Effect of Mechanochemical Processing on Adsorptive Properties of Blast Furnace Slag
Publication: Journal of Environmental Engineering
Volume 139, Issue 12
Abstract
Mechanochemistry is of greater interest at present because of its application in the transformation of waste. In this study, an innovative application is proposed, namely to mechanochemically treat blast furnace slag so that it can be recycled into a low-cost adsorbent. In particular, the way this industrial waste adsorbs methylene blue present in aqueous solutions has been dealt with in detail. To this end, the slag was treated in a planetary mill at different charge ratios, rotational speeds and milling times, and then characterized by laser granulometry, porosimetric, X-ray diffraction (XRD), and scanning electron microscopy (SEM) analyses. These investigations shed light on the interrelationships between milling conditions and the physico-chemical characteristics of the slag. Next, the most interesting samples to submit to the following adsorption equilibrium and kinetic tests were chosen. These runs were conducted at different dye initial concentrations and adsorption times, and the results were interpreted according to the previously analyzed characteristics of the slag. Furthermore, adsorption data was postprocessed to obtain values for the equilibrium and kinetic constants, the separation factor, the removal efficiency, the initial adsorption rate, and the characteristic adsorption times.
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Acknowledgments
The authors wish to thank Mrs. Lucia Testa (University of Naples), Dr. Massimo Urciuolo and Mr. Sabato Russo (IRC–CNR), and Dr. Giuseppina Carotenuto (University of Naples) for their help in some solid characterization. Gratitude is also expressed to Dr. Marco Balsamo and Mrs. Martina Orefice (University of Naples) for the useful discussion, and to the Linguistic Center of the University of Naples for the assistance in the language editing.
References
Andini, S., Bolognese, A., Formisano, D., Manfra, M., Montagnaro, F., and Santoro, L. (2012). “Mechanochemistry of ibuprofen pharmaceutical.” Chemosphere, 88(5), 548–553.
Andini, S., Cioffi, R., Colangelo, F., Montagnaro, F., and Santoro, L. (2008). “Adsorption of chlorophenol, chloroaniline and methylene blue on fuel oil fly ash.” J. Hazard. Mater., 157(2–3), 599–604.
Aresta, M., Caramuscio, P., De Stefano, L., and Pastore, T. (2003). “Solid state dehalogenation of PCBs in contaminated soil using .” Waste Manage., 23(4), 315–319.
Balsamo, M., Di Natale, F., Erto, A., Lancia, A., Montagnaro, F., and Santoro, L. (2010). “Arsenate removal from synthetic wastewater by adsorption onto fly ash.” Desalination, 263(1–3), 58–63.
Balsamo, M., Di Natale, F., Erto, A., Lancia, A., Montagnaro, F., and Santoro, L. (2011). “Cadmium adsorption by coal combustion ashes-based sorbents—relationship between sorbent properties and adsorption capacity.” J. Hazard. Mater., 187(1–3), 371–378.
Balsamo, M., Di Natale, F., Erto, A., Lancia, A., Montagnaro, F., and Santoro, L. (2012). “Steam- and carbon dioxide-gasification of coal combustion ash for liquid phase cadmium removal by adsorption.” Chem. Eng. J., 207–208, 66–71.
Boldyrev, V. V. (1995). “Mechanochemistry and sonochemistry.” Ultrason. Sonochem., 2(2), S143–S145.
Cao, G., Doppiu, S., Monagheddu, M., Orrù, R., Sannia, M., and Cocco, G. (1999). “Thermal and mechanochemical self-propagating degradation of chloro-organic compounds: The case of hexachlorobenzene over calcium hydride.” Ind. Eng. Chem. Res., 38(9), 3218–3224.
Caramuscio, P., De Stefano, L., Seggiani, M., Vitolo, S., and Narducci, P. (2003). “Preparation of activated carbons from heavy-oil fly ashes.” Waste Manage., 23(4), 345–351.
Cioffi, R., et al. (2008). “TG, FT-IR and NMR characterization of contaminated alumina and silica after mechanochemical treatment.” Chemosphere, 70(6), 1068–1076.
Cioffi, R., Colangelo, F., Montagnaro, F., and Santoro, L. (2011). “Manufacture of artificial aggregate using MSWI bottom ash.” Waste Manage., 31(2), 281–288.
Colangelo, F., Cioffi, R., Montagnaro, F., and Santoro, L. (2012). “Soluble salt removal from MSWI fly ash and its stabilization for safer disposal and recovery as road basement material.” Waste Manage., 32(6), 1179–1185.
Field, L. D., Sternhell, S., and Wilton, H. V. (1997). “Mechanochemistry of some hydrocarbons.” Tetrahedron, 53(11), 4051–4062.
Foo, K. Y., and Hameed, B. H. (2010). “Insights into the modeling of adsorption isotherms systems.” Chem. Eng. J., 156(1), 2–10.
Hall, A. K., Harrowfield, J. M., Hart, R. J., and McCormick, P. G. (1996). “Mechanochemical reaction of DDT with calcium oxide.” Environ. Sci. Technol., 30(12), 3401–3407.
Itskos, G., Koukouzas, N., Vasilatos, C., Megremi, I., and Moutsatsou, A. (2010). “Comparative uptake study of toxic elements from aqueous media by the different particle-size-fractions of fly ash.” J. Hazard. Mater., 183(1–3), 787–792.
Koukouzas, N., Vasilatos, C., Itskos, G., Mitsis, I., and Moutsatsou, A. (2010). “Removal of heavy metals from wastewater using CFB-coal fly ash zeolitic materials.” J. Hazard. Mater., 173(1–3), 581–588.
Kumar, S., Kumar, R., and Bandopadhyay, A. (2006). “Innovative methodologies for the utilisation of wastes from metallurgical and allied industries.” Resour. Conserv. Recy., 48(4), 301–314.
Leaist, D. G. (1988). “The effects of aggregation, counterion binding, and added NaCl on diffusion of aqueous methylene blue.” Can. J. Chem., 66(9), 2452–2457.
López-Delgado, A., Pérez, C., and López, F. A. (1998). “Sorption of heavy metals on blast furnace sludge.” Water Res., 32(4), 989–996.
Montagnaro, F., Salatino, P., and Scala, F. (2010). “The influence of temperature on limestone sulfation and attrition under fluidized bed combustion conditions.” Exp. Therm. Fluid Sci., 34(3), 352–358.
Montagnaro, F., Salatino, P., Scala, F., and Chirone, R. (2008). “An assessment of water and steam reactivation of a fluidized bed spent sorbent for enhanced capture.” Powder Technol., 180(1–2), 129–134.
Montagnaro, F., and Santoro, L. (2009). “Reuse of coal combustion ashes as dyes and heavy metal adsorbents: Effect of sieving and demineralization on waste properties and adsorption capacity.” Chem. Eng. J., 150(1), 174–180.
Montagnaro, F., and Santoro, L. (2010). “Non-conventional adsorbents for the removal of metal compounds from wastewaters.” Chapter 11, Sorption processes and pollution, G. Crini and P. M. Badot, eds., Presses Universitaires de Franche-Comté, Besançon, France, 297–312.
Montinaro, S., Concas, A., Pisu, M., and Cao, G. (2008). “Immobilization of heavy metals in contaminated soils through ball milling with and without additives.” Chem. Eng. J., 142(3), 271–284.
Nehrenheim, E., and Gustafsson, J. P. (2008). “Kinetic sorption modelling of Cu, Ni, Zn, Pb and Cr ions to pine bark and blast furnace slag by using batch experiments.” Bioresource Technol., 99(6), 1571–1577.
Oguz, E. (2004). “Removal of phosphate from aqueous solution with blast furnace slag.” J. Hazard. Mater., 114(1–3), 131–137.
Palaniandy, S., Azizli, K. A. M., Hussin, H., and Hashim, S. F. S. (2008). “Mechanochemistry of silica in jet milling.” J. Mater. Process. Tech., 205(1–3), 119–127.
Plescia, P., et al. (2003). “Mechanochemical treatment to recycling asbestos-containing waste.” Waste Manage., 23(3), 209–218.
Ramakrishna, K. R., and Viraraghavan, T. (1997). “Use of slag for dye removal.” Waste Manage., 17(8), 483–488.
Rudzinski, W., and Plazinski, W. (2006). “Kinetics of solute adsorption at solid/solution interfaces: A theoretical development of the empirical pseudo-first and pseudo-second order kinetic rate equations, based on applying the statistical rate theory of interfacial transport.” J. Phys. Chem., 110(33), 16514–16525.
Scala, F., Montagnaro, F., and Salatino, P. (2008). “Sulphation of limestones in a fluidized bed combustor: The relationship between particle attrition and microstructure.” Can. J. Chem. Eng., 86(3), 347–355.
Sobolev, K. (2005). “Mechano-chemical modification of cement with high volumes of blast furnace slag.” Cem. Concr. Comp., 27(7–8), 848–853.
Stellacci, P., Liberti, L., Notarnicola, M., and Bishop, P. L. (2009a). “Valorization of coal fly ash by mechano-chemical activation. Part I: Enhancing adsorption capacity.” Chem. Eng. J., 149(1–3), 11–18.
Stellacci, P., Liberti, L., Notarnicola, M., and Bishop, P. L. (2009b). “Valorization of coal fly ash by mechano-chemical activation. Part II. Enhancing pozzolanic reactivity.” Chem. Eng. J., 149(1–3), 19–24.
Sun, C. J., Li, M. G., Gau, S. H., and Chuang, C. J. (2011). “Effect of the milling solution on lead stabilization in municipal solid waste incinerator fly ash during the milling processes.” Waste Manage., 31(2), 318–324.
Suryanarayana, C. (2001). “Mechanical alloying and milling.” Prog. Mater. Sci., 46(1–2), 1–184.
Tanaka, Y., Zhang, Q., and Saito, F. (2003). “Synthesis of spinel with an aid of mechanochemical treatment.” Powder Technol., 132(1), 74–80.
Wang, S., Boyjoo, Y., Choueib, A., and Zhu, Z. H. (2005). “Removal of dyes from aqueous solution using fly ash and red mud.” Water Res., 39(1), 129–138.
Webi, T. W., and Chakravort, R. K. (1974). “Pore and solid diffusion models for fixed-bed adsorbers.” AIChE J., 20(2), 228–238.
Weng, C. H., and Wu, Y. C. (2012). “Potential low-cost biosorbent for copper removal: Pineapple leaf powder.” J. Environ. Eng., 286–292.
Xue, Y., Hou, H., and Zhu, S. (2009). “Adsorption removal of reactive dyes from aqueous solution by modified basic oxygen furnace slag: Isotherm and kinetic study.” Chem. Eng. J., 147(2–3), 272–279.
Zhang, F., Song, Z., Li, J., Chen, G., Jiang, X., and Cong, Q. (1991). “Structure studies of synthetic diamond thin films by x-ray diffraction.” Thin solid films, 199(1), 123–128.
Zhang, J., Shan, W., Ge, J., Shen, Z., Lei, Y., and Wang, W. (2012). “Kinetic and equilibrium studies of liquid-phase adsorption of phosphate on modified sugarcane bagasse.” J. Environ. Eng., 252–258.
Zhang, W., Huang, J., Yu, G., Deng, S., and Zhu, W. (2010). “Mechanochemical destruction of Dechlorane Plus with calcium oxide.” Chemosphere, 81(3), 345–350.
Zhang, Y., Lu, Z., Maroto-Valer, M. M., Andrésen, J. M., and Schobert, H. H. (2003). “Comparison of high-unburned-carbon fly ashes from different combustor types and their steam activated products.” Energ. Fuel., 17(2), 369–377.
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© 2013 American Society of Civil Engineers.
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Received: Jan 10, 2013
Accepted: Jul 17, 2013
Published online: Jul 19, 2013
Published in print: Dec 1, 2013
Discussion open until: Dec 19, 2013
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