Effects of Sugar Beet Molasses and Molasses-Based Boron Oxide Compound on Bitumen Properties
Publication: Journal of Materials in Civil Engineering
Volume 29, Issue 4
Abstract
In this study, sugar beet molasses and molasses-based boron oxide compound (MBOC) were used to modify the base bitumen. Sugar beet molasses is an organic waste material obtained from raw sugar during the refining process at sugar refineries. Molasses-based boron oxide is a synthetic material derived chemically in laboratory conditions by using proper amounts of sugar beet molasses and boron oxide. Each additive material was added separately at a level between 1 and 10% by weight of the penetration grade-base bitumen. The effects of the modifications on the bitumen and bituminous mixture properties were examined by means of a laboratory test group including rotational viscosity, penetration, softening point, ductility, dynamic shear rheometer (DSR), and Marshall Stability and Nicholson stripping tests. According to the Marshall Stability and Nicholson stripping test results, the bituminous mixture performance was found to be improved by MBOC, however, it stayed at the same level with sugar beet molasses.
Get full access to this article
View all available purchase options and get full access to this article.
References
AASHTO. (1993). “Standard specification for performance graded asphalt binder.” AASHTO MP1, Washington, DC
AASHTO. (2012). “Standard method of test for determining the rheological properties of asphalt binder using a dynamic shear rheometer (DSR).” AASHTO T315, Washington, DC.
Airey, G. D. (2003). “Rheological properties of styrene butadiene styrene polymer modified road bitumens.” Fuel, 82(14), 1709–1719.
Aksoy, A., Şamlıoğlu, K., Tayfur, S., and Ozen, H. (2005). “Effects of various additives on the moisture damage sensitivity of asphalt mixtures.” Constr. Build. Mater., 19(1), 11–18.
Al-Hadidy, A. I., and Tan, Y. (2009). “Mechanistic analysis of ST and SBS-modified flexible pavements.” Constr. Build. Mater., 23(8), 2941–2950.
Ameri, M., Mansourian, A., and Sheikhmotevali, A. H. (2013). “Laboratory evaluation of ethylene vinyl acetate modified bitumens and mixtures based upon performance related parameters.” Constr. Build. Mater., 40, 438–447.
Arslan, D., Gürü, M., and Çubuk, M. K. (2012a). “Improvement of bitumen and bituminious mixtures performance properties with organic based zincphosphate compound.” J. Faculty Eng. Archit. Gazi Univ., 27, 459–466.
Arslan, D., Gürü, M., and Çubuk, M. K. (2012b). “Performance assessment of organic-based synthetic calcium and boric acid modified bitumens.” Fuel, 102, 766–772.
Arslan, D., Gürü, M., and Çubuk, M. K. (2013). “Improvement of hot mix asphalt performance in cold regions by organic-based synthetic compounds.” Cold Reg. Sci. Technol., 85, 250–255.
Arslan, D., Gürü, M., and Çubuk, M. K. (2014). “Preventing of rutting and crackings in the bituminous mixtures by monoethylene and diethylene glycol based synthetic polyboron compounds.” Constr. Build. Mater., 50, 102–107.
Arslan, D., Gürü, M., Çubuk, M. K., and Çubuk, M. (2011). “Improvement of bitumen and bituminous mixtures performances by triethylene glycol based synthetic polyboron.” Constr. Build. Mater., 25(10), 3863–3868.
ASTM. (1980). “Test method for coating and stripping of bitumen-aggregate mixtures.” ASTM D1664-80, West Conshohocken, PA.
ASTM. (1989). “Test method for resistance of plastic flow of bituminous mixtures using marshall apparatus.” ASTM D1559, West Conshohocken, PA.
ASTM. (2002). “Standard test method for viscosity determination of asphalt at elevated temperatures using a rotational viscometer.” ASTM D4402-02, West Conshohocken, PA.
ASTM. (2007). “Standard test method for ductility of bituminous materials.” ASTM D113-07, West Conshohocken, PA.
ASTM. (2012). “Standard test method for softening point of bitumen (ring-and-ball apparatus).” ASTM D36-12, West Conshohocken, PA.
ASTM. (2013). “Standard test method for penetration of bituminous materials.” ASTM D5-13, West Conshohocken, PA.
Bulatovic, V. O., Rek, V., and Markovic, K. J. (2014). “Effect of polymer modifiers on the properties of bitumen.” J. Elastomers Plast., 46(5), 448–469.
Caro, S., Beltran, D. P., Alvarez, A. E., and Estakhri, C. (2012). “Analysis of moisture damage susceptibility of warm mix asphalt (WMA) mixtures based on dynamic mechanical analyzer (DMA) testing and a fracture mechanics model.” Constr. Build. Mater., 35, 460–467.
Chen, H., and Xu, Q. (2010). “Experimental study of fibers in stabilizing and reinforcing asphalt binder.” Fuel, 89(7), 1616–1622.
Chen, X., and Huang, B. (2008). “Evaluation of moisture damage in hot mix asphalt using simple performance and superpave indirect tensile tests.” Constr. Build. Mater., 22(9), 1950–1962.
Cong, P., Wang, J., Li, K., and Chen, S. (2012). “Physical and rheological properties of asphalt binders containing various antiaging agents.” Fuel, 97, 678–684.
Cong, P., Xun, P., Xing, M., and Chen, S. (2013). “Investigation of asphalt binder containing various crumb rubbers and asphalts.” Constr. Build. Mater., 40, 632–641.
Çubuk, M., Gürü, M., and Çubuk, M. K. (2009). “Improvement of bitumen performance with epoxy resin.” Fuel, 88(7), 1324–1328.
Çubuk, M., Gürü, M., Çubuk, M. K., and Arslan, D. (2013). “Improvement of properties of bitumen by organic-based magnesium additive.” J. Faculty Eng. Archit. Gazi Univ., 28(2), 257–264.
Çubuk, M., Gürü, M., Çubuk, M. K., and Arslan, D. (2014). “Rheological properties and performance evaluation of phenol formaldehyde modified bitumen.” J. Mater. Civ. Eng., .
Fang, C., Liu, X., Yu, R., Liu, P., and Lei, W. (2014). “Preparation and properties of asphalt modified with a composite composed of waste package poly(vinyl chloride) and organic montmorillonite.” J. Mater. Sci. Technol., 30(12), 1304–1310.
Fang, C., Yu, R., Li, Y., Zhang, M., Hu, J., and Zhang, M. (2013). “Preparation and characterization of an asphalt-modifying agent with waste packaging polyethylene and organic montmorillonite.” Polym. Test, 32(5), 953–960.
Galooyak, S. S., Dabir, B., Nazarbeygi, A. E., and Moeini, A. (2010). “Rheological properties and storage stability of bitumen/SBS/montmorillonite composites.” Constr. Build. Mater., 24(3), 300–307.
Gorkem, C., and Sengoz, B. (2009). “Predicting stripping and moisture induced damage of asphalt concrete prepared with polymer modified bitumen and hydrated lime.” Constr. Build. Mater., 23(6), 2227–2236.
Gürü, M., Çubuk, M. K., Arslan, D., Farzanian, S. A., and Bilici, İ. (2014). “An approach to the usage of polyethylene terephthalate (PET) waste as roadway pavement material.” J. Hazard. Mater., 279, 302–310.
Haddadi, S., Ghorbel, E., and Laradi, N. (2008). “Effects of the manufacturing process on the performances of the bituminous binders modified with EVA.” Constr. Build. Mater., 22(6), 1212–1219.
Hınıslıoğlu, S., and Ağar, E. (2004). “Use of waste high density polyethylene as bitumen modifier in asphalt concrete mix.” Mater. Lett., 58(3–4), 267–271.
Jun, L., Yuxia, Z., and Yuzhen, Z. (2008). “The research of GMA-g-LDPE modified Qinhuangdao bitumen.” Constr. Build. Mater., 22(6), 1067–1073.
Karakaş, A. S., Sayin, B., and Kuloğlu, N. (2014). “The changes in the mechanical properties of neat and SBS-modified HMA pavements due to traffic loads and environmental effects over a one-year period.” Constr. Build. Mater., 71, 406–415.
Khodaii, A., and Mehrara, A. (2009). “Evaluation of permanent deformation of unmodified and SBS modified asphalt mixtures using dynamic creep test.” Constr. Build. Mater., 23(7), 2586–2592.
Kim, T. W., Baek, J., Lee, H. J., and Choi, J. Y. (2013). “Fatigue performance evaluation of SBS modified mastic asphalt mixtures.” Constr. Build. Mater., 48, 908–916.
Kok, B. V., and Yilmaz, M. (2009). “The effects of using lime and styrene-butadiene-styrene on moisture sensitivity resistance of hot mix asphalt.” Constr. Build. Mater., 23(5), 1999–2006.
Kök, B. V., and Çolak, H. (2011). “Laboratory comparison of the crumb-rubber and SBS modified bitumen and hot mix asphalt.” Constr. Build. Mater., 25(8), 3204–3212.
Kumar, P., and Garg, R. (2011). “Rheology of waste plastic fibre-modified bitumen.” Int. J. Pavement Eng., 12(5), 449–459.
Liu, G., Wu, S., Ven, M. V. D., Yu, J., and Molenaar, A. (2010). “Influence of sodium and organo-montmorillonites on the properties of bitumen.” Appl. Clay Sci., 49(1–2), 69–73.
Moreno-Navarro, F., Sol-Sánchez, M., Rubio-Gámez, M. C., and Segarra-Martínez, M. (2014). “The use of additives for the improvement of the mechanical behavior of high modulus asphalt mixes.” Constr. Build. Mater., 70, 65–70.
Navarro, F. J., Partal, P., Martinez-Boza, F., Valencia, C., and Gallegos, C. (2002). “Rheological characteristics of ground tire rubber-modified bitumens.” Chem. Eng. J., 89(1–3), 53–61.
Özen, H., Aksoy, A., Tayfur, S., and Çelik, F. (2008). “Laboratory performance comparison of the elastomer modified asphalt mixtures.” Build. Environ., 43(7), 1270–1277.
Sengoz, B., and Isikyakar, G. (2008). “Analysis of styrene-butadiene-styrene polymer modified bitumen using fluorescent microscopy and conventional test methods.” J. Hazard Mater., 150(2), 424–432.
Shahabadi, A. Z., Shokuhfar, A., and Nejad, S. E. (2010). “Preparation and rheological characterization of asphalt binders reinforced with layered silicate nanoparticles.” Constr. Build. Mater., 24(7), 1239–1244.
Singh, M., Kumar, P., and Maurya, M. R. (2013). “Strength characteristics of SBS modified asphalt mixes with various aggregates.” Constr. Build. Mater., 41, 815–823.
Tayfur, S., Ozen, H., and Aksoy, A. (2007). “Investigation of rutting performance of asphalt mixtures containing polymer modifiers.” Constr. Build. Mater., 21(2), 328–337.
Ye, Q., Wu, S., and Li, N. (2009). “Investigation of the dynamic and fatigue properties of fiber-modified asphalt mixtures.” Int. J. Fatigue, 31(10), 1598–1602.
Yu, J., Zeng, X., Wu, S., Wang, L., and Liu, G. (2007). “Preparation and properties of montmorillonite modified asphalts.” Mater. Sci. Eng. A Struct., 447(1–2), 233–238.
Zhang, J., Yang, F., Pei, J., Xu, S., and An, F. (2015). “Viscosity-temperature characteristics of warm mix asphalt binder with Sasobit®.” Constr. Build. Mater., 78, 34–39.
Information & Authors
Information
Published In
Copyright
©2016 American Society of Civil Engineers.
History
Received: Jan 4, 2016
Accepted: Aug 23, 2016
Published online: Oct 26, 2016
Discussion open until: Mar 26, 2017
Published in print: Apr 1, 2017
Authors
Metrics & Citations
Metrics
Citations
Download citation
If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download.