Technical Papers
Jan 13, 2020

Effect of Nano-SiO2 on the Mechanical Properties, Microstructure, and Hydration Process of Cementitious Materials Incorporating Hydrophobic Admixture

Publication: Journal of Materials in Civil Engineering
Volume 32, Issue 3

Abstract

In this study, the effect of nano-SiO2 on the mechanical properties, microstructure, and hydration process of cementitious materials incorporating hydrophobic admixture (CM-HA) was studied through mechanical strength and hydration heat tests, x-ray diffraction (XRD), a scanning electron microscope (SEM), and mercury intrusion porosimetry (MIP). The results showed that the addition of hydrophobic admixture reduced the compressive strength of cement paste by about 18% in 28 days, and the addition of nano-SiO2 increased the strength of cement paste incorporating hydrophobic admixture by about 20% after 7 days, which indicated that the mechanical properties and strength development of CM-HA could be significantly improved by nano-SiO2 due to the nucleus effect, hydration activity, and nano-filling function, although hydrophobic admixture was not beneficial for the strength development due to the delay for hydration process. Results also indicated that nano-SiO2 could significantly accelerate the hydration rate and reduce the porosity of cement, especially the porosity of macropores. This study provided a new research method for alleviating the adverse effects of hydrophobic admixture on the mechanical properties and durability of concrete and implemented the application of nano-materials in hydrophobic materials.

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References

Al-Kheetan, M. J., M. M. Rahman, and D. A. Chamberlain. 2018. “A novel approach of introducing crystalline protection material and curing agent in fresh concrete for enhancing hydrophobicity.” Constr. Build. Mater. 160 (Jan): 644–652. https://doi.org/10.1016/j.conbuildmat.2017.11.108.
Chang, T. P., J. Y. Shih, K. M. Yang, and T. C. Hsiao. 2007. “Material properties of portland cement paste with nano-montmorillonite.” J. Mater. Sci. 42 (17): 7478–7487. https://doi.org/10.1007/s10853-006-1462-0.
Chen, H., P. Feng, and Y. Du. 2018. “The effect of superhydrophobic nano-silica particles on the transport and mechanical properties of hardened cement pastes.” Constr. Build. Mater. 182 (Sep): 620–628. https://doi.org/10.1016/j.conbuildmat.2018.06.146.
China National Standards. 2007. Common portland cement. [In Chinese.] GB175. Beijing: China National Standards.
China National Standards. 2008. Test methods for heat of hydration of cement. [In Chinese.] GB/T12959. Beijing: China National Standards.
China National Standards. 2011. Specification for mix proportion design of cement soil. [In Chinese.] JGJ T233. Beijing: China National Standards.
Corcione, C. E., R. Striani, C. Capone, M. Molfetta, S. Vendetta, and M. Frigione. 2018. “Preliminary study of the application of a novel hydrophobic photo-polymerizable nano-structured coating on concrete substrates.” Prog. Org. Coat. 121 (Aug): 182–189. https://doi.org/10.1016/j.porgcoat.2018.04.024.
Fernandez-Jimenez, A., F. Puertas, and A. Arteaga. 1998. “Determination of kinetic equations of alkaline activation of blast furnace slag by means of calorimetric data.” J. Therm. Anal. Calorim. 52 (3): 945–955. https://doi.org/10.1023/A:1010172204297.
Hosseini, P., M. Abolhasani, F. Mirzaei, M. R. K. Anbaran, Y. Khaksari, and H. Famili. 2018. “Influence of two types of nanosilica hydrosols on short-term properties of sustainable white portland cement mortar.” J. Mater. Civ. Eng. 30 (2): 04017289. https://doi.org/10.1061/(ASCE)MT.1943-5533.0002152.
Jia, L., C. Shi, X. Pan, J. Zhang, and L. Wu. 2016. “Effects of inorganic surface treatment on water permeability of cement-based materials.” Cem. Concr. Compos. 67 (3): 85–92. https://doi.org/10.1016/j.cemconcomp.2016.01.002.
Jo, B., C. Kim, G. Tae, and J. Park. 2007. “Characteristics of cement mortar with nano-SiO2 particles.” Constr. Build. Mater. 21 (6): 1351–1355. https://doi.org/10.1016/j.conbuildmat.2005.12.020.
Kafi, M. A., A. Sadeghi-Nik, A. Bahari, A. Sadeghi-Nik, and E. Mirshafiei. 2016. “Microstructural characterization and mechanical properties of cementitious mortar containing montmorillonite nanoparticles.” J. Mater. Civ. Eng. 28 (12): 04016155. https://doi.org/10.1061/(ASCE)MT.1943-5533.0001671.
Knudsen, T. 1984. “The dispersion model for hydration of portland cement I. General concepts.” Cem. Concr. Res. 14 (5): 622–630. https://doi.org/10.1016/0008-8846(84)90024-3.
Krstulović, R., and P. Dabić. 2000. “A conceptual model of the cement hydration process.” Cem. Concr. Res. 30 (5): 693–698. https://doi.org/10.1016/S0008-8846(00)00231-3.
Kutanaei, S. S., and A. J. Choobbasti. 2016. “Experimental study of combined effects of fibers and nanosilica on mechanical properties of cemented sand.” J. Mater. Civ. Eng. 28 (6): 06016001. https://doi.org/10.1061/(ASCE)MT.1943-5533.0001521.
Li, H., H. G. Xiao, J. Yuan, and J. Ou. 2004. “Microstructure of cement mortar with nano-particles.” Composites Part B 35 (2): 185–189. https://doi.org/10.1016/S1359-8368(03)00052-0.
Ltifi, M., A. Guefrech, P. Mounanga, and A. Khelidj. 2011. “Experimental study of the effect of addition of nano-silica on the behaviour of cement mortars mounir.” Procedia Eng. 10 (Jan): 900–905. https://doi.org/10.1016/j.proeng.2011.04.148.
Mehta, P. K. 1997. “Durability—Critical issues for the future.” Concr. Int. 19 (7): 27–33.
Meng, T., Y. Yu, X. Qian, S. Zhan, and K. Qian. 2012. “Effect of nano-TiO2 on the mechanical properties of cement mortar.” Constr. Build. Mater. 29 (3): 241–245. https://doi.org/10.1016/j.conbuildmat.2011.10.047.
Meng, T., Y. Yu, and Z. J. Wang. 2017. “Effect of nano-CaCO3 slurry on the mechanical properties and micro-structure of concrete with and without fly ash.” Composites Part B: Eng. 117 (May): 124–129. https://doi.org/10.1016/j.compositesb.2017.02.030.
Rai, S., and S. Tiwari. 2018. “Nano silica in cement hydration.” Mater. Today: Proc. 5 (3): 9196–9202. https://doi.org/10.1016/j.matpr.2017.10.044.
Rupasinghe, M., R. San Nicolas, P. Mendis, M. Sofi, and T. Ngo. 2017. “Investigation of strength and hydration characteristics in nano-silica incorporated cement paste.” Cem. Concr. Compos. 80 (Jul): 17–30. https://doi.org/10.1016/j.cemconcomp.2017.02.011.
Sanchez, F., and K. Sobolev. 2010. “Nanotechnology in concrete—A review.” Constr. Build. Mater. 24 (11): 2060–2071. https://doi.org/10.1016/j.conbuildmat.2010.03.014.
Schutter, G. D. 1999. “Hydration and temperature development of concrete made with blast-furnace slag cement.” Cem. Concr. Res. 29 (1): 143–149. https://doi.org/10.1016/S0008-8846(98)00229-4.
Schutter, G. D. 2002. “Fundamental study of early age concrete behaviour as a basis for durable concrete structures.” Mater. Struct. 35 (1): 15–21. https://doi.org/10.1007/BF02482085.
Shaikh, F. U. A., and S. W. M. Supit. 2016. “Effects of superplasticizer types and mixing methods of nanoparticles on compressive strengths of cement pastes.” J. Mater. Civ. Eng. 28 (2): 06015008. https://doi.org/10.1061/(ASCE)MT.1943-5533.0001373.
Shekari, A. H., and M. S. Razzaghi. 2011. “Influence of nano particles on durability and mechanical properties of high performance concrete.” Procedia Eng. 14 (2259): 3036–3041. https://doi.org/10.1016/j.proeng.2011.07.382.
Sonebi, M., M. T. Bassuoni, J. Kwasny, and A. K. Amanuddin. 2015. “Effect of nanosilica on rheology, fresh properties, and strength of cement-based grouts.” J. Mater. Civ. Eng. 27 (4): 04014145. https://doi.org/10.1061/(ASCE)MT.1943-5533.0001080.
Subbiah, K., D. J. Park, and Y. S. Lee. 2018. “Development of water-repellent cement mortar using silane enriched with nanomaterials.” Prog. Org. Coat. 125 (Dec): 48–60. https://doi.org/10.1016/j.porgcoat.2018.08.021.
Yu, J., H. Li, C. K. Y. Leung, X. Lin, J. Y. K. Lam, and I. M. L. Sham. 2017. “Matrix design for waterproof engineered cementitious composites (eccs).” Constr. Build. Mater. 139 (May): 438–446. https://doi.org/10.1016/j.conbuildmat.2017.02.076.
Zhang, P., C. Liu, and Q. Li. 2011. “Application of gray relational analysis for chloride permeability and freeze-thaw resistance of high-performance concrete containing nanoparticles.” J. Mater. Civ. Eng. 23 (12): 1760–1763. https://doi.org/10.1061/(ASCE)MT.1943-5533.0000332.

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Go to Journal of Materials in Civil Engineering
Journal of Materials in Civil Engineering
Volume 32Issue 3March 2020

History

Received: Oct 7, 2018
Accepted: Aug 26, 2019
Published online: Jan 13, 2020
Published in print: Mar 1, 2020
Discussion open until: Jun 13, 2020

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Songsong Lian [email protected]
Ph.D. Candidate, College of Civil Engineering and Architecture, Zhejiang Univ., 866 Yuhangtang Rd., Xihu District, Hangzhou 310058, China. Email: [email protected]
Associate Professor, College of Civil Engineering and Architecture, Zhejiang Univ., 866 Yuhangtang Rd., Xihu District, Hangzhou 310058, China (corresponding author). ORCID: https://orcid.org/0000-0002-4355-990X. Email: [email protected]
Menghua Wang [email protected]
Master, Zhejiang Electric Power Design Institute Co. Ltd., 68 Gucui Rd., Xihu District, Hangzhou 310012, China. Email: [email protected]
Hongming Yu [email protected]
Master Student, College of Civil Engineering and Architecture, Zhejiang Univ., 866 Yuhangtang Rd., Xihu District, Hangzhou 310058, China. Email: [email protected]

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