Technical Papers
Mar 28, 2018

Preparation and Characterization of an Eco-Friendly Binder from Alkali-Activated Aluminosilicate Solid Industrial Wastes Containing CKD and GGBS

Publication: Journal of Materials in Civil Engineering
Volume 30, Issue 6

Abstract

This work aims to prepare an eco-friendly binder from alkali-activated aluminosilicate solid industrial wastes. Eco-friendly binders provide a solution to the present ecological problem of producing non-portland-cement binders. Cement kiln dust (CKD) and ground granulated blast-furnace slag (GGBS) by-products were used to prepare the binder from alkali-activated GGBS-CKD mixed with XNa2O:0.5SiO2mol/kg. The characteristics of the prepared binder were studied using different techniques such as FTIR, DTA/TGA, XRD, and SEM. The compressive strength and bulk density of alkali-activated GGBS-CKD binders increased with increasing CKD contents up to 20% mass (Mix D2), then decreased with the increase of CKD contents from 30 to 50% mass. The chemically combined water and combined slag content of activated GGBS-CKD increased with increasing CKD content up to 50% mass (Mix D4). Mix D2 (20% mass of CKD) is the optimum mix composition. Ca(OH)2 (CH) and CaCO3 containing CKD disintegrated the aluminosilicate matrix of GGBS. CH acts as a Ca2+ ion source to accelerate the pozzolanic activity to form rigid spheres of the compact massive matrix of (N, C)–A–S–H gel having low porosity. In addition, CKD has higher alkali and SO42 content, which makes CKD an excellent activator to enhance the dissolution of GGBS to release silicate, aluminate, and/or aluminosilicate species and improve the alkali-activated network gel matrix formation.

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Acknowledgments

The authors extend their sincere appreciation to the Deanship of Scientific Research at the Al Imam Mohammad Ibn Saud Islamic University (IMSIU), Riyadh, Kingdom of Saudi Arabia, for its funding of this research through Research Group Project No. 351216.

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Go to Journal of Materials in Civil Engineering
Journal of Materials in Civil Engineering
Volume 30Issue 6June 2018

History

Received: May 4, 2017
Accepted: Nov 21, 2017
Published online: Mar 28, 2018
Published in print: Jun 1, 2018
Discussion open until: Aug 28, 2018

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Mohamed Heikal [email protected]
Professor of Inorganic Chemistry, Dept. of Chemistry, College of Science, Al Imam Mohammad Ibn Saud Islamic Univ., P.O. Box 90950, Riyadh, Saudi Arabia 11623; Professor of Inorganic Chemistry, Dept. of Chemistry, Faculty of Science, Benha Univ., Benha, Egypt (corresponding author). E-mail: [email protected]
M. E. A. Zaki
Professor of Organic Chemistry, Dept. of Chemistry, College of Science, Al Imam Mohammad Ibn Saud Islamic Univ., P.O. Box 90950, Riyadh, Saudi Arabia 11623.
A. Alshammari
Associate Professor of Organic Chemistry, Dept. of Chemistry, College of Science, Al Imam Mohammad Ibn Saud Islamic Univ., P.O. Box 90950, Riyadh, Saudi Arabia 11623.

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