Technical Papers
May 23, 2019

Effects of Alumina as an Effective Constituent of Metakaolin on Properties of Magnesium Phosphate Cements

Publication: Journal of Materials in Civil Engineering
Volume 31, Issue 8

Abstract

The main interest of this research investigation is to explore the effects of the Al2O3 proportion present in metakaolin (MK) on the mechanical properties of magnesium phosphate cement (MPC). Different contents of MK and Al2O3 were used to replace magnesium to prepare magnesium phosphate cement and some properties, such as setting time, compressive strength, flexural strength, and bonding strength, were tested in this paper. Experimental results showed that the presence of MK and alumina could decrease the exothermic reaction intensity of MPC, and resulted in extending setting time. The addition of MK can improve the compressive strength and flexural strength of MPC; meanwhile, the rate of flexural strength increasing with MK addition was lower than that of the compressive strength. It was also found that the bonding strength of MPC-containing MK and alumina was superior to the control mortar mixture. In addition, the improvement mechanism was discussed based on the microanalysis of X-ray diffraction (XRD), scanning electron microscope (SEM), along with energy dispersive spectrometer (EDS). The microstructure results showed that a homogeneous and amorphous substance (AlPO4) as a secondary hydration product was distributed widely, which modified the mechanical properties of MK-MPCs.

Get full access to this article

View all available purchase options and get full access to this article.

Acknowledgments

The authors acknowledge the support by the National Natural Science Foundation of China, Grant No. 51778363.

References

Al Menhosh, A., Y. Wang, and Y. Wang. 2016. “The mechanical properties of the concrete using metakaolin additive and polymer admixture.” J. Eng. 2016: 1–6. https://doi.org/10.1155/2016/1670615.
Antoni, M., J. Rossen, F. Martirena, and K. Scrivener. 2012. “Cement substitution by a combination of metakaolin and limestone.” Cem. Concr. Res. 42 (12): 1579–1589. https://doi.org/10.1016/j.cemconres.2012.09.006.
ASTM. 2013. Standard test method for time of setting of hydraulic cement mortar by modified vicat needle. C807-05. West Conshohocken, PA: ASTM.
Buj, I., J. Torras, D. Casellas, M. Rovira, and J. de Pablo. 2009. “Effect of heavy metals and water content on the strength of magnesium phosphate cements.” J. Hazard. Mater. 170 (1): 345–350. https://doi.org/10.1016/j.jhazmat.2009.04.091.
Chau, C., F. Qiao, and Z. Li. 2011. “Microstructure of magnesium potassium phosphate cement.” Constr. Build. Mater. 25 (6): 2911–2917. https://doi.org/10.1016/j.conbuildmat.2010.12.035.
Chinese Standard. 2008. Testing standard for adhesive strength of tapestry brick of construction engineering. JGJ110. Beijing: China Architecture & Building Press.
Ding, Z., B. Dong, F. Xing, N. Han, and Z. Li. 2012. “Cementing mechanism of potassium phosphate based magnesium phosphate cement.” Ceram. Int. 38 (8): 6281–6288. https://doi.org/10.1016/j.ceramint.2012.04.083.
Fan, S., and B. Chen. 2014. “Experimental study of phosphate salts influencing properties of magnesium phosphate cement.” Constr. Build. Mater. 65: 480–486. https://doi.org/10.1016/j.conbuildmat.2014.05.021.
Fan, S., and B. Chen. 2015. “Experimental research of water stability of magnesium alumina phosphate cements mortar.” Constr. Build. Mater. 94: 164–171. https://doi.org/10.1016/j.conbuildmat.2015.06.050.
Hall, D., R. Stevens, and B. El-Jazairi. 2001. “The effect of retarders on the microstructure and mechanical properties of magnesia-phosphate cement mortar.” Cem. Concr. Res. 31 (3): 455–465. https://doi.org/10.1016/S0008-8846(00)00501-9.
Jun, L., J. Yong-sheng, H. Guodong, and J. Cheng. 2017. “Retardation and reaction mechanisms of magnesium phosphate cement mixed with glacial acetic acid.” RSC Adv. 7 (74): 46852–46857. https://doi.org/10.1039/C7RA08383A.
Li, G., J. Zhang, and G. Zhang. 2017a. “Mechanical property and water stability of the novel CSA-MKPC blended system.” Constr. Build. Mater. 136: 99–107. https://doi.org/10.1016/j.conbuildmat.2017.01.036.
Li, Y., H. Lin, S. Hejazi, C. Zhao, and M. Xie. 2017b. “The effect of low temperature phase change material of hydrated salt on the performance of magnesium phosphate cement.” Constr. Build. Mater. 149: 272–278. https://doi.org/10.1016/j.conbuildmat.2017.05.110.
Liu, N., and B. Chen. 2016. “Experimental research on magnesium phosphate cements containing alumina.” Constr. Build. Mater. 121: 354–360. https://doi.org/10.1016/j.conbuildmat.2016.06.010.
Lu, X., and B. Chen. 2016. “Experimental study of magnesium phosphate cements modified by metakaolin.” Constr. Build. Mater. 123: 719–726. https://doi.org/10.1016/j.conbuildmat.2016.07.092.
Nazário Santos, F., S. Raquel Gomes de Sousa, A. José Faria Bombard, and S. Lopes Vieira. 2017. “Rheological study of cement paste with metakaolin and/or limestone filler using mixture design of experiments.” Constr. Build. Mater. 143: 92–103. https://doi.org/10.1016/j.conbuildmat.2017.03.001.
Neiman, R., and A. Sarma. 1980. “Setting and thermal reactions of phosphate investments.” J. Dental Res. 59 (9): 1478–1485. https://doi.org/10.1177/00220345800590090401.
Sarkar, A. 1991. “Hydration/dehydration characteristics of struvite and dittmarite pertaining to magnesium ammonium phosphate cement systems.” J. Mater. Sci. 26 (9): 2514–2518. https://doi.org/10.1007/BF01130204.
Shao, Y., X. Wu, F. Song, X. Xu, and C. Jiang. 2013. “Effect of porosity on the crack pattern and residual strength of ceramics after quenching.” J. Mater. Sci. 48 (18): 6431–6436.
Shehab El-Din, H., A. Eisa, B. Abdel Aziz, and A. Ibrahim. 2017. “Mechanical performance of high strength concrete made from high volume of metakaolin and hybrid fibers.” Constr. Build. Mater. 140: 203–209. https://doi.org/10.1016/j.conbuildmat.2017.02.118.
Soudée, E., and J. Péra. 2000. “Mechanism of setting reaction in magnesia-phosphate cements.” Cem. Concr. Res. 30 (2): 315–321. https://doi.org/10.1016/S0008-8846(99)00254-9.
Soudée, E., and J. Péra. 2002. “Influence of magnesia surface on the setting time of magnesia-phosphate cement.” Cem. Concr. Res. 32 (1): 153–157. https://doi.org/10.1016/S0008-8846(01)00647-0.
Vance, K., A. Kumar, G. Sant, and N. Neithalath. 2013. “The rheological properties of ternary binders containing portland cement, limestone, and metakaolin or fly ash.” Cem. Concr. Res. 52 (7): 196–207. https://doi.org/10.1016/j.cemconres.2013.07.007.
Wagh, A., S. Grover, and S. Jeong. 2003. “Chemically bonded phosphate ceramics: II, Warm-temperature process for alumina ceramics.” J. Am. Ceram. Soc. 86 (11): 1845–1849. https://doi.org/10.1111/j.1151-2916.2003.tb03570.x.
Wagh, A., and S. Jeong. 2003. “Chemically bonded phosphate ceramics: I, A dissolution model of formation.” J. Amer. Ceram. Soc. 86 (11): 1838–1844. https://doi.org/10.1111/j.1151-2916.2003.tb03569.x.
Wang, A., J. Zhang, J. Li, A. Ma, and L. Liu. 2013. “Effect of liquid-to-solid ratios on the properties of magnesium phosphate chemically bonded ceramics.” Mater. Sci. Eng.: C. 33 (5): 2508–2512. https://doi.org/10.1016/j.msec.2013.02.014.
Yang, Q., S. Zhang, and X. Wu. 2002. “Deicer-scaling resistance of phosphate cement-based binder for rapid repair of concrete.” Cem. Concr. Res. 32 (1): 165–168. https://doi.org/10.1016/S0008-8846(01)00651-2.
Yang, Q., B. Zhu, S. Zhang, and X. Wu. 2000. “Properties and applications of magnesia-phosphate cement mortar for rapid repair of concrete.” Cem. Concr. Res. 30 (11): 1807–1813. https://doi.org/10.1016/S0008-8846(00)00419-1.

Information & Authors

Information

Published In

Go to Journal of Materials in Civil Engineering
Journal of Materials in Civil Engineering
Volume 31Issue 8August 2019

History

Received: Nov 9, 2017
Accepted: Jan 30, 2019
Published online: May 23, 2019
Published in print: Aug 1, 2019
Discussion open until: Oct 23, 2019

Permissions

Request permissions for this article.

Authors

Affiliations

Master Student, State Key Laboratory of Ocean Engineering, Shanghai Jiao Tong Univ., Shanghai 200240, People’s Republic of China. Email: [email protected]
Bing Chen, Ph.D. [email protected]
Professor, State Key Laboratory of Ocean Engineering, Shanghai Jiao Tong Univ., Shanghai 200240, People’s Republic of China (corresponding author). Email: [email protected]
Ph.D. Candidate, Dept. of Civil Engineering, Shanghai Jiaotong Univ., Shanghai 200240, People’s Republic of China. ORCID: https://orcid.org/0000-0002-1251-2316. Email: [email protected]

Metrics & Citations

Metrics

Citations

Download citation

If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download.

Cited by

View Options

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Media

Figures

Other

Tables

Share

Share

Copy the content Link

Share with email

Email a colleague

Share