TECHNICAL PAPERS
Nov 8, 2010

Coupled Reactive Transport Model for Heat and Density Driven Flow in CO2 Storage in Saline Aquifers

Publication: Journal of Hazardous, Toxic, and Radioactive Waste
Volume 15, Issue 4

Abstract

In this paper, a novel reactive diffusion-convection transport model is proposed to investigate the flow during different CO2 trappings in deep saline aquifers. Dissolved and immiscible CO2 have trapping times ranging from 1 million to several million years. The mineral trapping has a much longer temporal scale than the solubility trapping. The fine resolution of diffusion-to-advection characteristics is mapped by a corresponding implementation of finite-element numerical simulation. The diffusivity and reaction rate has prominent effects on diffusion-convection-reaction behaviors of the CO2-brine system. The 2-D numerical solutions give insight into the trapping evolution of injected CO2 in a deep subsurface environment.

Get full access to this article

View all available purchase options and get full access to this article.

Acknowledgments

Thanks to three anonymous reviewers for a very careful review of the manuscript and the critical comments for improvements. Thanks to Ming Zhang (GSJ) for the invitation to this special issue of the Journal of Hazardous, Toxic, and Radioactive Waste. This research was funded by five projects during 2003–2010, in particular, the BaiRenJiHua program of the Chinese Academy of Sciences.

References

Ackerer, P., Younes, A., and Mose, R. (1999). “Modeling variable density flow and solute transport in porous medium: 1. Numerical model and verification.” Transp. Porous Media, 35(3), 345–373.
Anderson, D. A. (1984). Computational fluid mechanics and heat transfer, McGraw-Hill Education, New York.
Bachu, S. (1995). “Flow of variable-density formation water in deep sloping aquifers: Review of methods of representation with case studies.” J. Hydrol. (Amsterdam), 164(1-4), 19–38.
Bachu, S. (2008). “CO2 storage in geological media: Role, means, status and barriers to deployment.” Prog. Energy Combust. Sci., 34(2), 254–273.
Bachu, S., and Adams, J. J. (2003). “Sequestration of CO2 in geological media in response to climate change: Capacity of deep saline aquifers to sequester CO2 in solution.” Energy Convers. Manage., 44(20), 3151–3175.
Bachu, S., Gunter, W. D., and Perkins, E. H. (1994). “Aquifer disposal of CO2: Hydrodynamic and mineral trapping.” Energy Convers. Manage., 35(4), 269–279.
Capone, F., and Rionero, S. (2005). “On the instability of double diffusive convection in porous media under boundary data periodic in space.” Trends and applications of mathematics to mechanics, S. Rionero and G. Romano, eds., Springer, Milan, 1–8.
Chen, F. (1991). “Throughflow effects on convective instability in superposed fluid and porous layers.” J. Fluid Mech., 231, 113–133.
Cooper, C. A., Glass, R. J., and Tyler, S. W. (1997). “Experimental investigation of the stability boundary for double-diffusive finger convection in a Hele-Shaw cell.” Water Resour. Res., 33(4), 517–526.
Cross, M., et al. (2007). “Computational modelling of multi-physics and multi-scale processes in parallel.” Int. J. Comput. Methods Eng. Sci. Mech., 8(2), 63–74.
Diersch, H.-J. (1988). “Finite element modelling of recirculating density-driven saltwater intrusion processes in groundwater.” Adv. Water Resour., 11(1), 25–43.
Diersch, H. J. G., and Kolditz, O. (2002). “Variable-density flow and transport in porous media: Approaches and challenges.” Adv. Water Resour., 25(8-12), 899–944.
Elder, J. W. (1967). “Transient convection in a porous medium.” J. Fluid Mech., 27(3), 609–623.
Ennis-King, J., and Paterson, L. (2007). “Coupling of geochemical reactions and convective mixing in the long-term geological storage of carbon dioxide.” Int. J. Greenhouse Gas Control, 1(1), 86–93.
Ennis-King, J. P., and Paterson, L. (2005). “Role of convective mixing in the long-term storage of carbon dioxide in deep saline formations.” SPE Journal, 10(3), 349–356.
Farajzadeh, R., Salimi, H., Zitha, P. L. J., and Bruining, H. (2007). “Numerical simulation of density-driven natural convection in porous media with application for CO2 injection projects.” Int. J. Heat Mass Transfer, 50(25-26), 5054–5064.
Freedman, V., and Ibaraki, M. (2002). “Effects of chemical reactions on density-dependent fluid flow: On the numerical formulation and the development of instabilities.” Adv. Water Resour., 25(4), 439–453.
Hassanzadeh, H., Pooladi-Darvish, M., and Keith, D. W. (2007). “Scaling behavior of convective mixing, with application to geological storage of CO2.” AIChE J., 53(5), 1121–1131.
Hesse, M., Riaz, A., Tchelepi, H., and Orr, L. (2006). “Natural convection during CO2-storage in aquifers.” The Global Climate and Energy Project (GCEP) Research Symp., Stanford University, Palo Alto, CA.
Hidalgo, J. J., and Carrera, J. (2009). “Effect of dispersion on the onset of convection during CO2 sequestration.” J. Fluid Mech., 640, 441–452.
Hidalgo, J. J., Carrera, J., and Medina, A. (2009). “Role of salt sources in density-dependent flow.” Water Resour. Res., 45(5), W05503.
Hughes, J. D., Sanford, W. E., and Vacher, H. L. (2005). “Numerical simulation of double-diffusive finger convection.” Water Resour. Res., 41(1), W01019.
Johnson, J. W., Nitao, J., Steefel, C., and Knaus, K. (2001). “Reactive transport modeling of geologic CO2 sequestration in saline aquifers: The influence of intra-aquifer shales and the relative effectiveness of structural solubility, and mineral trapping during prograde and retrograde sequestration.” 1st National Conf. on Carbon Sequestration, National Energy and Technology Laboratory, USA, Washington, DC.
Knabner, P., Tapp, C., and Thiele, K. (2001). “Adaptivity in the finite volume discretization of variable density flows in porous media.” Phys. Chem. Earth B, 26(4), 319–324.
Kolditz, O., Ratke, R., Diersch, H.-J. G., and Zielke, W. (1998). “Coupled groundwater flow and transport: 1. Verification of variable density flow and transport models.” Adv. Water Resour., 21(1), 27–46.
Li, Q., and Ito, K. (2008). “An integrated thermal-hydraulic-mechanical-chemical-biological (THMCB) multiscale and multiphysics coupled system with applications to geological disposal problems.” AIST Symposium: The Annual Conf. of GREEN 2008, National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba, Japan.
Li, Q., Wu, Z. S., and Li, X. C. (2009). “Prediction of CO2 leakage during sequestration into marine sedimentary strata.” Energy Convers. Manage., 50(3), 503–509.
Li, X. C., Liu, Y. F., Bai, B., and Fang, Z. M. (2006). “Ranking and screening of CO2 saline aquifer storage zones in China.” Chin. J. Rock Mech. Eng., 25(5), 963–968 (in Chinese).
Lie, K.-A., Aarnes, J. E., Kippe, V., and Krogstad, S. (2005). “Multiscale methods for flow in porous media.” Rakenteiden Mekaniikka (J. Structural Mechanics), 38(3), 19–25.
Manning, D. A. C. (2008). “Biological enhancement of soil carbonate precipitation: Passive removal of atmospheric CO2.” Mineral Mag., 72(2), 639–649.
Marini, L. (2007). Geological sequestration of carbon dioxide: Thermodynamics, kinetics, and reaction path modeling, Elsevier, Boston.
Metz, B., Davidson, O., de Coninck, H., Loos, M., and Meyer, L. (2005). IPCC 2005: IPCC special report on carbon dioxide capture and storage, Cambridge University Press, Cambridge, UK, 431.
Mojtabi, A., and Charrier-Mojtabi, M.-C. (2000). “Double-diffusive convection in porous media.” Handbook of porous media, K. Vafai, ed., Marcel Dekker, Inc., New York, 559–603.
Oldenburg, C. M., and Pruess, K. (1995). “Dispersive transport dynamics in a strongly coupled groundwater-brine flow system.” Water Resour. Res., 31(2), 289–302.
Ozgur, E., and Gumrah, F. (2009). “Diffusive and convective mechanisms during CO2 sequestration in aquifers.” Energy Sources, Part A, 31(8), 698–709.
Perrochet, P., and Berod, D. (1993). “Stability of the standard Crank-Nicolson-Galerkin scheme applied to the diffusion-convection equation: Some new insights.” Water Resour. Res., 29(9), 3291–3297.
Pinder, G. F., and Gray, W. G. (1977). Finite element simulation in surface and subsurface hydrology, Academic Press, New York.
Pringle, S. E., Glass, R. J., and Cooper, C. A. (2002). “Double-diffusive finger convection in a Hele-Shaw cell: An experiment exploring the evolution of concentration fields, length scales and mass transfer.” Transp. Porous Media, 47(2), 195–214.
Pruess, K. (2008). Numerical modeling studies of the dissolution-diffusion-convection process during CO2 storage in saline aquifers, Lawrence Berkeley National Laboratory, Berkeley, CA, 33.
Pruess, K., Xu, T. F., Apps, J., and Garcia, J. (2003). “Numerical modeling of aquifer disposal of CO2.” SPE J., 8(1), 49–60.
Riaz, A., Hesse, M., Tchelepi, H. A., and Orr, F. M. (2006). “Onset of convection in a gravitationally unstable diffusive boundary layer in porous media.” J. Fluid Mech., 548, 87–111.
Shen, C. Y. (1989). “The evolution of the double-diffusive instability: Salt fingers.” Phys. Fluids A, 1(5), 829–844.
Simmons, C. T., Pierini, M. L., and Hutson, J. L. (2002). “Laboratory investigation of variable-density flow and solute transport in unsaturated–saturated porous media.” Transp. Porous Media, 47(2), 215–244.
Thiele, M., and Diersch, H.-J. (1986). “‘Overshooting’ effects due to hydrodispersive mixing of saltwater layers in aquifers.” Adv. Water Resour., 9(1), 24–33.
Zhang, Y., and Dawe, R. (1998). “The kinetics of calcite precipitation from a high salinity water.” Appl. Geochem., 13(2), 177–184.
Zheng, C., and Bennett, G. D. (2002). Applied contaminant transport modeling, Wiley, New York.

Information & Authors

Information

Published In

Go to Journal of Hazardous, Toxic, and Radioactive Waste
Journal of Hazardous, Toxic, and Radioactive Waste
Volume 15Issue 4October 2011
Pages: 251 - 258

History

Received: Jun 22, 2010
Accepted: Oct 12, 2010
Published online: Nov 8, 2010
Published in print: Oct 1, 2011

Permissions

Request permissions for this article.

Authors

Affiliations

Research Scientist, Geological Survey of Japan (GSJ), National Institute of Advanced Industrial Science and Technology (AIST), Central 7, Higashi 1-1-1, Tsukuba 305-8567, Japan; and Professor, State Key Laboratory of Geomechanics and Geotechnical Engineering, Institute of Rock and Soil Mechanics, Chinese Academy of Sciences (CAS), Wuhan, China. E-mail: [email protected]

Metrics & Citations

Metrics

Citations

Download citation

If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download.

Cited by

View Options

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Media

Figures

Other

Tables

Share

Share

Copy the content Link

Share with email

Email a colleague

Share