TECHNICAL PAPERS
Feb 3, 2011

Assessment of Low pH Coagulation Performance Using Fluorescence Spectroscopy

Publication: Journal of Environmental Engineering
Volume 137, Issue 7

Abstract

Optimization of organic matter (OM) removal is of key importance for effective water treatment, as its presence affects treatment processes. In particular, OM increases the operational cost of treatment caused by increased coagulant and disinfectant demands. In the work reported here, fluorescence spectroscopy is used to assess the effect of changing coagulation pH on OM removal, character, and composition. The results of a 3-month trial of low pH coagulation operation at a major surface water treatment works in the Midlands region of the UK are discussed, together with the effect upon total organic carbon (TOC) removal. OM removal was assessed on the basis of both measured removal and fluorescence-inferred removal (through intensity-reduction measurements). Fluorescence spectroscopy demonstrated that optimized coagulation affects the quantitative and qualitative OM properties. Fluorescence analyses were shown to complement other OM measurements, with reductions of peak intensities correlating well with removal of TOC in a range of different treatment conditions.

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Acknowledgments

The authors are grateful for the financial and logistical support provided by Severn Trent Water Ltd. and the University of Birmingham.

References

Baker, A. (2001). “Fluorescence excitation-emission matrix characterization of some sewage-impacted rivers.” Environ. Sci. Technol., 35(5), 948–953.
Baker, A., Tipping, E., Thacker, S. A., and Gondar, D. (2008). “Relating dissolved organic matter fluorescence and functional properties.” Chemosphere, 73(11), 1765–1772.
Beggs, K. M. H., Summers, R. S., and McKnight, D. M. (2009). “Characterizing chlorine oxidation of dissolved organic matter and disinfection by-product formation with fluorescence spectroscopy and parallel factor analysis.” J. Geophys. Res. Biogeosci., 114, G04001.
Bieroza, M., Baker, A., and Bridgeman, J. (2009). “Relating freshwater organic matter fluorescence to organic carbon removal efficiency in drinking water treatment.” Sci. Total Environ., 407(5), 1765–1774.
Chow, C. W. K., van Leeuwen, J. A., Drikas, M., Fabris, R., Spark, K. K., and Page, D. W. (1999). “The impact of the character of natural organic matter in conventional treatment with alum.” Water Sci. Technol., 40(9), 97–104.
Coble, P. G. (1996). “Characterization of marine and terrestrial DOM in seawater using excitation-emission matrix spectroscopy.” Mar. Chem., 51(4), 325–346.
Edzwald, J. K., and Tobiason, J. E. (1999). “Enhanced coagulation: US requirements and a broader view.” Water Sci. Technol., 40(9), 63–70.
European Environmental Agency. (2007). Corine land cover 2000 (CLC2000) 100 m, version 9/2007, 〈http://www.eea.europa.eu〉, Copenhagen, Denmark.
Fabris, R., Chow, C. W. K., Drikas, M., and Eikebrokk, B. (2008). “Comparison of NOM character in selected Australian and Norwegian drinking waters.” Water Res., 42(15), 4188–4196.
Henderson, R. K., Baker, A., Parsons, S. A., and Jefferson, B. (2008b). “Characterisation of algogenic organic matter extracted from cyanobacteria, green algae and diatoms.” Water Res., 42(13), 3435–3445.
Hudson, N. J., Baker, A., and Reynolds, D. (2007). “Fluorescence analysis of dissolved organic matter in natural, waste and polluted waters–A review.” River Res. Appl., 23(6), 631–649.
Kim, H.-C., and Yu, M.-J. (2005). “Characterization of natural organic matter in conventional water treatment processes for selection of treatment processes focused on DBPs control.” Water Res., 39(19), 4779–4789.
Kuzniz, T., et al. (2007). “Instrumentation for the monitoring of toxic pollutants in water resources by means of neural network analysis of absorption and fluorescence spectra.” Sens. Actuators, B, 121(1), 231–237.
Lambert, P., et al. (2003). “Field fluorometers as dispersed oil-in-water monitors.” J. Hazard. Mater., 102(1), 57–79.
O’Melia, C. R., Becker, W. C., and Au, K.-K. (1999). “Removal of humic substances by coagulation.” Water Sci. Technol., 40(9), 47–54.
Randtke, S. J. (1988). “Organic contaminant removal by coagulation and related process combinations.” J. Am. Water Works Assoc., 80(5), 40–56.
Roccaro, P., Vagliasindi, G. A., and Korshin, G. V. (2009). “Changes in NOM fluorescence caused by chlorination and their associations with disinfection by-products formation.” Environ. Sci. Technol., 43(3), 724–729.
U.S. Environmental Protection Agency (U.S. EPA). (1999). “Research plan for microbial pathogens and disinfection by-products in drinking water.” EPA/600/R-97-122, U.S. EPA, Office of Research and Development, Office of Water, Washington, DC.
van Leeuwen, J., Daly, R., and Holmes, A. (2005). “Modeling the treatment of drinking water to maximize dissolved organic matter removal and minimize disinfection by-product formation.” Desalination, 176(1–3), 81–89.
Volk, C., Bell, K., Ibrahim, E., Verges, D., Amy, G., and Lechevallier, M. (2000). “Impact of enhanced and optimized coagulation on removal of organic matter and its biodegradable fraction in drinking water.” Water Res., 34(12), 3247–3257.
Yu, J., Wang, D., Yan, M., Ye, C., Yang, M., and Ge, X. (2006). “Optimized coagulation of high alkalinity low temperature and particle water: pH adjustment and polyelectrolytes as coagulant aids.” Environ. Monit. Assess., 131(1–3), 377–386.

Information & Authors

Information

Published In

Go to Journal of Environmental Engineering
Journal of Environmental Engineering
Volume 137Issue 7July 2011
Pages: 596 - 601

History

Received: Jan 12, 2010
Accepted: Feb 1, 2011
Published online: Feb 3, 2011
Published in print: Jul 1, 2011

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Authors

Affiliations

Magdalena Bieroza
Senior Research Associate, Centre for Sustainable Water Management, Lancaster Environment Centre, Lancaster, LA1 4YQ, UK.
Andy Baker
Professor, School of Civil and Environmental Engineering and School of Biology, Earth and Environmental Sciences, The Univ. of New South Wales, 110 King St., Manly Vale, NSW 2093, Australia.
John Bridgeman
Reader in Environmental Engineering, School of Civil Engineering, Univ. of Birmingham, Edgbaston, Birmingham, B15 2TT, UK (corresponding author). E-mail: [email protected]

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