Low Temperature Fracture Properties of Polyphosphoric Acid Modified Asphalt Mixtures
Publication: Journal of Materials in Civil Engineering
Volume 24, Issue 8
Abstract
The low temperature fracture properties of polyphosphoric acid (PPA) modified mixtures are evaluated and compared with those of polymer modified mixtures. The main objective is to determine whether PPA can partially or completely substitute traditional polymer modifiers, without adversely affecting the mixture’s resistance to thermal cracking. Laboratory compacted and field cored test samples from the Minnesota Road Research Project (MnROAD) were tested using traditional methods as well as newly developed fracture testing protocols: indirect tensile test (IDT), semicircular bending test (SCB), and disk-shaped compact tension test (DCT). The effects of temperature, air-void content, comma and long-term aging on low temperature fracture properties were analyzed; and field performance observations of the test cells from MnROAD were discussed. On the basis of the analysis, the fracture resistance of the PPA modified mixture is less than that of the SBS modified mixture. However, when PPA is used to substitute part of the SBS, a mixture with fracture resistance comparable to that of the mixture modified with SBS alone is produced.
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Acknowledgments
This research was sponsored by Federal Highway Administration National Pooled Fund Study TPF-5(132) led by the Minnesota Department of Transportation. This support is gratefully acknowledged. The authors also acknowledge Dr. Eshan Dave for providing DCT test results for all asphalt mixtures. The results and opinions presented are those of the authors and do not necessarily reflect those of the sponsoring agencies.
References
AASHTO. (2003). “Standard method of test for determining the creep compliance and strength of hot-mix asphalt (HMA) using indirect tensile test device.” T322-03, Washington, DC.
AASHTO. (2005). “Standard test method for the bulk specific gravity of compacted bituminous mixtures using saturated surface-dry specimens.” AASHTO T166, Washington, DC.
AASHTO. (2006). “Standard specification for mixture conditioning of hot mix asphalt (HMA).” AASHTO R30-02, Washington, DC.
Arnold, T. S., Youtcheff, J. S. Jr., and Needham, S. P. (2009). “Use of phosphoric acid as modifier for hot-mix asphalt.” Polyphosphoric Acid Modification of Asphalt Binders: A Workshop, Circular E-C160, Transportation Research Board, Washington, DC, 40–51.
ASTM. (2007). “Standard test method for determining fracture energy of asphalt–aggregate mixtures using the disk-shaped compact tension geometry.” D7313-07, West Conshohocken, PA.
Bishara, S. W., Mahoney, D., and McReynolds, R. L. (2001). “Modification of binder with acid: Advantages and disadvantages.” TRB Superpave Abstracts 2001: 80th Transportation Research Board Annual Meeting, Transportation Research Board, Washington, DC.
Clyne, T., Johnson, E., McGraw, J., and Reinke, G. (2009). “Field investigation of polyphosphoric acid modified binders at MnROAD.” Polyphosphoric Acid Modification of Asphalt Binders: A Workshop, Circular E-C 160, 115–130.
Dickinson, E. J. (1974). “The constitution and quality of paving grade asphalts produced by air blowing distillation residues of Kuwait and ‘light Arabian’ crude oil.” Conf. Proc., Association of Asphalt Paving Technologists, Transportation Research Board, Washington, DC, 132–161.
Fee, D., Maldonado, R., Reinke, G., and Romagosa, H. (2010). “Polyphosphoric acid modification of asphalt.” Transp. Res. Record: J. Transp. Res. Board, 2179, 49–57.
Giavarini, C., Mastrofini, D., Scarsella, M., Barré, L., and Espinat, D. (2000). “Macrostructure and rheological properties of chemically modified residues and bitumens.” Energy FuelsENFUEM, 14(2), 495–502.
Ho, S., Zanzotto, L., and MacLeod, D. (2001). “Impact of chemical modification on composition and properties of asphalt binders.” Proc., Canadian Technical Asphalt Association, Vol. 46, Polyscience, Quebec, Canada, 153–170.
Kodrat, I., Sohn, D., and Hesp, S. A. M. (2007). “Comparison of polyphosphoric acid-modified asphalt binders with straight and polymer-modified materials.” Transportation Research Record 1998, Transportation Research Board, Washington, DC, 47–55.
Li, X., and Marasteanu, M. O. (2004). “Evaluation of the low temperature fracture resistance of asphalt mixtures using the semi circular bend test.” J. Assoc. Asphalt Paving Technol.JAAPGG, 73, 401–426.
Li, X., and Marasteanu, M. O. (2010). “Using semi circular bending test to evaluate low temperature fracture resistance for asphalt concrete.” Exp. Mech.EXMCAZ, 50(7), 867–876.
Maldonado, R., Falkiewicz, M., and Bazi, G. (2006). “Asphalt modification with polyphosphoric acid.” Proc., Canadian Technical Asphalt Association, 51st Annual Meeting, 163–178.
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© 2012. American Society of Civil Engineers.
History
Received: Mar 31, 2011
Accepted: Jan 24, 2012
Published online: Jan 26, 2012
Published in print: Aug 1, 2012
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