workability. Antifatigue performance gradually decreased under the action of load with the extension of time. The elastic properties were finally damaged by fatigue.
Get full access to this article
View all available purchase options and get full access to this article.
Data Availability Statement
Some or all data, models, or code that support the findings of this study are available from the corresponding author upon reasonable request.
Acknowledgments
The authors gratefully acknowledge financial support from the National Natural Science Foundation of China (NSFC) (Grant No. 52008069), Chongqing Postdoctoral Science Foundation (No. cstc2019jcyj-bshX0121), and Chongqing Technology Innovation and Application Development Project (CSTC2019JSCX-MSXM1685).
References
ASTM. 2014. Guide for using fluorescence microscopy to quantify the spread area of fixed cells. ASTM F2998-14. West Conshohocken, PA: ASTM.
Bian, F., Y. Zhao, X. Huang, and Z. Wang. 2010. “Experimental study of water aging on asphalt during service life of pavements.” J. Southeast Univ. 26 (4): 618.
Bocci, E., G. Cerni, and S. Colagrande. 2016. “Mechanical behaviour of asphalt concrete containing C&D recycled materials.” In Proc., 8th RILEM Int. Symp. on Testing and Characterization of Sustainable and Innovative Bituminous Materials. New York: Springer.
Buttlar, W. G., et al. 2014. “Digital image correlation techniques to investigate strain fields and cracking phenomena in asphalt materials.” Mater. Struct. 47 (8): 1373–1390. https://doi.org/10.1617/s11527-014-0362-z.
Cavalli, M. C., M. Zaumanis, E. Mazza, M. N. Partl, and L. D. Poulikakos. 2018. “Aging effect on rheology and cracking behaviour of reclaimed binder with bio-based rejuvenators.” J. Cleaner Prod. 189 (Jul): 88–97. https://doi.org/10.1016/j.jclepro.2018.03.305.
Chen, J., W. Wang, Y. Sun, J. Liu, and B. Xu. 2019. “Low-temperature performance and aging resistance analysis of asphalt binders based on BBR and FT-IR.” J. China Foreign Highway 39 (1): 200–205.
Chen, L., S. Chen, and Z. He. 2016. “Macro aging characteristics of asphalt under heat and light coupling condition.” [In Chinese.] J. Chongqing Jiaotong Univ. (Nat. Sci.) 35 (6): 38–44.
Ding, H., G. Zhou, and H. Wang. 2014. “Influence of thermal-aging on chemical composition of polymer modified asphalt and physical characteristics.” Pet. Asphalt 72 (3): 1–9. https://doi.org/10.1001/jamaneurol.2014.4068.
Ding, Y., B. Huang, and X. Shu. 2016. “Characterizing blending efficiency of plant produced asphalt paving mixtures containing high RAP.” Constr. Build. Mater. 126 (Nov): 172–178. https://doi.org/10.1016/j.conbuildmat.2016.09.025.
Geng, J., Q. Wang, and W. Li. 2013. “Aging behavior of SBS modified asphalt in coupled water—Heat condition.” In Vol. 723 of Innovation and sustainable technology in road and airfield pavement, edited by J. R. Chang and S. R. Yang. Zurich, Switzerland: Trans Tech.
Glover, C. J., R. R. Davison, C. H. Domke, Y. Ruan, P. Juristyarini, and D. B. Knorr. 2001. Development of a new method for assessing asphalt binder performance durability., 1–334. College Station, TX: Texas A&M Transportation Institute.
Haghshenas, H. F., Y. Kim, M. D. Morton, T. Smith, M. Khedmati, and D. F. Haghshenas. 2018. “Effect of softening additives on the moisture susceptibility of recycled bituminous materials using chemical-mechanical-imaging methods.” J. Mater. Civ. Eng. 30 (9): 04018207. https://doi.org/10.1061/(ASCE)MT.1943-5533.0002405.
Haghshenas, H. F., H. Nabizadeh, Y. Kim, and S. R. Kommidi. 2016. Research on high-RAP asphalt mixtures with rejuvenators and WMA additives. Lincoln, NE: Nebraska Dept. of Transportation.
Han, K. 2019. Identification of asphalt aging gene and prediction research of aging law based on omics technology. Shandong, China: Shandong Jianzhu Univ.
He, Z., L. Chen, L. Ran, and X. Wang. 2017. “Feature analysis on performance and molecular structure of asphalt under coupling aging conditions.” [In Chinese.] J. Chang’an Univ. (Nat. Sci. Ed.) 37 (5): 8–14.
Herrington, P. R. 1995. “Thermal decomposition of asphalt sulfoxides.” Fuel 74 (8): 1232–1235. https://doi.org/10.1016/0016-2361(95)00039-8.
Hu, M., G. Sun, D. Sun, Y. Zhang, J. Ma, and T. Lu. 2020a. “Effect of thermal aging on high viscosity modified asphalt binder: Rheological property, chemical composition and phase porphology.” Constr. Build. Mater. 241: 118023. https://doi.org/10.1016/j.conbuildmat.2020.118023.
Hu, Z., H. Zhang, S. Wang, and T. Xu. 2020b. “Thermal-oxidative aging mechanism of asphalt binder based on isothermal thermal analysis at the SARA level.” Constr. Build. Mater. 225 (Sep): 119349. https://doi.org/10.1016/j.conbuildmat.2020.119349.
Jiang, Y., Q. Chen, D. Hou, J. Li, and H. Zhang. 2016. “Analysis of four components of asphalt based on entropy minimization algorithm.” J. Comput. Theor. Nanosci. 13 (2): 1442–1449. https://doi.org/10.1166/jctn.2016.5066.
Li, H., X. Huang, and H. Wang. 2005. “Water aging of asphalt during its service life of pavements.” [In Chinese.] Acta Petrolei Sin.(Pet. Process. Sect.) 21 (4): 75–78.
Liao, Z., and A. Geng. 2001. “Characterization of FT-IR analysis of asphaltenes and its geochemical implications.” [In Chinese.] Geochimica 50 (5): 433.
Little, D. N., D. H. Allen, and A. Bhasin. 2018. “Mastics and mortars.” In Modeling and design of flexible pavements and materials, 237–259. Cham, Switzerland: Springer.
Liu, L., W. Dong, L. Sun, and T. Jiang. 2009. “Ultraviolet radiation aging performance of SBS and SBR modified asphalt.” [In Chinese.] J. Build. Mater. 012 (6): 676.
Luo, L., Y. Lu, and R. Zhang. 2004. Premature failure of asphalt pavement in Sichuan province and its mitigation. Chengdu, China: Southwest Jiaotong Univ.
MOTPRC (Ministry of Transport of the People’s Republic of China). 2011. Standard test methods of bitumen and bituminous mixtures for highway engineering. Beijing: MOTPRC.
Nabizadeh, H., H. F. Haghshenas, Y. R. Kim, and F. T. S. Aragão. 2017. “Effects of rejuvenators on high-RAP mixtures based on laboratory tests of asphalt concrete mixtures and fine aggregate matrix mixtures.” Constr. Build. Mater. 152 (Oct): 65–73. https://doi.org/10.1016/j.conbuildmat.2017.06.101.
Nayak, P., and U. C. Sahoo. 2017. “Rheological, chemical and thermal investigations on an aged binder rejuvenated with two non-edible oils.” [In Chinese.] Road Mater. Pavement Des. 18 (3): 612–629. https://doi.org/10.1080/14680629.2016.1182058.
Petersen, J. C. 1993. “Asphalt oxidation: An overview including a new model for oxidation proposing that physicochemical factors dominate the oxidation kinetics.” Fuel Sci. Technol. Int. 11 (1): 57–87. https://doi.org/10.1080/08843759308916058.
Praticò, F. G., M. Giunta, M. Mistretta, and T. Maria Gulotta. 2020. “Energy and environmental life cycle assessment of sustainable pavement materials and technologies for urban roads.” Sustainability 12 (2): 704. https://doi.org/10.3390/su12020704.
Qian, G., Z. Li, H. Wei, and J. Li. 2018. “The influence of the water content on the asphalt aging.” [In Chinese.] J. Transp. Sci. Eng. 34 (2): 7–11.
Rahmani, E., M. K. Darabi, D. N. Little, and E. A. Masad. 2017. “Constitutive modeling of coupled aging-viscoelastic response of asphalt concrete.” Constr. Build. Mater. 131 (Jan): 1–15. https://doi.org/10.1016/j.conbuildmat.2016.11.014.
Ran, L., and Z. He. 2016. Research on aging mechanism and high performance regenerant of SBS modified asphalt under coupling condition of light, heat, water. Chengdu, China: Chongqing Jiaotong Univ.
Sol-Sanchez, M., F. Moreno-Navarro, G. Garcia-Trave, and M. C. Rubio-Gamez. 2015. “Laboratory study of the long-term climatic deterioration of asphalt mixtures.” Constr. Build. Mater. 88 (Jul): 32–40. https://doi.org/10.1016/j.conbuildmat.2015.03.090.
Tan, Z., Q. Li, and X. B. Ding. 2016. “Asphalt comprehensive aging method of heat-oxygen-water-ultraviolet.” [In Chinese.] J. Changsha Univ. Sci. Technol. Nat. Sci. 13 (2): 25.
Tokede, O. O., A. Whittaker, R. Mankaa, and M. Traverso. 2020. “Life cycle assessment of asphalt variants in infrastructures: The case of lignin in Australian road pavements.” Structures 25 (Jun): 190–199. https://doi.org/10.1016/j.istruc.2020.02.026.
Wang, H., and G. Peng. 2009. Degradation of epoxy wave absorbing materials in different environment condition. Qinhuangdao, China: Yanshan Univ.
Wang, J., J. Yuan, K. W. Kim, and F. Xiao. 2018. “Chemical, thermal and rheological characteristics of composite polymerized asphalts.” Fuel 227 (Sep): 289–299. https://doi.org/10.1016/j.fuel.2018.04.100.
Xu, G., and H. Wang. 2017. “Molecular dynamics study of oxidative aging effect on asphalt binder properties.” Fuel 188 (Jan): 1–10. https://doi.org/10.1016/j.fuel.2016.10.021.
Yang, X., W. An, W. Zhang, L. Chang, and Y. Wang. 2012. “Variation of sunshine hours and related driving forces in Southwestern China.” [In Chinese.] J. Lanzhou Jiaotong Univ. (Nat. Sci. Ed.) 48 (5): 52–60.
Zeng, W., S. Wu, J. Wen, and Z. Chen. 2015. “The temperature effects in aging index of asphalt during UV aging process.” Constr. Build. Mater. 93 (Sep): 1125–1131. https://doi.org/10.1016/j.conbuildmat.2015.05.022.
Zhang, Z., T. Ling, and Z. Leng. 2017. Study on the properties of the warm mix asphalt on plateau regions. Chongqing, China: Chongqing Jiaotong Univ.
Information & Authors
Information
Published In
Copyright
© 2021 American Society of Civil Engineers.
History
Received: Dec 17, 2020
Accepted: Jun 3, 2021
Published online: Nov 17, 2021
Published in print: Feb 1, 2022
Discussion open until: Apr 17, 2022
Authors
Metrics & Citations
Metrics
Citations
Download citation
If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download.
Cited by
- Shifa Xu, Xiaoyu Ren, Hongliang Wu, Hongzhe Liu, Meng Xu, Zixiao Zhu, Meng Ling, Effect of Ultraviolet Aging on Fundamental Properties of Polymer and Crumb Rubber Modified Asphalt and Asphalt Mixtures, Journal of Materials in Civil Engineering, 10.1061/JMCEE7.MTENG-17039, 36, 5, (2024).
- Qiang Li, DongXu Liu, ChaoSheng Yuan, Microscopic Analysis of Aging Characteristics of SBS-Modified Asphalt Based on FTIR Technology, Journal of Materials in Civil Engineering, 10.1061/JMCEE7.MTENG-15491, 35, 11, (2023).
- Liqiang Hu, Wenxing Bai, Yongxing Liu, Kaibiao Nong, Chaosheng Yuan, Chengming Qin, Aging Characteristics of SBS-Modified Asphalt under Thermo-Photo-Oxygen Coupling Conditions, Journal of Materials in Civil Engineering, 10.1061/JMCEE7.MTENG-15423, 35, 10, (2023).
- A. Samea, F.B. Abdelaal, Effect of elevated temperatures on the degradation behaviour of elastomeric bituminous geomembranes, Geotextiles and Geomembranes, 10.1016/j.geotexmem.2022.10.010, 51, 1, (219-232), (2023).
- Jianhua Yang, Zhengqi Zhang, Ying Fang, Jierong Shi, Xinhong Yang, Exploration for Cohesion and Adhesion Characteristics of High Viscosity–Modified Asphalt: Impacts of Composition-Associated Factors and Thermal Aging, Journal of Materials in Civil Engineering, 10.1061/(ASCE)MT.1943-5533.0004491, 34, 11, (2022).
- Yongjie Ding, Danni Li, Yanghui Wang, Wei Wei, Prediction of the Rejuvenator Diffusion Coefficient in Aged Asphalt Based on Free Volume Theory, ACS Sustainable Chemistry & Engineering, 10.1021/acssuschemeng.2c06215, 11, 1, (407-415), (2022).
- Shisong Ren, Xueyan Liu, Sandra Erkens, Peng Lin, Yangming Gao, Multi-component analysis, molecular model construction, and thermodynamics performance prediction on various rejuvenators of aged bitumen, Journal of Molecular Liquids, 10.1016/j.molliq.2022.119463, 360, (119463), (2022).