Enzyme-Induced Carbonate Precipitation Combined with Polyvinyl Alcohol to Solidify Aeolian Sand
Publication: Journal of Materials in Civil Engineering
Volume 33, Issue 12
Abstract
Enzyme-induced carbonate precipitation (EICP) has emerged as a soil reinforcement technique in recent decades. To enhance the durability of EICP-solidified soil, a method of EICP combined with polyvinyl alcohol (PVA) is proposed to improve aeolian sand. A cementation solution for was prepared in the PVA solution. Unconfined compression strength, wind erosion, water erosion, and penetration resistance tests were performed to investigate the effect of EICP with different concentrations of PVA (1%, 2%, 3%, 4%, and 5%) on aeolian sand solidification. The durability of aeolian sand solidified by EICP and 3% PVA was examined through freeze–thaw and dry–wet cycle tests. The results demonstrated that the material precipitated from EICP solution is calcite; and that the presence of PVA can improve significantly the unconfined compressive strength, wind erosion resistance, water erosion resistance, and surface strength of EICP-solidified aeolian sand; and that 3% PVA is enough for sand treatment in practical applications. Additionally, –solidified aeolian sand had high durability to the freeze–thaw and dry–wet cycles. Scanning electron microscopy (SEM) images revealed films with a network structure in the solidified aeolian sand after adding PVA. Combined with the mercury intrusion capillary pressure test, these tests indicated that the improvement of the performance of –solidified sand mainly was due to the fact that the PVA films enhanced cementation between soil particles and between soil particles and calcium carbonate, and because PVA film–wrapped calcium carbonate filled the large-size pores in the soil.
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Data Availability Statement
The data used in this work are available from the corresponding author upon reasonable request.
Acknowledgments
This study was funded by the National Natural Science Foundation of China (No. 51578147) and Science and Technology Department of Ningxia (No. 2020BFG02014).
References
Agrawal, R. P., and S. K. Sharma. 1984. “Effect of triple superphosphate and polyvinyl alcohol on crust strength, soil physical properties and seedling emergence of pearl millet.” Tropical Agric. 61 (4): 269–272.
Almajed, A., H. Khodadadi Tirkolaei, and E. Kavazanjian Jr. 2018. “Baseline investigation on enzyme-induced calcium carbonate precipitation.” J. Geotech. Geoenviron. Eng. 144 (11): 04018081. https://doi.org/10.1061/(ASCE)GT.1943-5606.0001973.
Almajed, A., H. Khodadadi Tirkolaei, E. Kavazanjian, and N. Hamdan. 2019. “Enzyme induced biocementated sand with high strength at low carbonate content.” Sci Rep 9 (1): 1–7. https://doi.org/10.1038/s41598-018-38361-1.
Aydin, K., O. Sivrikaya, and F. Uysal. 2020. “Effects of curing time and freeze–thaw cycle on strength of soils with high plasticity stabilized by waste marble powder.” J. Mater. Cycles Waste Manage. 22 (5): 1459–1474. https://doi.org/10.1007/s10163-020-01035-0.
Braissant, O., G. Cailleau, C. Dupraz, and E. P. Verrecchia. 2003. “Bacterially induced mineralization of calcium carbonate in terrestrial environments: The role of exopolysaccharides and amino acids.” J. Sediment. Res. 73 (3): 485–490. https://doi.org/10.1306/111302730485.
Carmona, J. P. S. F., P. J. V. Oliveira, and L. J. L. Lemos. 2016. “Biostabilization of a sandy soil using enzymatic calcium carbonate precipitation.” Procedia Eng. 143: 1301–1308. https://doi.org/10.1016/j.proeng.2016.06.144.
Chandra, A., and K. Ravi. 2018. “Application of enzyme-induced carbonate precipitation (EICP) to improve the shear strength of different type of soils.” In Problematic soils and geoenvironmental concerns, 617–632. Singapore: Springer.
Chen, R., I. Lee, and L. Zhang. 2015. “Biopolymer stabilization of mine tailings for dust control.” J. Geotech. Geoenviron. Eng. 141 (2): 04014100. https://doi.org/10.1061/(ASCE)GT.1943-5606.0001240.
Chen, W., Z. Dong, Z. Li, and Z. Yang. 1996. “Wind tunnel test of the influence of moisture on the erodibility of loessial sandy loam soils by wind.” J. Arid. Environ. 34 (4): 391–402. https://doi.org/10.1006/jare.1996.0119.
Chepil, W. S., and N. P. Woodruff. 1963. “The physics of wind erosion and its control.” In Vol. 15 of Advances in agronomy, 211–302. New York: Academic Press.
de Vos, J. A. 1996. “Testing compost as an anti wind erosion agent in a wind tunnel.” Soil Technol. 9 (4): 209–221. https://doi.org/10.1016/S0933-3630(96)00017-7.
Dilrukshi, R. A. N., and S. Kawasaki. 2019. “Effect of plant-derived urease-induced carbonate formation on the strength enhancement of sandy soil.” In Ecological wisdom inspired restoration engineering, 93–108. Singapore: Springer.
Edwards, L. M. 2013. “The effects of soil freeze–thaw on soil aggregate breakdown and concomitant sediment flow in Prince Edward Island: A review.” Can. J. Soil Sci. 93 (4): 459–472. https://doi.org/10.4141/cjss2012-059.
Estroff, L. A., L. Addadi, S. Weiner, and A. D. Hamilton. 2004. “An organic hydrogel as a matrix for the growth of calcite crystals.” Org. Biomol. Chem. 2 (1): 137–141. https://doi.org/10.1039/b309731e.
Fujita, Y., F. G. Ferris, R. D. Lawson, F. S. Colwell, and R. W. Smith. 2000. “Subscribed content calcium carbonate precipitation by ureolytic subsurface bacteria.” Geomicrobiol. J. 17 (4): 305–318. https://doi.org/10.1080/782198884.
Gao, Y., X. Tang, J. Chu, and J. He. 2019. “Microbially induced calcite precipitation for seepage control in sandy soil.” Geomicrobiol. J. 36 (4): 366–375. https://doi.org/10.1080/01490451.2018.1556750.
Gatto, L. W. 2000. “Soil freeze–thaw-induced changes to a simulated rill: Potential impacts on soil erosion.” Geomorphology 32 (1–2): 147–160. https://doi.org/10.1016/S0169-555X(99)00092-6.
Ghazavi, M., and M. Roustaie. 2010. “The influence of freeze–thaw cycles on the unconfined compressive strength of fiber-reinforced clay.” Cold Reg. Sci. Technol. 61 (2–3): 125–131. https://doi.org/10.1016/j.coldregions.2009.12.005.
Hamdan, N., and E. Kavazanjian Jr. 2016. “Enzyme-induced carbonate mineral precipitation for fugitive dust control.” Géotechnique 66 (7): 546–555. https://doi.org/10.1680/jgeot.15.P.168.
Hamdan, N., E. Kavazanjian Jr., and S. O’Donnell. 2013. “Carbonate cementation via plant derived urease.” In Proc., 18th Int. Conf. on Soil Mechanics and Geotechnical Engineering, 2–6. Paris: Presses des Ponts.
Hamdan, N., Z. Zhao, M. Mujica, E. Kavazanjian Jr., and X. He. 2016. “Hydrogel-assisted enzyme-induced carbonate mineral precipitation.” J. Mater. Civ. Eng. 28 (10): 04016089. https://doi.org/10.1061/(ASCE)MT.1943-5533.0001604.
Hamed Khodadadi, T., E. Kavazanjian, L. van Paassen, and J. DeJong. 2017. “Bio-grout materials: A review.” In Grouting 2017, 1–12. Reston, VA: ASCE.
Javadi, N., H. Khodadadi, N. Hamdan, and E. Kavazanjian Jr. 2018. “EICP treatment of soil by using urease enzyme extracted from watermelon seeds.” In IFCEE 2018, 115–124. Reston, VA: ASCE.
Jiang, N.-J., C.-S. Tang, L.-Y. Yin, Y.-H. Xie, and B. Shi. 2019. “Applicability of microbial calcification method for sandy-slope surface erosion control.” J. Mater. Civ. Eng. 31 (11): 04019250. https://doi.org/10.1061/(ASCE)MT.1943-5533.0002897.
Kade, A., and S. D. Warren. 2002. “Soil and plant recovery after historic military disturbances in the Sonoran Desert, USA.” Arid Land Res. Manage. 16 (3): 231–243. https://doi.org/10.1080/153249802760284784.
Kavazanjian, E., and N. Hamdan. 2015. “Enzyme induced carbonate precipitation (EICP) columns for ground improvement.” In IFCEE 2015, 2252–2261. Reston, VA: ASCE.
Konrad, J. M. 1989. “Physical processes during freeze-thaw cycles in clayey silts.” Cold Reg. Sci. Technol. 16 (3): 291–303. https://doi.org/10.1016/0165-232X(89)90029-3.
Kukal, S. S., M. Kaur, S. S. Bawa, and N. Gupta. 2007. “Water-drop stability of PVA-treated natural soil aggregates from different land uses.” Catena 70 (3): 475–479. https://doi.org/10.1016/j.catena.2006.11.013.
Lal, R. 2000. “Soil management in the developing countries.” Soil Sci. 165 (1): 57–72. https://doi.org/10.1097/00010694-200001000-00008.
Li, X.-Y., L.-Y. Liu, and J.-H. Wang. 2004. “Wind tunnel simulation of aeolian sandy soil erodibility under human disturbance.” Geomorphology 59 (1–4): 3–11. https://doi.org/10.1016/j.geomorph.2003.09.001.
Li, Y., J. Cui, T. Zhang, T. Okuro, and S. Drake. 2009. “Effectiveness of sand-fixing measures on desert land restoration in Kerqin Sandy Land, northern China.” Ecol. Eng. 35 (1): 118–127. https://doi.org/10.1016/j.ecoleng.2008.09.013.
Liu, K.-W., N.-J. Jiang, J.-D. Qin, Y.-J. Wang, C.-S. Tang, and X.-L. Han. 2020. “An experimental study of mitigating coastal sand dune erosion by microbial- and enzymatic-induced carbonate precipitation.” Acta Geotech. 16 (2): 467–480. https://doi.org/10.1007/s11440-020-01046-z.
Miao, L., L. Wu, and X. Sun. 2020a. “Enzyme-catalysed mineralisation experiment study to solidify desert sands.” Sci. Rep. 10 (1): 1–12.
Miao, L., L. Wu, X. Sun, X. Li, and J. Zhang. 2020b. “Method for solidifying desert sands with enzyme-catalysed mineralization.” Land Degradation Dev. 31 (11): 1317–1324. https://doi.org/10.1002/ldr.3499.
Mujah, D., L. Cheng, and M. A. Shahin. 2019. “Microstructural and geomechanical study on biocemented sand for optimization of MICP process.” J. Mater. Civ. Eng. 31 (4): 04019025. https://doi.org/10.1061/(ASCE)MT.1943-5533.0002660.
Nafisi, A., S. Safavizadeh, and B. M. Montoya. 2019. “Influence of microbe and enzyme-induced treatments on cemented sand shear response.” J. Geotech. Geoenviron. Eng. 145 (9): 06019008. https://doi.org/10.1061/(ASCE)GT.1943-5606.0002111.
Neupane, D., H. Yasuhara, and N. Kinoshita. 2015. “Evaluation of enzyme mediated calcite grouting as a possible soil improvement technique.” In Proc., 14th Int. Conf. of Int. Association for Computer Methods and Recent Advances in Geomechanics, 2014 (IACMAG 2014): Computer Methods and Recent Advances in Geomechanics, 1169–1172. London: Taylor & Francis.
Oades, J. M. 1976. “Prevention of crust formation in soils by poly(vinyl alcohol).” Soil Res. 14 (2): 139–148. https://doi.org/10.1071/SR9760139.
Powers, M. C. 1953. “A new roundness scale for sedimentary particles.” J. Sediment. Res. 23 (2): 117–119.
Qi, J., W. Ma, and C. Song. 2008. “Influence of freeze–thaw on engineering properties of a silty soil.” Cold Reg. Sci. Technol. 53 (3): 397–404. https://doi.org/10.1016/j.coldregions.2007.05.010.
Refaei, M., M. G. Arab, and M. Omar. 2020. “Sandy soil improvement through biopolymer assisted EICP.” In Proc., Geo-Congress 2020: Foundations, Soil Improvement, and Erosion, 612–619. Reston, VA: ASCE.
Sen, K. K., P. B. S. Bhadoria, and B. Datta. 1995. “Influence of soil conditioners on soil physical properties and maize growth.” Tropical Agric. 72 (1): 23–27.
Song, J. Y., Y. Sim, J. Jang, W.-T. Hong, and T. S. Yun. 2019. “Near-surface soil stabilization by enzyme-induced carbonate precipitation for fugitive dust suppression.” Acta Geotech. 15 (7): 1967–1980.
Tang, C.-S., Y.-J. Cui, B. Shi, A.-M. Tang, and N. An. 2016. “Effect of wetting-drying cycles on soil desiccation cracking behavior.” In Vol. 9 of Proc., E3S Web of Conf., 12003. Paris: EDP Sciences.
Tang, L. 1986. “A study of the quantitative relationship between strength and pore-size distribution of porous materials.” Cem. Concr. Res. 16 (1): 87–96. https://doi.org/10.1016/0008-8846(86)90072-4.
Thong, C. C., D. C. L. Teo, and C. K. Ng. 2016. “Application of polyvinyl alcohol (PVA) in cement-based composite materials: A review of its engineering properties and microstructure behavior.” Constr. Build. Mater. 107 (Mar): 172–180. https://doi.org/10.1016/j.conbuildmat.2015.12.188.
Van Driessche, A. E. S., M. Kellermeier, L. G. Benning, and D. Gebauer, eds. 2016. New perspectives on mineral nucleation and growth: From solution precursors to solid materials. Cham, Switzerland: Springer.
Wang, T., P. Li, Z. Ren, G. Xu, Z. Li, Y. Yang, S. Tang, and J. Yao. 2017. “Effects of freeze-thaw on soil erosion processes and sediment selectivity under simulated rainfall.” J. Arid Land 9 (2): 234–243. https://doi.org/10.1007/s40333-017-0009-3.
Wang, X., H. Zhan, J. Wang, and P. Li. 2019. “On the mechanical damage to tailings sands subjected to dry–wet cycles.” Bull. Eng. Geol. Environ. 78 (6): 4647–4657. https://doi.org/10.1007/s10064-018-1427-y.
Wischmeier, W. H., and D. D. Smith. 1978. Predicting rainfall erosion losses: A guide to conservation planning. New Delhi, India: Dept. of Agriculture, Science and Education Administration.
Yang, J., F. Wang, L. Fang, and T. Tan. 2007. “Synthesis, characterization and application of a novel chemical sand-fixing agent-poly(aspartic acid) and its composites.” Environ. Pollut. 149 (1): 125–130. https://doi.org/10.1016/j.envpol.2006.12.021.
Yasuhara, H., K. Hayashi, and M. Okamura. 2011. “Evolution in mechanical and hydraulic properties of calcite-cemented sand mediated by biocatalyst.” In Proc., Geo-Frontiers 2011: Advances in Geotechnical Engineering, 3984–3992. Reston, VA: ASCE.
Yin, G., Q. Zhang, W. Wang, Y. Chen, W. Geng, and H. Liu. 2012. “Experimental study on the mechanism effect of seepage on microstructure of tailings.” Saf. Sci. 50 (4): 792–796. https://doi.org/10.1016/j.ssci.2011.08.032.
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Published In
Journal of Materials in Civil Engineering
Volume 33 • Issue 12 • December 2021
Copyright
© 2021 American Society of Civil Engineers.
History
Received: Oct 27, 2020
Accepted: May 5, 2021
Published online: Oct 4, 2021
Published in print: Dec 1, 2021
Discussion open until: Mar 4, 2022
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