Simultaneous Desulfurization and Denitrification of Mud-Phosphorus Emulsion
Publication: Journal of Environmental Engineering
Volume 146, Issue 7
Abstract
In this study, a new technology was proposed for removing and NO from industrial flue gas via wet catalytic oxidation technology that uses a mud-phosphorus emulsion as the absorption liquid. In this study, the optimal reaction temperature, gas rate, oxygen content, and mud-phosphorus emulsion solid-to-liquid ratio were determined. At a reaction temperature of 60°C, the gas flow rate was , the oxygen content was 20%, and the solid-to-liquid ratio in the mud-phosphorus emulsion was . When the system was operated for 880 min, the desulfurization rate was 99%; when the system was operated for 860 min, the denitrification rate was still 99%, and the desulfurization and denitrification effects were ideal. The proposed technology opens new avenues for the purification and resource utilization of sulfur-containing flue gas.
Get full access to this article
View all available purchase options and get full access to this article.
Data Availability Statement
All data included in this study are available upon request by contact with the corresponding author.
Acknowledgments
This study was funded by the National Natural Science Foundation of China (Grant No. 51568067) and the Applied Basic Research Surface of Yunnan Province (Grant No. 2016FB100). We are very grateful to all members of the project team for their help.
References
Biswas, R., S. Devotta, T. Chakrabarti, and R. A. Pandey. 2005. “Flue gas desulfurization: Physicochemical and biotechnological approaches.” Crit. Rev. Environ. Sci. Technol. 35 (6): 571–622. https://doi.org/10.1080/10643380500326374.
Chang, S. G., and G. C. Lee. 1992. “LBL PhoSNOx process for combined removal of and from flue gas.” Environ. Prog. 11 (1): 66–73. https://doi.org/10.1002/ep.670110120.
Chinese Standards. 2000. Determination of sulfur dioxide in exhaust from stationary pollution sources. HJ T56. Beijing: Chinese Standard.
Chinese Standards. 2009. Determination of nitrogen oxides in ambient air. HJ 479. Beijing: Chinese Standard.
Chinese Standards. 2011. China’s thermal power factories emission standards for atmospheric pollutants. GB13223. Beijing: Chinese Standards.
del Valle-Zermeño, R., M. Niubó, J. Formosa, M. Guembe, J. A. Aparicio, and J. M. Chimenos. 2015. “Synergistic effect of the parameters affecting wet flue gas desulfurization using magnesium oxides by-products.” Chem. Eng. J. 262 (Feb): 268–277. https://doi.org/10.1016/j.cej.2014.09.085.
Huss, A., P. K. Lim, and C. A. Eckert. 1982. “Oxidation of aqueous sulfur dioxide. 2. High-pressure studies and proposed reaction mechanisms.” J. Phys. Chem. 86 (21): 4229–4233. https://doi.org/10.1021/j100218a028.
Kang, Y. S., S. S. Kim, and S. C. Hong. 2015. “Combined process for removal of SO2, NOx, and particulates to be applied to a 1.6-MWe pulverized coal boiler.” J. Ind. Eng. Chem. 30 (Oct): 197–203. https://doi.org/10.1016/j.jiec.2015.05.022.
Li, M., B. F. Peng, L. S. Wei, Z. J. Hu, and M. Xu. 2015. “Research on the simultaneous desulfurization and denitrification of fumes by combining ozone oxidation and the double alkali method.” Adv. Mater. Res. 1073-1076: 759–763. https://doi.org/10.4028/www.scientific.net/AMR.1073-1076.759.
Liu, D. K., D.-X. Shen, and S.-G. Chang. 1991. “Removal of and from aqueous emulsions of yellow phosphorus and alkali.” Environ. Sci. Technol. 25 (1): 55–60. https://doi.org/10.1021/es00013a003.
Shen, D. X. 2002. “Simultaneous purification of and in flue gas with alkali yellow phosphorus emulsion.” China Environ. Prot. Ind. 8: 27–28.
Sun, C., N. Zhao, H. Wang, and Z. Wu. 2015. “Simultaneous absorption of NOx and using magnesia slurry combined with ozone oxidation.” Energy Fuels 29 (5): 3276–3283. https://doi.org/10.1021/acs.energyfuels.5b00229.
Wang, F., L. J. Jia, J. Y. Gao, T. C. Liu, and P. Ning. 2018. “Liquid phase catalytic purification of nitrogen oxides by mud and phosphorus.” Chem. Environ. Prot. 38 (1): 72–76. https://doi.10.3969/j.issn.1006-1878.2018.01.000.
Information & Authors
Information
Published In
Copyright
©2020 American Society of Civil Engineers.
History
Received: May 4, 2019
Accepted: Dec 3, 2019
Published online: May 15, 2020
Published in print: Jul 1, 2020
Discussion open until: Oct 15, 2020
Authors
Metrics & Citations
Metrics
Citations
Download citation
If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download.