Technical Papers
Jan 24, 2022

Calcium Hypochlorite Pretreatment Enhances Waste-Activated Sludge Degradation during Aerobic Digestion

Publication: Journal of Environmental Engineering
Volume 148, Issue 4

Abstract

Conventional activated sludge processes, as the main biological treatment approach for municipal wastewater treatment in centralized wastewater treatment plants (WWTP), generate a large amount of waste-activated sludge (WAS) that needs to be managed before disposal. However, the degradation of WAS is usually limited by the slow hydrolysis rate and low biodegradable rate. Here, an effective pretreatment strategy using calcium hypochlorite treating waste-activated sludge before aerobic digestion was explored. Performance results showed that after the pretreatment with 0.1  gCa(ClO)2 per gram of total solids (TS), volatile solids (VS) in WAS were reduced by 65.05%±2.68% after 20 days of aerobic digestion, nearly twice the reduction of VS in un-pretreated WAS. The best treatment conditions under tested experiment conditions were 12 h of WAS pretreatment process with 0.1  gCa(ClO)2per1  g TS and 12 days hydraulic retention time (HRT) of aerobic digestion. Kinetic model analysis revealed that the VS reduction of WAS during aerobic digestion was enhanced by the Ca(ClO)2 pretreatment, likely through cell lysis and extracellular polymeric substances (EPS) decomposition. Moreover, microbial community analysis revealed that the relative abundance of certain bacteria (e.g., Xanthomonadaceae, Saprospirales, and Cytophagaceae) increased, which can be attributed to the change of the chemical and biological environment in the aerobic digesters after pretreatment. This study demonstrated the feasibility of applying calcium hypochlorite pretreatment in WAS aerobic digestion to improve sludge digestibility and volume reduction.

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Data Availability Statement

All data, models, and code generated or used during the study appear in the published article.

Acknowledgments

The authors acknowledge financial support from a Natural Sciences and Engineering Research Council of Canada (NSERC) Discovery Grant, the Canada Research Chair (CRC) in Future Water Services (Y. Liu), the Alberta Innovates Clean Technology Facilities Support Program, and the China Scholarship Council (CSC) Ph.D. scholarship (A. Mou and N. Yu).

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Go to Journal of Environmental Engineering
Journal of Environmental Engineering
Volume 148Issue 4April 2022

History

Received: Sep 9, 2021
Accepted: Oct 28, 2021
Published online: Jan 24, 2022
Published in print: Apr 1, 2022
Discussion open until: Jun 24, 2022

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Ph.D. Student, Dept. of Civil and Environmental Engineering, Univ. of Alberta, 6-106 Natural Resources Engineering Facility, Markin/CNRL, Edmonton, AB, Canada T6G 1H9. Email: [email protected]
Najiaowa Yu [email protected]
Ph.D. Candidate, Dept. of Civil and Environmental Engineering, Univ. of Alberta, 6-029 Natural Resources Engineering Facility, Markin/CNRL, Edmonton, AB, Canada T6G 1H9. Email: [email protected]
Postdoctoral Fellow, Dept. of Civil and Environmental Engineering, Univ. of Alberta, Donadeo Innovation Centre for Engineering, Edmonton, AB, Canada T6G 2E1. Email: [email protected]
Huijuan Sun [email protected]
Ph.D. Candidate, Dept. of Civil and Environmental Engineering, Univ. of Alberta, 6-029 Natural Resources Engineering Facility, Markin/CNRL, Edmonton, AB, Canada T6G 1H9. Email: [email protected]
Professor, Dept. of Civil and Environmental Engineering, Univ. of Alberta, 7-263 Donadeo Innovation Centre for Engineering, Edmonton, AB, Canada T6G 1H9 (corresponding author). ORCID: https://orcid.org/0000-0001-5058-8373. Email: [email protected]

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  • Enhanced hydrogen production from sludge anaerobic fermentation by combined freezing and calcium hypochlorite pretreatment, Science of The Total Environment, 10.1016/j.scitotenv.2022.160134, 858, (160134), (2023).

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