Technical Papers
Jul 13, 2013

Synthesis and Characterization of Biomodified Rubber Asphalt: Sustainable Waste Management Solution for Scrap Tire and Swine Manure

Publication: Journal of Environmental Engineering
Volume 139, Issue 12

Abstract

This paper investigates the feasibility of the application of scrap tire and swine manure to produce a sustainable alternative for bituminous asphalt used in pavement construction. Biobinder is produced from swine manure by using a thermochemical conversion process; biobinder is then blended with crumb rubber and asphalt binder (PG 64-22) to produce biomodified rubber (BMR) asphalt. In addition to offering a renewable alternative for petroleum-based binder, BMR can be a hybrid environmental solution for the management of swine manure and scrap tire. To study the merit of application of BMR in the asphalt industry, this paper compares the rheological properties of BMR with a crumb rubber–modified (CRM) binder commonly being used in the United States. The authors found that BMR has comparable properties with the CRM binder. In addition, the authors found that the introduction of the biobinder to the CRM binder was beneficial in improving the low temperature property of the CRM binder while also reducing the CRM binder’s overall viscosity. In turn, this would allow for lower mixing and compaction temperatures of CRM asphalt while alleviating crumb rubber’s stiffening effect and enhancing the CRM asphalt’s pumpability. A lower mixing and compaction temperature will reduce the greenhouse gas emission during application of the CRM binder in pavement construction.

Get full access to this article

View all available purchase options and get full access to this article.

Acknowledgments

The National Science Foundation (Award No: 1150695) and NCHRP IDEA Project 171 sponsored this research. The authors would like to acknowledge the invaluable support provided by S. Hamoush, B. Zada, and F. Mirzaefard of North Carolina Agriculture and Technical State Univ. The contents of this paper reflect the view of the authors, who are responsible for the facts and the accuracy of the data presented. This paper does not constitute a standard, specification, or regulation.

References

Abdelrahman, M. (2011). “Monitoring the interaction of asphalt with crumb rubber modifier (CRM).” Proc., 2011 Engineering Research and Innovation Conf., National Science Foundation (NSF), Washington, DC.
Airey, G., Mohammed, M. H., and Fichter, C. (2008). “Rheological characteristics of synthetic road binders.” Fuel, 87(10), 1763–1775.
Appleford, J. M., Ocfemia, K. C. S., Zhang, Y., Christianson, L., Funk, T. L., and Dong, R. (2005). Analysis and characterization of the product oil and other products of hydrothermal conversion of swine manure, American Society of Agricultural and Biological Engineers, St. Joseph, MI, 054092.
ASTM. (2008a). “Standard test methods for rubber compounding materials determination of particle size distribution of recycled vulcanizate particulate rubber.” ASTM D5644-01, West Conshohoken, PA.
ASTM. (2008b). “Standard test method for viscosity determination of asphalt at elevated temperatures using a rotational viscometer.” ASTM D4402, West Conshohoken, PA.
Attia, M., and Abdelrahman, M. (2009). “Enhancing the performance of crumb rubber-modified binders through varying the interaction conditions.” Int. J. Pav. Eng., 10(6), 423–434.
Banse, M., Tabeau, A., Woltjer, G., and van Meijl, H. (2007). “Impact of European Union biofuel policies on world agricultural and food markets.” Global Trade Analysis Project (GTAP) Conf, Center for Global Trade Analysis, Purdue Univ., West Lafayette, IN.
Birgisson, B., Drakos, C., and Roque, R. (2005). “Final report: Guidelines for use of modified binders.” Florida DOT, 〈http://www.dot.state.fl.us/research-center/Completed_Proj/Summary_SMO/FDOT_BC354_77_rpt.pdf〉 (Mar. 4, 2012).
Burkholder, J., et al. (2007). “Impacts of waste from concentrated animal feeding operations on water quality.” Environ Health Perspect, 115(2), 308–312.
California DOT. (2005). “Use of scrap tire rubber: State of the technology and best practices.” 〈http://www.dot.ca.gov/hq/esc/Translab/ofpm/pdf/T021_ScrapTire.pdf〉 (Feb. 1, 2012).
Cantrell, K. B., Ducey, T., Ro, K. S., and Hunt, P. G. (2008). “Livestock waste-to-bioenergy generation opportunities.” Bioresour. Technol., 99(17), 7941–7953.
Chen, Y.-S. A., Zuckerman, G. J., and Zering, K. (2008). “Applying target costing in the development of marketable and environmentally friendly products from swine waste.” Eng. Econ., 53(2), 156–170.
Claudy, P. M., and Martin, D. (1998). “Thermal behavior of asphalt cements.” Thermochim. Acta, 324(1–2), 203–213.
Conesa, J. A., Martín-Gullón, I., Font, R., and Jauhiainen, J. (2004). “Complete study of the pyrolysis and gasification of scrap tires in a pilot plant reactor.” Environ. Sci. Technol., 38(11), 3189–3194.
Connecticut Dept. of Energy, and Environmental Protection. (2013). “Recycling and disposal of scrap tires.” 〈http://www.ct.gov/dep/cwp/view.asp?A=2714&Q=324902〉 (Feb. 26, 2012).
Dong, R., Li., J., and Wang, S. (2011). “Laboratory evaluation of pre-devulcanized crumb rubber–modified asphalt as a binder in hot-mix asphalt.” J. Mater. Civ. Eng., 1138–1144.
EPA. (2012). “Waste—resource conservation—common wastes & materials—scrap tire.” 〈http://www.epa.gov/osw/conserve/materials/tires/basic.htm#exp〉 (Feb. 5, 2012).
Fini, E. H., et al. (2011). “Bio-binder from swine manure: A sustainable modifier for asphalt binder.” J. Mater. Civ. Eng., 1506–1513.
Firoozifar, S., Foroutan, S., and Foroutan, S. (2011). “The effect of asphaltene on thermal properties of bitumen.” Chem. Eng. Res. Des., 89(10), 2044–2048.
Guleria, S. P., and Dutta, R. K. (2011). “Unconfined compressive strength of fly ash–lime–gypsum composite mixed with treated tire chips.” J. Mater. Civ. Eng., 1255–1263.
Huang, B., Mohammad, L. N., Graves, P. S., and Abadie, C. (2002). “Louisiana experience with crumb rubber-modified hot-mix asphalt pavement.” Transp. Res. Rec., 1789(1), 1–13.
International Rubber Study Group (IRSG). (2013). “Statistical summary of world rubber situation.” 〈http://www.rubberstudy.com/documents/WebSiteData_2.0.pdf〉 (Mar. 15, 2012).
Jackson, L. L., Keeney, D. R., and Gilbert, E. M. (2000). “Swine manure management plans in north-central Iowa: Nutrient loading and policy implications.” J. Soil Water Conserv., 55(2), 205.
Jarecki, M. K., Parkin, T. B., Chan, A. S. K., Hatfield, J. L., and Jones, R. (2008). “Greenhouse gas emissions from two soils receiving nitrogen fertilizer and swine manure slurry.” J. Environ. Qual., 37(4), 1432–1438.
Jeong, K., Lee, S., Amirkhanian, S. N., and Kim, K. W. (2010). “Interaction effects of crumb rubber modified asphalt binders.” Constr. Build. Mater., 24(5), 824–831.
Karmakar, S. S., NKetia, M. M., Laguë, C. C., and Agnew, J. J. (2010). “Development of expert system modeling based decision support system for swine manure management.” Comput. Electron. Agric., 71(1), 88–95.
Lee, S. J., Akisetty, C. K., and Amirkhanian, S. N. (2008a). “Recycling of laboratory-prepared long-term aged binders containing crumb rubber modifier.” Constr. Build. Mater., 22(9), 1906–1913.
Lee, S. J., Amirkhanian, S. N., and Putman, B. J. (2009). “Characterization of recycled aged RAP binders containing crumb rubber modifier using gel permeation chromatography.” J. Mater. Civil Eng., 382–391.
MacDonald, J. M., and McBride, W. D. (2009). “The transformation of U.S. livestock agriculture: Scale, efficiency, and risks.” Economic Research Service EIB-43, USDA, Washington, DC.
Mohammad, L. N., Cooper, S. B., and Elseifi, M. A. (2011). “Characterization of HMA mixtures containing high reclaimed asphalt pavement content with crumb rubber additives.” J. Mater. Civ. Eng., 1560–1568.
Navarro, F. M., and Gámez, M. R. (2011). “Influence of crumb rubber on the indirect tensile strength and stiffness modulus of hot bituminous mixes.” J. Mater. Civ. Eng., 715–724.
New York DOT. (2013). “Fuel, asphalt, and steel price adjustments.” 〈https://www.dot.ny.gov/main/business-center/contractors/construction-division/fuel-asphalt-steel-price-adjustments〉 (Apr. 4, 2013).
Ocfemia, K. (2005). “Hydrothermal process of swine manure to oil using a continuous reactor system.” Ph.D. dissertation, Univ. of Illinois at Urbana-Champaign, Champaign, IL.
Raouf, M. A., and Williams, R. C. (2010a). “General physical and chemical properties of bio-binders derived from fast pyrolysis bio-oils.” Proc., 2010 Mid-Continent Transp. Research Forum, U.S. Dept. of Transportation’s Research and Innovative Technology Administration (RITA).
Raouf, M. A., and Williams, R. C. (2010b). “Temperature and shear susceptibility of a nonpetroleum binder as a pavement material.” Transp. Res. Rec., 2180(1), 9–18.
Rasmussen, R., Lytton, R. L., and Chang, G. K. (2002). “Method to predict temperature susceptibility of an asphalt binder.” J. Mater. Civ. Eng., 246–252.
Roberts, F., Kandhal, P., Brown, E., Lee, D., and Kennedy, T. (1996). Hot mix asphalt materials, mixture design, and construction, 2nd Ed., NAPA Education Foundation, Lanham, MD.
Shuangning, X., Yuanhui, Z., and Shahbazi, A. (2009). “Swine manure solid separation and thermochemical conversion to heavy oil.” Bioresources, 4(2), 458–470.
Silva, R., and Silva, A. (2011). “The potential benefits and risks to the environment in using bio-energy.” Syst. Pract. Act. Res., 24(6), 545–554.
Songela, F., and Maclean, A. (2008). “Scoping exercise (situational analysis) on biofuels industry within and outside Tanzania.” Energy for Sustainable Development, 〈http://www.wwf.se/source.php/1203701/WWF_Tanzania_Scoping_Report_Biofuels.pdf〉 (Mar. 18, 2012).
Stevenson, K., Stallwood, B., and Hart, A. G. (2008). “Tire rubber recycling and bioremediation: A review.” Biorem. J., 12(1), 1–11.
Thodesen, C., Shatanawi, K., and Amirkhanian, S. (2009a). “Effect of crumb rubber characteristics on crumb rubber modified (CRM) binder viscosity.” Constr. Build. Mater., 23(1), 295–303.
Thodesen, C., Xiao, F., and Amirkhanian, S. N. (2009b). “Modeling viscosity behavior of crumb rubber modified binders.” Constr. Build. Mater., 23(9), 3053–3062.
Thu, K., et al. (1997). “A control study of the physical and mental health of residents living near a large-scale swine operation.” J. Agric. Saf. Health, 3(1), 13–26.
USDA. (2005). “National program 206: Manure and byproduct utilization FY 2005 annual report.” 〈http://www.ars.usda.gov/research/programs/programs.htm?np_code=206&docid=13337〉 (Feb. 5, 2012).
Wang, H., You, Z., Mills-Beale, J., and Hao, P. (2012). “Laboratory evaluation on high temperature viscosity and low temperature stiffness of asphalt binder with high percent scrap tire rubber.” Constr. Build. Mater., 26(1), 583–590.
Xiu, S. N., Rojanala, H. K., Shahbazi, A., Fini, E. H., and Wang, L. (2012). “Pyrolysis and combustion characteristics of bio-oil from swine manure.” J. Therm. Anal. Calorim., 107(2), 823–829.
Yang, N., Chen, D., Hu, S., Li, Y., and Jin, Y. (2010). “Evaluation of the tire industry of China based on physical input–output analysis.” J. Ind. Ecol., 14(3), 457–466.
Zhang, Y. (2004). “Converting swine manure to oil: U of I makes the process faster, easier.” ASCE News, Urbana-Champaign, Illinois, 〈http://news.aces.illinois.edu/news/converting-swine-manure-oil-u-i-makes-process-faster-easier〉 (Feb. 5, 2012).

Information & Authors

Information

Published In

Go to Journal of Environmental Engineering
Journal of Environmental Engineering
Volume 139Issue 12December 2013
Pages: 1454 - 1461

History

Received: May 8, 2012
Accepted: Jul 11, 2013
Published online: Jul 13, 2013
Published in print: Dec 1, 2013
Discussion open until: Dec 13, 2013

Permissions

Request permissions for this article.

Authors

Affiliations

Ellie H. Fini [email protected]
M.ASCE
Assistant Professor, Dept. of Civil Engineering, North Carolina Agriculture and Technical State Univ., 1601 E. Market St., Greensboro, NC 27411 (corresponding author). E-mail: [email protected]
Daniel J. Oldham [email protected]
M.ASCE
Research Assistant, Dept. of Civil Engineering, North Carolina Agriculture and Technical State Univ., 1601 E. Market St., Greensboro, NC 27411. E-mail: [email protected]
Taher Abu-Lebdeh [email protected]
M.ASCE
Associate Professor, Dept. of Civil Engineering, North Carolina Agriculture and Technical State Univ., 1601 E. Market St., Greensboro, NC 27411. E-mail: [email protected]

Metrics & Citations

Metrics

Citations

Download citation

If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download.

Cited by

View Options

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Media

Figures

Other

Tables

Share

Share

Copy the content Link

Share with email

Email a colleague

Share