Technical Papers
Mar 29, 2021

Rice-Straw Ash as a Potential Supplementary Cementitious Material: Influence of Thermochemical Conversion on Its Properties

Publication: Journal of Materials in Civil Engineering
Volume 33, Issue 6

Abstract

Agro-waste ashes can be used as supplementary cementitious materials in concrete. Although many studies have been reported on the use of rice husk ash as a pozzolan, only limited studies are attempted on the use of rice-straw ash in concrete. The composition of rice straw and the influence of thermochemical processing on the amorphous nature and microstructure of rice-straw ash are reported in this study. Moreover, compressive strength, water penetration test, and rapid chloride permeability tests were conducted for rice-straw ash blended concrete. Results from the study indicate that rice-straw ash obtained from pyrolysis temperatures up to 700°C were amorphous and contained reactive silica. From considerations of strength, workability, and durability, 10% rice-straw ash is observed to be the optimum level of replacement. Rice-straw ash blended concrete with 20% replacement level exhibited better performance against water penetration and chloride ingress than control concrete.

Get full access to this article

View all available purchase options and get full access to this article.

Data Availability Statement

Some or all data, models, or code that support the findings of this study are available from the corresponding author upon reasonable request.

References

Abou-Sekkina, M. M., R. M. Issa, A. E. D. M. Bastawisy, and W. A. El-Helece. 2010. “Characterization and evaluation of thermodynamic parameters for Egyptian heap fired rice straw ash (RSA).” Int. J. Chem. 2 (1): 81–88. https://doi.org/10.5539/ijc.v2n1p81.
Anala, R., and P. Nambisan. 2015. “Study of morphology and chemical composition of phytoliths on the surface of paddy straw.” Paddy Water Environ. 13 (4): 521–527. https://doi.org/10.1007/s10333-014-0468-5.
Appari, S., V. M. Janardhanan, R. Bauri, and S. Jayanti. 2014. “Deactivation and regeneration of Ni catalyst during steam reforming of model biogas: An experimental investigation.” Int. J. Hydrogen Energy 39 (1): 297–304. https://doi.org/10.1016/j.ijhydene.2013.10.056.
ASTM. 2015. Standard test method for compositional analysis by thermogravimetry. West Conshohocken, PA: ASTM.
ASTM. 2019. Standard test method for electrical indication of concrete’s ability to resist chloride ion penetration. West Conshohocken, PA: ASTM.
Ataie, F. F., and K. A. Riding. 2013. “Thermochemical pretreatments for agricultural residue ash production for concrete.” J. Mater. Civ. Eng. 25 (11): 1703–1711. https://doi.org/10.1061/(ASCE)MT.1943-5533.0000721.
Ataie, F. F., and K. A. Riding. 2016. “Influence of agricultural residue ash on early cement hydration and chemical admixtures adsorption.” Constr. Build. Mater. 106 (Mar): 274–281. https://doi.org/10.1016/j.conbuildmat.2015.12.091.
Athira, G., A. Bahurudeen, and S. Appari. 2019. “Sustainable alternatives to carbon intensive paddy field burning in India: A framework for cleaner production in agriculture, energy, and construction industries.” J. Cleaner Prod. 236 (Nov): 117598. https://doi.org/10.1016/j.jclepro.2019.07.073.
Bharadwaj, A., Y. Wang, S. Sridhar, and V. S. Arunachalam. 2004. “Pyrolysis of rice husk.” Curr. Sci. 87 (7): 981–986.
Binod, P., R. Sindhu, R. R. Singhania, S. Vikram, L. Devi, S. Nagalakshmi, N. Kurien, R. K. Sukumaran, and A. Pandey. 2010. “Bioethanol production from rice straw: An overview.” Bioresour. Technol. 101 (13): 4767–4774. https://doi.org/10.1016/j.biortech.2009.10.079.
BIS (Bureau of Indian Standards). 2004. Method of tests for strength of concrete. Berlin: BIS.
Bryś, A., J. Bryś, E. Ostrowska-Ligęza, A. Kaleta, K. Górnicki, S. Głowacki, and P. Koczoń. 2016. “Wood biomass characterization by DSC or FT-IR spectroscopy.” J. Therm. Anal. Calorim. 126 (1): 27–35. https://doi.org/10.1007/s10973-016-5713-2.
Cao, Y., and H. Tan. 2004. “Structural characterization of cellulose with enzymatic treatment.” J. Mol. Struct. 705 (1–3): 189–193. https://doi.org/10.1016/j.molstruc.2004.07.010.
Chen, H., W. Zhao, and N. Liu. 2011. “Thermal analysis and decomposition kinetics of Chinese forest peat under nitrogen and air atmospheres.” In Energy and fuels, 797–803. Washington, DC: American Chemical Society.
Coats, A. W., and J. P. Redfern. 1964. “Kinetic parameters from thermogravimetric data.” Nature 201 (4914): 68–69. https://doi.org/10.1038/201068a0.
Dhyani, V., and T. Bhaskar. 2018. “A comprehensive review on the pyrolysis of lignocellulosic biomass.” Renewable Energy 129 (Dec): 695–716. https://doi.org/10.1016/j.renene.2017.04.035.
DIN (Deutsches Institut für Normung). 1991. German standard for determination of permeability of concrete. Berlin: DIN.
Doyle, C. D. 1961. “Kinetic analysis of thermogravimetric data.” J. Appl. Polym. Sci. 5 (15): 285–292. https://doi.org/10.1002/app.1961.070051506.
Gopinath, A., A. Bahurudeen, S. Appari, and P. Nanthagopalan. 2018. “A circular framework for the valorisation of sugar industry wastes: Review on the industrial symbiosis between sugar, construction and energy industries.” J. Cleaner Prod. 203 (12): 89–108. https://doi.org/10.1016/j.jclepro.2018.08.252.
Jenkins, B., L. Baxter, T. Miles, and T. Miles. 1998. “Combustion properties of biomass.” Fuel Process. Technol. 54 (1–3): 17–46. https://doi.org/10.1016/S0378-3820(97)00059-3.
Jindo, K., H. Mizumoto, Y. Sawada, M. A. Sanchez-Monedero, and T. Sonoki. 2014. “Physical and chemical characterization of biochars derived from different agricultural residues.” Biogeosciences 11 (23): 6613–6621. https://doi.org/10.5194/bg-11-6613-2014.
Ma, Z., J. Wang, Y. Yang, Y. Zhang, C. Zhao, Y. Yu, and S. Wang. 2018. “Comparison of the thermal degradation behaviors and kinetics of palm oil waste under nitrogen and air atmosphere in TGA-FTIR with a complementary use of model-free and model-fitting approaches.” J. Anal. Appl. Pyrolysis 134 (Sep): 12–24. https://doi.org/10.1016/j.jaap.2018.04.002.
Nelson, M. L., and R. T. O’Connor. 1964. “Relation of certain infrared bands to cellulose crystallinity and crystal lattice type. Part II. A new infrared ratio for estimation of crystallinity in celluloses I and II.” J. Appl. Polym. Sci. 8 (3): 1325–1341. https://doi.org/10.1002/app.1964.070080323.
Nybacka, L. 2016. Fourier transform infrared spectroscopy of glucose. Uppsala, Sweden: Fourier Transform Infrared Spectroscopy.
Ounas, A., A. Aboulkas, K. El harfi, A. Bacaoui, and A. Yaacoubi. 2011. “Pyrolysis of olive residue and sugar cane bagasse: Non-isothermal thermogravimetric kinetic analysis.” Bioresour. Technol. 102 (24): 11234–11238. https://doi.org/10.1016/j.biortech.2011.09.010.
Piperno, D. R. 2006. Phytoliths: A comprehensive guide for archaeologists and paleoecologists. Lanham, MD: Rowman Altamira.
Ramasamy, V. 2012. “Compressive strength and durability properties of rice husk ash concrete.” J. Civ. Eng. 16 (1): 93–102. https://doi.org/10.1007/s12205-012-0779-2.
Roselló, J., L. Soriano, M. P. Santamarina, J. L. Akasaki, J. Monzó, and J. Payá. 2017. “Rice straw ash: A potential pozzolanic supplementary material for cementing systems.” Ind. Crops Prod. 103 (Sep): 39–50. https://doi.org/10.1016/j.indcrop.2017.03.030.
Shi, J., D. Xing, and J. Li. 2012. “FTIR studies of the changes in wood chemistry from wood forming tissue under inclined treatment.” Energy Procedia 16 (Jan): 758–762. https://doi.org/10.1016/j.egypro.2012.01.122.
Traoré, M., J. Kaal, and A. Martínez Cortizas. 2016. “Application of FTIR spectroscopy to the characterization of archeological wood.” Spectrochim. Acta, Part A 153 (Jan): 63–70. https://doi.org/10.1016/j.saa.2015.07.108.
USDA. 2020. World agricultural production. Washington, DC: USDA.
Varma, A. K., and P. Mondal. 2016. “Physicochemical characterization and pyrolysis kinetic study of sugarcane bagasse using thermogravimetric analysis.” J. Energy Resour. Technol. 138 (5): 052205. https://doi.org/10.1115/1.4032729.
Yadav, R. S. 2019. “Stubble burning: A problem for the environment, agriculture and humans.” Down To Earth. Accessed June 4, 2019. https://www.downtoearth.org.in/blog/agriculture/stubble-burning-a-problem-for-the-environment-agriculture-and-humans-64912.
Yang, H., R. Yan, H. Chen, D. H. Lee, and C. Zheng. 2007. “Characteristics of hemicellulose, cellulose and lignin pyrolysis.” Fuel 86 (12–13): 1781–1788. https://doi.org/10.1016/j.fuel.2006.12.013.

Information & Authors

Information

Published In

Go to Journal of Materials in Civil Engineering
Journal of Materials in Civil Engineering
Volume 33Issue 6June 2021

History

Received: Jul 10, 2020
Accepted: Oct 27, 2020
Published online: Mar 29, 2021
Published in print: Jun 1, 2021
Discussion open until: Aug 29, 2021

Permissions

Request permissions for this article.

Authors

Affiliations

Postdoctoral Researcher, Dept. of Civil Engineering, Indian Institute of Technology Bombay, Mumbai 400076, India. ORCID: https://orcid.org/0000-0001-6746-3198. Email: [email protected]
Assistant Professor, Dept. of Civil Engineering, Birla Institute of Technology and Science Pilani, Hyderabad Campus, Telangana 500078, India (corresponding author). ORCID: https://orcid.org/0000-0002-8300-2321. Email: [email protected]
Srinivas Appari [email protected]
Assistant Professor, Dept. of Chemical Engineering, Birla Institute of Technology and Science Pilani, Pilani Campus, Rajasthan 333031, India. Email: [email protected]

Metrics & Citations

Metrics

Citations

Download citation

If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download.

Cited by

View Options

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Media

Figures

Other

Tables

Share

Share

Copy the content Link

Share with email

Email a colleague

Share