Technical Papers
Jan 21, 2015

Silica Aerogel–Glass Fiber Composites As Fire Shield for Steel Frame Structures

Publication: Journal of Materials in Civil Engineering
Volume 27, Issue 10

Abstract

In this study, glass fiber silica aerogel composites were fabricated and used to protect steel frames against fire. Glass-fiber-coated silica aerogel was synthesized by immersing glass fibers into silica sol. Following gel formation, surface modifications were carried out. Samples were dried carefully at relatively high temperatures and ambient pressure. The samples were then prepared at two different solution pH values and four different aging times. Brunauer-Emmett-Teller (BET) and Barrett-Joyner-Halenda (BJH) techniques have been employed to find the specific surface areas and pore diameters of the silica aerogel, formed as a coating on the glass fibers. Fourier transform infrared spectroscopy (FTIR) was used to investigate the chemical reactions. The coverage of fibers by the aerogel was also verified by scanning electron microscopy (SEM). To examine the composites’ fire resistance, a laboratory turbotorch and infrared thermometer have been used. Fire was applied directly to the composite surface while the temperature was read on the other side. The relationship between the fire resistivity of the composites and physical characteristics of the aerogel such, as porosity and specific surface area, is discussed.

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References

Aegerter, M. A., Leventis, N., and Koebel, M. M. (2011). Aerogels handbook, Springer, New York.
Al-Oweini, R., and El-Rassy, H. (2009). “Synthesis and characterization by FTIR spectroscopy of silica aerogels prepared using several Si(OR)4 and R″Si(OR′)3 precursors.” J. Mol. Struct., 919(1–3), 140–145.
Bangi, U. K., Rao, A. P., Hirashima, H., and Rao, A. V. (2009). “Physico-chemical properties of ambiently dried sodium silicate based aerogels catalyzed with various acids.” J. Sol-Gel Sci. Technol., 50(1), 87–97.
Bangi, U. K., Rao, A. V., and Rao, A. P. (2008). “A new route for preparation of sodium-silicate-based hydrophobic silica aerogels via ambient pressure drying.” J. Sci. Technol. Adv. Mater., 9(3), 035006.
Bheekhun, N., Abu Talib, A. R., and Roshdi, M. H. (2013). “Aerogels in aerospace: An overview.” J. Adv. Mater. Sci. Eng., 2013, 406065.
Biener, J., Baumann, T., and Wang, Y. (2007). “Ruthenium/aerogel nano composites via atomic laser deposition.” J. Nanotechnol., 18(5), 055303.
Brinker, C. J., and Scherer, G. W. (1990). Sol-gel science: The physics and chemistry of sol-gel processing, Gulf Professional Publishing, Academic Press, INC, London.
Fricke, J., and Tillotson, T. (1997). “Aerogels: Production, characterization, and applications.” J. Thin. Solid Films, 297(1–2), 212–223.
Gesser, H. D., and Goswami, P. C. (1989). “Aerogels and related porous materials.” J. Chem. Rev., 89(4), 765–788.
He, F., Zhao, H., Qu, X., Zhang, C., and Qiu, W. (2009). “Modified aging process for silica aerogel.” J. Mater. Process. Technol., 209(3), 1621–1626.
Jyoti, L., Gurav, A., and Venkateswara, R. (2009). “Physical properties of sodium silicate based silica aerogels prepared by single step sol-gel process dried at ambient pressure.” J. Alloys Compd., 476(1–2), 397–402.
Liao, Y., and Wu, H. (2012). “Engineering thermal and mechanical properties of flexible fiber-reinforced aerogel composites.” J. Sol-Gel Technol., 63(3), 445–456.
Pajonk, G. (2003). “Some applications of silica aerogels.” J. Colloid Polym. Sci., 281(7), 637–651.
Rao, A. P., Rao, A. V., and Pajonk, G. M. (2007). “Hydrophobic and physical properties of the ambient pressure dried silica aerogels with sodium silicate precursor using various surface modification agents.” J. Appl. Surf. Sci., 253(14), 6032–6040.
Sarawade, P. B., and Kim, J. K. (2010). “Preparation of hydrophobic mesoporous silica powder with a high specific surface area by surface modification of a wet-gel slurry and spray-drying.” J. Powder Technol., 197(3), 288–294.
Sarawade, P. B., and Kim, J. K. (2011). “Synthesis of hydrophilic and hydrophobic xerogels with superior properties using sodium silicate.” J. Microporous Mesoporous Mater., 139(1–3), 138–147.
Sarawade, P. B., Kim, J. K., Hilonga, A., and Kim, H. T. (2010). “Influence of aging conditions on textural properties of water-glass-based silica aerogels prepared at ambient pressure.” Korean J. Chem. Eng., 27(4), 1301–1309.
Scheuerpflug, P., Fricke, J., and Neubert, G. (1991). “Low-temperature thermal transport in silica aerogels.” J. Phys. D-Appl. Phys., 24(8), 1395–1403.
Soleimani Dorcheh, A., and Abbasi, M. H. (2008). “Silica aerogel: Synthesis, properties and characterization.” J. Mater. Process. Technol., 199(1–3), 10–26.
Tadjarodi, A., Haghverdi, M., and Mohammadi, V. (2012). “Preparation and characterization of nano-porous silica aerogel from rice husk ash by drying at atmospheric pressure.” J. Mater. Res. Bull., 47(9), 2584–2589.
Wang, L. J., Zhao, S. Y., and Yang, M. (2009). “Structural characteristics and thermal conductivity of ambient pressure dried silica aerogels with one-step solvent exchange/surface modification.” J. Mater. Chem. Phys., 113(1), 485–490.
Waseem, M., Mustafa, S., Naeem, A., Shah, K. H., Shah, I., and ul-Haq, I. (2009). “Synthesis and characterization of silica by solgel method.” J. Pak. Med. Soc., 3(1), 19–21.
Woignier, T., Primera, J., and Alaoui, A. (2011). “Mechanical behavior of nano composites aerogel.” J. Sol-Gel Sci., 58(2), 385–393.
Zhou, X., Zhong, L., and Xu, Y. (2008). “Surface modification of silica aerogels with trimethyl-chlorosilane in the ambient pressure drying.” J. Inorg. Mater., 44(9), 976–979.

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Go to Journal of Materials in Civil Engineering
Journal of Materials in Civil Engineering
Volume 27Issue 10October 2015

History

Received: Jul 15, 2014
Accepted: Dec 4, 2014
Published online: Jan 21, 2015
Discussion open until: Jun 21, 2015
Published in print: Oct 1, 2015

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Authors

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Siamak Motahari [email protected]
School of Chemical Engineering, College of Engineering, Univ. of Tehran, 1417613131 Tehran, Iran (corresponding author). E-mail: [email protected]
Amin Abolghasemi
School of Chemical Engineering, College of Engineering, Univ. of Tehran, 1417613131 Tehran, Iran.

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