Assesment of Pozzolanic Performance of Sugarcane Bagasse Ash
Publication: Journal of Materials in Civil Engineering
Volume 28, Issue 2
Abstract
Sugarcane bagasse ash is obtained as a by-product from cogeneration combustion boilers in sugar industries, and is reported to be a useful supplementary cementitious material in concrete. A clear evaluation of pozzolanic activity of sugarcane bagasse ash is imperative to achieve its effective utilization in concrete instead of being disposed as a waste in enormous quantities. Pozzolanic activity of raw sugarcane bagasse ash and a processed sample of the same was assessed by five different standard methods in this study. The methods used were: strength activity index test, lime reactivity test, Frattini test, electrical conductivity test, and lime saturation test. In addition, chemical and mineralogical analyses were also performed on the bagasse ash. Durability performance of concrete with bagasse ash blended cement was evaluated and compared with fly ash-based concrete. The results from the studies indicate that raw bagasse ash has low pozzolanic activity due to presence of fibrous carbon particles. Removal of these fibrous particles from raw bagasse ash, which occurs during the processing methodology followed in this study, significantly improves its pozzolanic activity. The permeability of bagasse ash blended concrete was found to be significantly reduced compared to control and fly ash blended concrete, at an equivalent level of compressive strength.
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Acknowledgments
The authors wish to thank Madras Sugar Limited, Tamil Nadu, India for providing sugarcane bagasse ash used in this study.
References
Alexander, M. G., Ballim, Y., and Mackechnie, J. R. (1999). “Guide to the use of durability indexes for achieving durability in concrete structures. Achieving durable and economic concrete construction in the South African context.” Res. Monograph., 2(1), 5–11.
Aquino, W., Lange, D. A., and Olek, J. (2001). “The influence of metakaolin and silica fume on the chemistry of alkali-silica reaction products.” Cem. Concr. Compos., 23(6), 485–493.
ASTM. (2007). “Standard test method for flow of hydraulic cement mortar.” C1437-07, West Conshohocken, PA.
ASTM. (2011a). “Standard test methods for fineness of hydraulic cement by air-permeability apparatus.” C204-11, West Conshohocken, PA.
ASTM. (2011b). “Standard test methods for sampling and testing fly ash or natural pozzolans for use in portland-cement concrete.” C311-11, West Conshohocken, PA.
ASTM (2012). “Standard specification for coal fly ash and raw or calcined natural pozzolan for use in concrete.” C618, West Conshohocken, PA.
ASTM (2013). “Standard specification for chemical admixtures for concrete.” C494/C494M, West Conshohocken, PA.
Badogiannis, E., and Tsivilis, S. (2009). “Exploitation of poor Greek kaolins: Durability of metakaolin concrete.” Cem. Concr. Compos., 31(2), 128–133.
Bahurudeen, A., Marckson, A. V., Kishore, A., and Santhanam, M. (2014). “Development of sugarcane bagasse ash based portland pozzolana cement and evaluation of compatibility with superplasticizers.” Constr. Build. Mater., 68, 465–475.
Bahurudeen, A., and Santhanam, M. (2014). “Sugarcane bagasse ash—An alternative supplementary cementitious material.” Proc., Int. Conf. on Advances in Civil Engineering and Chemistry of Innovative Materials, SRM Univ., Chennai, India, 837–842.
CEN (European Committee for Standardization). (2005). “Method of testing cement. Pozzolanicity test for pozzolanic cement.” EN 196-5, Belgium, U.K.
Chusilp, N., Chai, J., and Kraiwood, K. (2009). “Utilization of bagasse ash as a pozzolanic material in concrete.” Constr. Build. Mater., 23(11), 3352–3358.
Cordeiro, G. C., Filho, R. D., Tavares, L. M., and Fairbairn, E. M. (2008). “Pozzolanic activity and filler effect of sugar cane bagasse ash in portland cement and lime mortars.” Cem. Concr. Compos., 30(5), 410–418.
Cordeiro, G. C., Filho, R. D., Tavares, L. M., and Fairbairn, E. M. (2009a). “Effect of calcination temperature on the pozzolanic activity of sugar cane bagasse ash.” Constr. Build. Mater., 23(10), 3301–3303.
Cordeiro, G. C., Filho, R. D., Tavares, L. M., and Fairbairn, E. M., (2009b). “Ultrafine grinding of sugar cane bagasse ash for application as pozzolanic admixture in concrete.” Cem. Concr. Res., 39(2), 110–115.
DIN (Deutsches Institut für Normung). (1994). “Testing of hardened concrete.” 1048-5, German Institute for Standardization, Berlin.
Donatello, S., Tyrer, M., and Cheeseman, C. R. (2010). “Comparison of test methods to assess pozzolanic activity.” Cem. Concr. Compos., 32(2), 121–127.
Duan, P., Shui, Z., Chen, W., and Shen, C. (2013). “Enhancing microstructure and durability of concrete from ground granulated blast furnace slag and metakaolin as cement replacement materials.” J. Mater. Res. Tech., 2(1), 52–59.
Durability Index Testing Procedure Manual. (2009). “Concrete durability index testing.” Cape Town, South Africa.
Frias, M., Ernesto, V., and Holmer, S. (2011). “Brazilian sugar cane bagasse ashes from the cogeneration industry as active pozzolans for cement manufacture.” Cem. Concr. Compos., 33(4), 490–496.
Frias, M., and Rodriguez, C. (2007). “Effect of incorporating ferroalloy industry wastes as complementary cementing materials on the properties of blended cement matrices.” Cem. Concr. Res., 30(3), 212–219.
Frias, M., Villar, C. E., Sanchez, R. M. I., and Valencia, M. E. (2005). “The effect that different pozzolanic activity methods has on the kinetic constants of the pozzolanic reaction in sugar cane straw ash/lime systems: Application of a kinetic-diffusive model.” Cem. Concr. Res., 35(11), 2137–2142.
Ganesan, K., Rajagopal, M., and Thangavel, K. (2007). “Evaluation of bagasse ash as supplementary cementitious material.” Cem. Concr. Compos., 29(6), 515–524.
Garcia, R., Vigil, V. R., Vegas, I., Frias, M., Sanchez, R. M. I. (2008). “The pozzolanic properties of paper sludge waste.” Constr. Build. Mater., 22(7), 1484–1490.
Githachuri, K., and Alexander, M. G. (2013). “Durability performance potential and strength of blended portland limestone cement concrete.” Cem. Concr. Compos., 39, 115–121.
Horsakulthai, V., Phiuvanna, S., and Kaenbud, W. (2011). “Investigation on the corrosion resistance of bagasse-rice husk-wood ash blended cement concrete by impressed voltage.” Constr. Build. Mater., 25(1), 54–60.
IS (Indian Standard). (2004). “Methods of test for pozzolanic materials.” 1727-04, Bureau of Indian Standards, New Delhi, India.
IS (Indian Standard). (2005). “Methods of physical tests for hydraulic cement. Determination of consistency of standard cement paste.” 4031—Part 4, Bureau of Indian Standards, New Delhi, India.
IS (Indian Standard). (2007). “Specification for coarse and fine aggregates from natural sources for concrete.” 383-07, Bureau of Indian Standards, New Delhi, India.
IS (Indian Standard). (2008). “Specification for 53 grade ordinary portland cement.” 12269-08, Bureau of Indian Standards, New Delhi, India.
Khatib, J. M., and Clay, R. M. (2003). “Absorption characteristics of metakaolin concrete.” Cem. Concr. Res., 34(1), 19–29.
Luxan, M. P., Madruga, F., and Saavedra, J. (1989). “Rapid evaluation of pozzolanic activity of natural products by conductivity measurement.” Cem. Concr. Res., 19(1), 63–68.
McCarter, W. J., and Tran, D. (1996). “Monitoring pozzolanic activity by direct activation with calcium hydroxide.” Constr. Build. Mater., 10(3), 179–184.
Morales, E. V., Cocina, E. V., Frias, M., Santos, S. F., and Savastano, H. (2009). “Effects of calcining conditions on the microstructure of sugar cane waste ashes (SCWA): Influence in the pozzolanic activation.” Cem. Concr. Compos., 31(1), 22–28.
Moropoulou, A., Bakolas, E., and Aggelakopoulou, E. (2004). “Evaluation of pozzolanic activity of natural and artificial pozzolans by thermal analysis.” Thermochim. Acta., 420(1–2), 135–140.
Otieno, M., Beushausen, H., and Alexander, M. (2014). “Effect of chemical composition of slag on chloride penetration resistance of concrete.” Cem. Concr. Compos., 46, 56–64.
Paya, J., Borrachero, M. V., Monzo, J., Mora, E. P., and Amahjour, F. (2001). “Enhanced conductivity measurement techniques for evaluation of fly ash pozzolanic activity.” Cem Concr. Res., 31(1), 41–49.
Paya, J., Monzo, J., Borrachero, M. V., Pinzon, L. D., and Ordonez, L. M. (2002). “Sugarcane bagasse ash (SCBA): Studies on its properties for reusing in concrete production.” J. Chem. Tech. Biotech., 77(3), 321–325.
Pontes, J., Silva, S. A., and Faria, A. (2013). “Evaluation of pozzolanic reactivity of artificial pozzolans.” Trans. Tech. Pub., 730–732, 433–438.
Quero, V. G. J., Martinez, F. M. L., Garcia, P. M., Tiburcio, C. G., and Nava, J. C. G. (2013). “Influence of sugar-cane bagasse ash and fly ash on the rheological behaviour of cement pastes and mortars.” Constr. Build. Mater., 40, 691–701.
Shekarchi, M., Bonakdar, A., Bakhshi, M., Mirdamadi, A., and Mobasher, B. (2010). “Transport properties in metakaolin blended concrete.” Constr. Build. Mater., 24(11), 2217–2223.
SIA (Schweizerischen Ingenieur- und Architektenverein). (2003). “Non-destructive site air-permeability test. Concrete construction—Complementary specifications.” SIA 162/1-E, Switzerland.
Singh, N. B., Singh, V. D., and Rai, S. (2000). “Hydration of bagasse ash-blended portland cement.” Cem. Concr. Res., 30(9), 1485–1488.
Somna, R., Jaturapitakkul, C., Rattanachu, P., and Chalee, W. (2012). “Effect of ground bagasse ash on mechanical and durability properties of recycled aggregate concrete.” Mater. Des., 36, 597–603.
Turanli, L., Uzal, B., and Bektas, F. (2005). “Effect of large amounts of natural pozzolan addition on properties of blended cements.” Cem. Concr. Res., 35(6), 1106–1111.
Walters, G. V. and Jones, T. R. (1991). “Effect of metakaolin on ASR in concrete manufactured with reactive aggregates.” Proc., Int. Conf. on the Durability of concrete, Vol. 2, American Concrete Institute, MI, 941–947.
Zhang, M. H., and Malhotra, V. M. (1996). “High-performance concrete incorporating rice husk ash as a supplementary cementing material.” Amer. Concr. Inst. Mater. J., 93(6), 629–636.
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© 2015 American Society of Civil Engineers.
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Received: Oct 20, 2014
Accepted: Apr 8, 2015
Published online: Jul 2, 2015
Discussion open until: Dec 2, 2015
Published in print: Feb 1, 2016
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