Abstract

The dynamic shear rheometer was used to investigate the effect of polyphosphoric acid (PPA) and styrene-butadiene-styrene (SBS) modification on the rheological and mechanical behavior of asphalt binder and asphalt mastic. In this research, three SBS contents (2%, 4%, and 6%) and three PPA contents (0.5%, 1%, and 2% by weight of neat asphalt binder) were used. Also, two volume fractions (18% and 35%) of silica filler were selected to fabricate asphalt mastic samples. In total, 1 neat asphalt binder, 6 modified asphalt samples, and 12 modified asphalt mastics were investigated. By using storage and loss moduli data of all samples in a frequency range between 0.1 and 100 Hz at various temperatures between −25°C and 22°C, the Cole-Cole and black space diagrams were plotted and analyzed. The results clearly show that the linear viscoelastic behavior of asphalt mastic is directly related to asphalt binder because of the identical forms of the Cole-Cole curve. An optical microscope was also used to see filler particle distribution in the bitumen structure. The stiffening phenomenon for a volume fraction of 35% was observed in comparison with a volume fraction of 18%, consistent with other previous research work. Adding PPA causes extra stiffening related to formation of the strong structure of PPA between filler particles.

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References

Aflaki, S., and P. Hajikarimi. 2012. “Implementing viscoelastic rheological methods to evaluate low temperature performance of modified asphalt binders.” Constr. Build. Mater. 36: 110–118. https://doi.org/10.1016/j.conbuildmat.2012.04.076.
Aflaki, S., P. Hajikarimi, E. H. Fini, and B. Zada. 2014. “Comparing effects of biobinder with other asphalt modifiers on low-temperature characteristics of asphalt.” J. Mater. Civ. Eng. 26 (3): 429–439. https://doi.org/10.1061/(ASCE)MT.1943-5533.0000835.
Aflaki, S., and N. Tabatabaee. 2009. “Proposals for modification of Iranian bitumen to meet the climatic requirements of Iran.” Constr. Build. Mater. 23 (6): 2141–2150. https://doi.org/10.1016/j.conbuildmat.2008.12.014.
Airey, G. D. 2003. “Rheological properties of styrene butadiene styrene polymer modified road bitumens.” Fuel 82 (14): 1709–1719. https://doi.org/10.1016/S0016-2361(03)00146-7.
Arnold, T. S., S. P. Needham, and J. Youtcheff. 2009. “Use of phosphoric acid as a modifier for hot-mix asphalt.” In Proc., 88th Transportation Research Board Annual Meetings. Washington, DC: Transportation Research Information Database.
ASTM. 2013. Standard test method for penetration of bituminous materials. ASTM D5. West Conshohocken, PA: ASTM.
ASTM. 2014a. Standard test method for rubber—Determination of bound styrene in styrene butadiene rubber by refractive index. ASTM D5775. West Conshohocken, PA: ASTM.
ASTM. 2014b. Standard test method for softening point of bitumen (ring-and-ball apparatus). ASTM D36. West Conshohocken, PA: ASTM.
ASTM. 2014c. Standard test methods for rubber from synthetic sources—Volatile matter. ASTM D5668. West Conshohocken, PA: ASTM.
ASTM. 2015a. Standard test method for rubber from synthetic sources—Total and water soluble ash. ASTM D5667. West Conshohocken, PA: ASTM.
ASTM. 2015b. Standard test method for rubber property—Durometer hardness. ASTM D2240. West Conshohocken, PA: ASTM.
Awanti, S. S., M. S. Amarnath, and A. Veeraragavan. 2008. “Laboratory evaluation of SBS modified bituminous paving mix.” J. Mater. Civ. Eng. 20 (4): 327–330. https://doi.org/10.1061/(ASCE)0899-1561(2008)20:4(327).
Bahia, H., R. Moraes, and R. Velasquez. 2012. “The effect of bitumen stiffness on the adhesive strength measured by the bitumen bond strength test.” In Proc., 5th Eurasphalt and Eurobitume Congress. Geneva: International Road Federation.
Baldino, N., D. Gabriele, C. O. Rossi, L. Seta, F. R. Lupi, and P. Caputo. 2012. “Low temperature rheology of polyphosphoric acid (PPA) added bitumen.” Constr. Build. Mater. 36: 592–596. https://doi.org/10.1016/j.conbuildmat.2012.06.011.
Bardesi, A., B. Brule, J. F. Corte, E. Diani, A. Gerritsen, G. Lefevre, and S. Watkins. 1999. “Use of modified bituminous binders, special bitumens and bitumens with additives in pavement applications.” In Proc., Technical Committee Flexible Roads (C8) World Road Association (PIARC). Paris: World Road Association Mondiale De la Route.
Baumgardner, G. L., J. F. Masson, J. R. Hardee, A. M. Menapace, and A. G. Williams. 2005. “Polyphosphoric acid modified asphalt: Proposed mechanisms.” J. Assoc. Asphalt Paving Technol. 74: 283–305.
Brinson, H. F., and L. C. Brinson. 2008. Polymer engineering science and viscoelasticity: An introduction. New York: Springer.
Buttlar, W., D. Bozkurt, G. Al-Khateeb, and A. Waldhoff. 1999. “Understanding asphalt mastic behavior through micromechanics.” Transp. Res. Rec. 1681: 157–169. https://doi.org/10.3141/1681-19.
Chen, J.-S., M.-C. Liao, and M.-S. Shiah. 2002. “Asphalt modified by styrene-butadiene-styrene triblock copolymer: Morphology and model.” J. Mater. Civ. Eng. 14 (3): 224–229. https://doi.org/10.1061/(ASCE)0899-1561(2002)14:3(224).
Dae Han, C., J. Kim, D. Man Baek, and S. Gun Chu. 1990. “Viscoelastic behavior, order-disorder transition, and phase equilibria in mixtures of a block copolymer and an endblock-associating resin.” J. Polym. Sci., Part B: Polym. Phys. 28 (3): 315–341. https://doi.org/10.1002/polb.1990.090280306.
D’Angelo, J. A. 2012. “Effect of polyphosphoric acid on asphalt binder properties.” In Proc., Workshop on Polyphosphoric Acid Modification of Asphalt Binders, 27–39. Washington, DC: Transportation Research Board.
Faheem, A. F., and H. Bahia. 2009. “Conceptual phenomenological model for interaction of asphalt binders with mineral fillers.” J. Assoc. Asphalt Paving Technol. 78: 679–720.
Faheem, A. F., and H. Bahia. 2011. “Modelling of asphalt mastic in terms of filler-bitumen interaction.” Supplement, Road Mater. Pavement Des. 11 (S1): 281–303. https://doi.org/10.1080/14680629.2010.9690335.
Fee, D., R. Maldonado, G. Reinke, and H. Romagosa. 2010. “Polyphosphoric acid modification of asphalt.” Transp. Res. Rec. 2179: 49–57. https://doi.org/10.3141/2179-06.
Hajikarimi, P., F. F. Tehrani, F. Moghadas Nejad, J. Absi, M. Rahi, A. Khodaii, and C. Petit. 2018. “Generalized fractional viscoelastic modeling of low temperature characteristics of asphalt binders modified with polyphosphoric acid and distillate aromatic extracts oil.” J. Mater. Civ. Eng. 30 (7): 04018147. https://doi.org/10.1061/(ASCE)MT.1943-5533.0002353.
Huang, S.-C., F. P. Miknis, W. Schuster, S. Salmans, M. Farrar, and R. Boysen. 2011. “Rheological and chemical properties of hydrated lime and polyphosphoric acid–modified asphalts with long-term aging.” J. Mater. Civ. Eng. 23 (5): 628–637. https://doi.org/10.1061/(ASCE)MT.1943-5533.0000219.
Isacsson, U., and X. Lu. 1999. “Laboratory investigation of polymer modified bitumens.” J. Assoc. Asphalt Paving Technol. 68: 35–63.
Kim, M., and W. Buttlar. 2010. “Stiffening mechanisms of asphalt-aggregate mixtures.” Transp. Res. Rec. 2181: 98–108. https://doi.org/10.3141/2181-11.
Kim, Y.-R., and D. N. Little. 2004. “Linear viscoelastic analysis of asphalt mastics.” J. Mater. Civ. Eng. 16 (2): 122–132. https://doi.org/10.1061/(ASCE)0899-1561(2004)16:2(122).
Kök, B. V., and H. Çolak. 2011. “Laboratory comparison of the crumb-rubber and SBS modified bitumen and hot mix asphalt.” Constr. Build. Mater. 25 (8): 3204–3212. https://doi.org/10.1016/j.conbuildmat.2011.03.005.
Lackner, R., M. Spiegl, R. Blab, and J. Eberhardsteiner. 2005. “Is low-temperature creep of asphalt mastic independent of filler shape and mineralogy? Arguments from multiscale analysis.” J. Mater. Civ. Eng. 17 (5): 485–491. https://doi.org/10.1061/(ASCE)0899-1561(2005)17:5(485).
Lesueur, D. 2009. “The colloidal structure of bitumen: Consequences on the rheology and on the mechanisms of bitumen modification.” Adv. Colloid Interface Sci. 145 (1): 42–82. https://doi.org/10.1016/j.cis.2008.08.011.
Man Sze Ho, S., L. Zanzotto, and D. MacLeod. 2002. “Impact of different types of modification on low-temperature tensile strength and tcritical of asphalt binders.” Transp. Res. Rec. 1810: 1–8. https://doi.org/10.3141/1810-01.
Moghadas Nejad, F., P. Aghajani, A. Modarres, and H. Firoozifar. 2012. “Investigating the properties of crumb rubber modified bitumen using classic and SHRP testing methods.” Constr. Build. Mater. 26 (1): 481–489. https://doi.org/10.1016/j.conbuildmat.2011.06.048.
Navarro, F. J., P. Partal, F. Martínez-Boza, and C. Gallegos. 2005. “Influence of crumb rubber concentration on the rheological behavior of a crumb rubber modified bitumen.” Energy Fuels 19 (5): 1984–1990. https://doi.org/10.1021/ef049699a.
Olard, F., and H. Di Benedetto. 2011. “General “2S2P1D” model and relation between the linear viscoelastic behaviours of bituminous binders and mixes.” Road Mater. Pavement Des. 4 (2): 185–224. https://doi.org/10.1080/14680629.2003.9689946.
Orange, G., D. Dupuis, J. V. Martin, F. Farcas, C. Such, and B. Marcant. 2004. “Chemical modification of bitumen through polyphosphoric acid: Properties-microstructure relationship.” In Proc., 3rd Eurasphalt and Eurobitumen Congress, 733–745. Geneva: International Road Federation.
Sengoz, B., and G. Isikyakar. 2008. “Evaluation of the properties and microstructure of SBS and EVA polymer modified bitumen.” Constr. Build. Mater. 22 (9): 1897–1905. https://doi.org/10.1016/j.conbuildmat.2007.07.013.
Shashidhar, N., and A. Shenoy. 2002. “On using micromechanical models to describe dynamic mechanical behavior of asphalt mastics.” Mech. Mater. 34 (10): 657–669. https://doi.org/10.1016/S0167-6636(02)00166-7.
Tan, Y., and M. Guo. 2013. “Using surface free energy method to study the cohesion and adhesion of asphalt mastic.” Constr. Build. Mater. 47: 254–260. https://doi.org/10.1016/j.conbuildmat.2013.05.067.
Topal, A. 2010. “Evaluation of the properties and microstructure of plastomeric polymer modified bitumens.” Fuel Process. Technol. 91 (1): 45–51. https://doi.org/10.1016/j.fuproc.2009.08.007.
Van Rompu, J., H. Di Benedetto, M. Buannic, T. Gallet, and C. Ruot. 2012. “New fatigue test on bituminous binders: Experimental results and modeling.” Constr. Build. Mater. 37: 197–208. https://doi.org/10.1016/j.conbuildmat.2012.02.099.
Yildirim, Y. 2007. “Polymer modified asphalt binders.” Constr. Build. Mater. 21 (1): 66–72. https://doi.org/10.1016/j.conbuildmat.2005.07.007.
Zegeye, E. T., K. H. Moon, M. Turos, T. R. Clyne, and M. O. Marasteanu. 2012. “Low temperature fracture properties of polyphosphoric acid modified asphalt mixtures.” J. Mater. Civ. Eng. 24 (8): 1089–1096. https://doi.org/10.1061/(ASCE)MT.1943-5533.0000488.
Zhang, F., and J. Yu. 2010. “The research for high-performance SBR compound modified asphalt.” Constr. Build. Mater. 24 (3): 410–418. https://doi.org/10.1016/j.conbuildmat.2009.10.003.

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Go to Journal of Materials in Civil Engineering
Journal of Materials in Civil Engineering
Volume 31Issue 1January 2019

History

Received: Jan 20, 2018
Accepted: Jun 25, 2018
Published online: Oct 22, 2018
Published in print: Jan 1, 2019
Discussion open until: Mar 22, 2019

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Pouria Hajikarimi [email protected]
Ph.D. Candidate, Dept. of Civil and Environmental Engineering, Amirkabir Univ. of Technology, Hafez Ave., 1591634311 Tehran, Iran. Email: [email protected]
Fateh Fakhari Tehrani [email protected]
Assistant Professor, Centre Universitaire de Génie Civil, Université de Limoges, 17 Blvd. Jacques Derche, Egletons 19300, France; Conservatoire National des Arts et Métiers, 292 Rue Saint-Martin, Paris 75003, France. Email: [email protected]
Fereidoon Moghadas Nejad [email protected]
Professor and Head of Transportation Group, Dept. of Civil and Environmental Engineering, Amirkabir Univ. of Technology, Hafez Ave., 1591634311 Tehran, Iran (corresponding author). Email: [email protected]
Joseph Absi [email protected]
Professor, Unité Mixte de Recherche Centre National de la Recherche Scientifique, Institut de Recherche sur les Ceramiques, Univ. of Limoges, 7315, 12 Rue Atlantis, 87068 Limoges, Cedex, France. Email: [email protected]
Mohammad Rahi [email protected]
Manager, Dept. of Research and Development, Pasargad Oil Company Bitumen Plant, Tondgouyan Oil Refinery, Tondgouyan Hwy., Rajaei Shahr, Tehran 19395-4598, Iran. Email: [email protected]
Ali Khodaii [email protected]
Professor, Dept. of Civil and Environmental Engineering, Amirkabir Univ. of Technology, Hafez Ave., 1591634311 Tehran, Iran. Email: [email protected]
Christophe Petit [email protected]
Professor, Centre Universitaire de Génie Civil, Université de Limoges, 17 Blvd. Jacques Derche, Egletons 19300, France. Email: [email protected]

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