Technical Papers
Feb 4, 2016

Effect of Cyclic Carbonation on Chloride Ingression in GGBS Concrete

This article has a reply.
VIEW THE REPLY
Publication: Journal of Materials in Civil Engineering
Volume 28, Issue 7

Abstract

Carbonation and chloride ingress are the two main causes of corrosion in reinforced concrete structures. An investigation to monitor the ingress of chlorides and the effect of carbonation on chloride ingression during an accelerated 12 month cyclic wetting and drying exposure regime that simulates conditions in which multiple mode transport mechanisms are active was conducted on ground granulated blast furnace slag (GGBS) concrete. The penetration of chloride and carbon dioxide was evaluated using water and acid soluble chloride profiles and phenolphthalein indicator, respectively. The results indicated that when chloride and carbon dioxide ingress concomitantly the effects can be adverse. Carbonation has a detrimental effect on the binding capacity of the concrete, increasing the concentration of free (water soluble) chlorides. This contributed to greater concentration and greater penetration of chlorides and thus an increased corrosion risk.

Get full access to this article

View all available purchase options and get full access to this article.

References

ACI (American Concrete Institute). (2011). "Building code requirements for structural concrete and commentary." ACI 318-11, Farmington Hills, MI.
Angst, U., Elsener, B., Larsen, C. K., and Vennesland, Ø. (2009). “Critical chloride content in reinforced concrete—A review.” Cem. Concr. Res., 39(12), 1122–1138.
Arya, C., and Xu, Y. (1995). “Effect of cement type on chloride binding and corrosion of steel in concrete.” Cem. Concr. Res., 25(4), 893–902.
Bamforth, P. B., Price, W. F., and Emerson, M. (1997). An international review of chloride ingress into structural concrete, TRL (Transport Research Laboratory), Wokingham, U.K.
Bostanci, Ş. C., Limbachiya, M., and Kew, H. (2015). “Portland slag and composites cement concrete: Engineering and durability properties.” J. Cleaner Prod., 12, 1–11.
BSI (British Standards Institution). (1986). “Testing concrete—Part 125: Methods for mixing and sampling fresh concrete in the laboratory.”, London.
BSI (British Standards Institution). (2006). “Products and systems for the protection and repair of concrete structures—Test methods—Determination of carbonation depth in hardened concrete by the phenolphthalein method.” BS EN 14630:2006, London.
BSI (British Standards Institution). (2007). “Products and systems for the protection and repair of concrete structures—Test methods—Determination of chloride content in hardened concrete.” BS EN 14629, London.
BSI (British Standards Institution). (2009). “Testing hardened concrete—Part 2: Making and curing specimens for strength tests.” BS EN 12390-2, London.
BSI (British Standards Institution). (2013). “Concrete. Specification, performance, production and conformity.” BS EN 206, London.
Buenfeld, N. R., and Newman, J. B. (1984). “The permeability of concrete in a marine environment.” Mag. Concr. Res., 36(127), 67–80.
Dhir, R. K., El-Mohr, M. A. K., and Dyer, T. D. (1996). “Chloride binding in GGBS concrete.” Cem. Concr. Res., 26(12), 1767–1773.
Glass, G. K., Reddy, B., and Buenfeld, N. R. (2000). “The participation of bound chloride in passive film breakdown on steel in concrete.” Corros. Sci., 42(11), 2013–2021.
Goñi, S., and Guerrero, A. (2003). “Accelerated carbonation of Friedel’s salt in calcium aluminate cement paste.” Cem. Concr. Res., 33(1), 21–26.
Kropp, J. (1995). “Performance criteria for concrete durability.”, Taylor & Francis, London.
Lu, X., Li, C., and Zhang, H. (2002). “Relationship between the free and total chloride diffusivity in concrete.” Cem. Concr. Res., 32(2), 1–7.
Luo, R., Cai, Y., Wang, C., and Huang, X. (2003). “Study of chloride binding and diffusion in GGBS concrete.” Cem. Concr. Res., 31(1), 323–326.
McPolin, D. O., Basheer, P. A. M., Long, A. E., Grattan, K. T. V., and Sun, T. (2007). “New test method to obtain pH profiles due to carbonation of concretes containing supplementary.” J. Mater. Civ. Eng., 936–946.
Mehta, P. K., and Monteiro, P. J. M. (2006). Concrete, microstructures, properties, and materials, 3rd Ed., McGraw-Hill, New York.
Montemor, M. F., Cunha, M. P., Ferreira, M. G., and Simões, A. M. (2002). “Corrosion behaviour of rebars in fly ash mortar exposed to carbon dioxide and chlorides.” Cem. Concr. Compos., 24(1), 45–53.
Nagatakii, S., and Ohga, H. (1992). “Combined effect of carbonation and chloride on corrosion in fly ash concrete.” Spec. Publ., 132, 227–244.
Neville, A. (1995a). “Chloride attack of reinforced concrete: An overview.” Mater. Struct., 28(2), 63–70.
Neville, A. M. (1995b). Properties of concrete, 4th Ed., Longman, Harlow, U.K.
Nilsson, L.-O. (1996). “Interaction between microclimate and concrete—A prerequisite for deterioration.” Constr. Build. Mater., 10(5), 301–308.
Osborne, G. J. (1999). “Durability of portland blast furnace slag cement concrete.” Cem. Concr. Compos., 21(1), 11–21.
Parrott, L. J. (1987). A review of carbonation in reinforced concrete, BRE, Garston, U.K.
Polder, R. B., and Peelen, W. H. (2002). “Characterisation of chloride transport and reinforcement corrosion in concrete under cyclic wetting and drying by electrical resistivity.” Cem. Concr. Compos., 24(5), 427–435.
Schiessl, P. (1988). Corrosion of steel in concrete, Chapman and Hall, London.
Suryavanshi, A. K., Scantlebury, J. D., and Lyon, S. B. (1996). “Mechanism of Friedel’s salt formation in cements rich in tri-calcium aluminate.” Cem. Concr. Res., 26(5), 717–727.
Suryavanshi, A. K., and Swamy, R. N. (1996). “Stability of Friedel’s salt in carbonated concrete structural elements.” Cem. Concr. Res., 26(5), 729–741.
Thomas, M. D. A., Hooton, R. D., Scott, A., and Zibara, H. (2012). “The effect of supplementary cementitious materials on chloride binding in hardened cement paste.” Cem. Concr. Res., 42(1), 1–7.
Tilly, G. P. (2011). “Durability of concrete repairs.” Concrete repairs, M. Grantham, ed., Taylor and Francis, Oxford, U.K.
Tilly, G. P., and Jacobs, J. (2007). Concrete repairs: Performance in service and current practice, BRE, Garston, U.K.
Ye, H., Jin, N., Jin, X., and Fu, C. (2012). “Model of chloride penetration into cracked concrete subject to drying-wetting cycles.” Constr. Build. Mater., 36, 259–269.
Yuan, Q., Shi, C., De Schutter, G., Audenaert, K., and Deng, D. (2009). “Chloride binding of cement-based materials subjected to external chloride environment—A review.” Constr. Build. Mater., 23(1), 1–13.

Information & Authors

Information

Published In

Go to Journal of Materials in Civil Engineering
Journal of Materials in Civil Engineering
Volume 28Issue 7July 2016

History

Received: Jun 2, 2015
Accepted: Nov 6, 2015
Published online: Feb 4, 2016
Published in print: Jul 1, 2016
Discussion open until: Jul 4, 2016

Permissions

Request permissions for this article.

Authors

Affiliations

Jonathon Backus [email protected]
Graduate Engineer, Mouchel, Liverpool L2 2QP, U.K. (corresponding author). E-mail: [email protected]
Daniel McPolin
Senior Lecturer, Queen’s Univ. Belfast, Belfast BT7 1NN, U.K.

Metrics & Citations

Metrics

Citations

Download citation

If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download.

Cited by

View Options

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Media

Figures

Other

Tables

Share

Share

Copy the content Link

Share with email

Email a colleague

Share