Technical Papers
Apr 26, 2019

Numerical Model for Decontamination of Organic Contaminants in Polyethylene Drinking Water Pipes in Premise Plumbing by Flushing

Publication: Journal of Environmental Engineering
Volume 145, Issue 7

Abstract

Polymeric materials such as polyethylene are used extensively for indoor drinking water applications. These materials are subject to permeation by organic compounds such as those found in petroleum products and industrial chemicals, which can result in water quality issues with potential health effects. Although flushing is a common decontamination technique, disagreements and knowledge gaps in the scientific literature complicate prediction of how much flushing may be required to address organic contamination incidents. This paper utilizes a numerical solution to the diffusion equation to predict flushing decontamination times for toluene in cross-linked polyethylene tubing. Results suggest that for premise plumbing materials typically used for indoor drinking water applications, contaminated polyethylene tubing can be resistant to decontamination by flushing, possibly requiring days of continuous flushing to achieve contaminant removal to below regulatory levels.

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Acknowledgments

The authors would like to thank Jon Burkhardt and Toby Sanan for participating in helpful discussions related to practical matters of the laboratory work and presentation of results. The authors would also like to thank Michael Elovitz for providing valuable insight regarding equipment and instrumentation. The authors also wish to thank the anonymous peer reviewers for their insightful comments, which greatly enhanced this paper. The US Environmental Protection Agency through its Office of Research and Development funded and collaborated in the research described here. It has been subjected to the Agency’s review and has been approved for publication. Note that approval does not signify that the contents necessarily reflect the views of the Agency. Any mention of trade names, products, or services does not imply an endorsement by the EPA or the US Government. EPA does not endorse any commercial products, services, or enterprises. This project was supported in part by an appointment to the Research Participation Program at USEPA, administered by the Oak Ridge Institute for Science and Education through an interagency agreement between the US Department of Energy and EPA.

References

Bonoli, L., and P. Witherspoon. 1968. “Diffusion of aromatic and cycloparaffin hydrocarbons in water from 2 to 60 deg.” J. Phys. Chem. 72 (7): 2532–2534. https://doi.org/10.1021/j100853a045.
Carslaw, H. S., and J. C. Jaeger. 1959. Conduction of heat in solids. Oxford, UK: Clarendon Press.
Casteloes, K. S., R. Brazeau, and A. Whelton. 2015. “Decontaminating chemically contaminated residential premise plumbing systems by flushing.” Environ. Sci. Water Res. Technol. 1 (6): 787–799. https://doi.org/10.1039/C5EW00118H.
Casteloes, K. S., G. P. Mendis, H. K. Avins, J. A. Howarter, and A. J. Whelton. 2017. “The interaction of surfactants with plastic and copper plumbing materials during decontamination.” J. Hazard. Mater. 325: 8–16. https://doi.org/10.1016/j.jhazmat.2016.11.067.
Coleman, T. F., and Y. Li. 1996a. “A reflective Newton method for minimizing a quadratic function subject to bounds on some of the variables.” SIAM J. Optim. 6 (4): 1040–1058. https://doi.org/10.1137/S1052623494240456.
Coleman, T. F., and Y. Li. 1996b. “An interior trust region approach for nonlinear minimization subject to bounds.” SIAM J. Optim. 6 (2): 418–445. https://doi.org/10.1137/0806023.
Crank, J. 1975. The mathematics of diffusion. Oxford, UK: Clarendon Press.
Huang, X., S. Andry, J. Yaputri, D. Kelly, D. A. Ladner, and A. J. Whelton. 2017. “Crude oil contamination of plastic and copper drinking water pipes.” J. Hazard. Mater. 339: 385–394. https://doi.org/10.1016/j.jhazmat.2017.06.015.
Jones, D., and R. K. Rowe. 2016. “BTEX migration through various geomembranes and vapor barriers.” J. Geotech. Geoenviron. Eng. 142 (10): 04016044. https://doi.org/10.1061/(ASCE)GT.1943-5606.0001502.
Jones, E., T. Oliphant, and P. Peterson. 2014. “SciPy: Open source scientific tools for Python, 2014.” Accessed August 12, 2018. http://www.scipy.org.
Joo, J. C., J. Y. Kim, and K. Nam. 2004. “Mass transfer of organic compounds in dilute aqueous solutions into high density polyethylene geomembranes.” J. Environ. Eng. 130 (2): 175–183. https://doi.org/10.1061/(ASCE)0733-9372(2004)130:2(175).
Joo, J. C., K. Nam, and J. Y. Kim. 2005. “Estimation of mass transport parameters of organic compounds through high density polyethylene geomembranes using a modified double-compartment apparatus.” J. Environ. Eng. 131 (5): 790–799. https://doi.org/10.1061/(ASCE)0733-9372(2005)131:5(790).
Langtangen, H. P. 2013. Computational partial differential equations: Numerical methods and diffpack programming. Berlin: Springer.
Mao, F., S. K. Ong, and J. A. Gaunt. 2015. “Modeling benzene permeation through drinking water high density polyethylene (HDPE) pipes.” J. Water Health 13 (3): 758–772. https://doi.org/10.2166/wh.2015.183.
McWatters, R. S., A. Rutter, and R. K. Rowe. 2016. “Geomembrane applications for controlling diffusive migration of petroleum hydrocarbons in cold region environments.” J. Environ. Manage. 181: 80–94. https://doi.org/10.1016/j.jenvman.2016.05.065.
Park, J. K., and M. Nibras. 1993. “Mass flux of organic chemicals through polyethylene geomembranes.” Water Environ. Res. 65 (3): 227–237. https://doi.org/10.2175/WER.65.3.6.
Park, J. K., J. P. Sakti, and J. A. Hoopes. 1996. “Transport of organic compounds in thermoplastic geomembranes. I: Mathematical model.” J. Environ. Eng. 122 (9): 800–806. https://doi.org/10.1061/(ASCE)0733-9372(1996)122:9(800).
Park, M.-G., C. H. Benson, and T. B. Edil. 2012. “Comparison of batch and double compartment tests for measuring VOC transport parameters in geomembranes.” Geotext. Geomembr. 31: 15–30. https://doi.org/10.1016/j.geotexmem.2011.09.001.
Park, M.-G., T. B. Edil, and C. H. Benson. 2011. “Modeling volatile organic compound transport in composite liners.” J. Geotech. Geoenviron. Eng. 138 (6): 641–657. https://doi.org/10.1061/(ASCE)GT.1943-5606.0000630.
Sangam, H. P., and R. K. Rowe. 2001. “Migration of dilute aqueous organic pollutants through HDPE geomembranes.” Geotext. Geomembr. 19 (6): 329–357. https://doi.org/10.1016/S0266-1144(01)00013-9.
Selleck, R. E., and B. J. Marinas. 1991. “Analyzing the permeation of organic chemicals through plastic pipes.” J. Am. Water Works Assoc. 83 (7): 92–97. https://doi.org/10.1002/j.1551-8833.1991.tb07184.x.
Setnickova, K., Z. Wagner, R. D. Noble, and P. Uchytil. 2011. “Semi-empirical model of toluene transport in polyethylene membranes based on the data using a new type of apparatus for determining gas permeability, diffusivity and solubility.” Chem. Eng. Sci. 66 (22): 5566–5574. https://doi.org/10.1016/j.ces.2011.07.037.
Skjevrak, I., A. Due, K. O. Gjerstad, and H. Herikstad. 2003. “Volatile organic components migrating from plastic pipes (HDPE, PEX and PVC) into drinking water.” Water Res. 37 (8): 1912–1920. https://doi.org/10.1016/S0043-1354(02)00576-6.
Tang, J., D. L. Gallagher, and A. M. Dietrich. 2012. “Predicting permeation of organic contaminants into polyethylenes.” J. Environ. Eng. 139 (2): 205–212. https://doi.org/10.1061/(ASCE)EE.1943-7870.0000644.
Whelton, A. J., A. M. Dietrich, and D. L. Gallagher. 2010. “Contaminant diffusion, solubility, and material property differences between HDPE and PEX potable water pipes.” J. Environ. Eng. 136 (2): 227–237. https://doi.org/10.1061/(ASCE)EE.1943-7870.0000147.
Whelton, A. J., L. McMillan, M. Connell, K. M. Kelley, J. P. Gill, K. D. White, R. Gupta, R. Dey, and C. Novy. 2015. “Residential tap water contamination following the freedom industries chemical spill: Perceptions, water quality, and health impacts.” Environ. Sci. Technol. 49 (2): 813–823. https://doi.org/10.1021/es5040969.
Whelton, A. J., and T. Nguyen. 2013. “Contaminant migration from polymeric pipes used in buried potable water distribution systems: A review.” Crit. Rev. Environ. Sci. Technol. 43 (7): 679–751. https://doi.org/10.1080/10643389.2011.627005.

Information & Authors

Information

Published In

Go to Journal of Environmental Engineering
Journal of Environmental Engineering
Volume 145Issue 7July 2019

History

Received: Sep 11, 2018
Accepted: Nov 28, 2018
Published online: Apr 26, 2019
Published in print: Jul 1, 2019
Discussion open until: Sep 26, 2019

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Authors

Affiliations

Levi M. Haupert [email protected]
ORISE Fellow, Oak Ridge Institute for Science and Education Research Program, USEPA, 26 Martin Luther King Dr. West, Cincinnati, OH 45268 (corresponding author). Email: [email protected]
Matthew L. Magnuson [email protected]
Research Chemist, National Homeland Security Research Center, Office of Research and Development, US Environmental Protection Agency, 26 West Martin Luther King Dr., Cincinnati, OH 45268. Email: [email protected]

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