Case Studies
Mar 14, 2011

Corrosion Damage Diagnosis of a 44-Year-Old Ammonium Nitrate Prill Tower in a Petrochemical Complex

Publication: Journal of Performance of Constructed Facilities
Volume 26, Issue 4

Abstract

One of the most aggressive environments for concrete is in an industrial area such as a petrochemical complex compound. In this area, exposure to highly corrosive materials such as ammonium nitrate, high carbonation rates (resulting from increased concentration of carbon dioxide (CO2) in industrial environments, and environmental conditions (such as relative humidity and temperature fluctuations) can collectively contribute to weakening the durability of concrete. This paper presents a study of corrosion damage of concrete and the embedded reinforcing steel of a 44-year-old nitrate prill tower of a petrochemical complex located in Shiraz, a city in southern Iran. After a thorough visual inspection and observing different deterioration mechanisms, a comprehensive set of conventional experiments to assess the durability of reinforced concrete was performed. Various degrees of deterioration were associated with different exposure conditions along the tower. Results indicated that the concrete had been severely decalcified up to 3 cm from its surface. However, reinforcement corrosion was negligible. Results moreover show that exposure to ammonium nitrate solutions was the primary reason for the high deterioration of the concrete of the tower.

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Acknowledgments

The authors would like to acknowledge the technical support of the Construction Materials Institute (CMI) experts, particularly the support of Mr. Masoud Moradian and Mr. Navid Heidarzadeh. The authors are also grateful to Mr. Amir Hossein Etemadi, Ph.D. student of the University of Toronto.

References

Al-Bahar, S., Attiogbe, E. K., and Kamal, H. (1998). “Investigation of corrosion damage in a reinforced concrete structure in Kuwait.” ACI Mater. J.AMAJEF, 95(3), 226–231.
Al-Khaiat, H., and Haque, M. N. (1997). “Carbonation of some coastal concrete structures in Kuwait.” ACI Mater. J.AMAJEF, 94(6), 602–607.
American Concrete Institute (ACI). (1984). “Guide for the design and construction of fixed offshore concrete structures.” ACI 357R-84, ACI Committee 357, Farmington Hills, MI.
American Concrete Institute (ACI). (2001). “Protection of metals in concrete against corrosion.” ACI 222R-01, ACI Committee 222, Farmington Hills, MI.
American Concrete Institute (ACI). (2002). “Building code requirements for structural concrete and commentary.” ACI 318R-02, ACI Committee 318, Farmington Hills, MI.
ASTM. (1999). “Standard test method for half-cell potentials of uncoated reinforcing steel in concrete.” ASTM C876-91, ASTM International, West Conshohoken, PA.
Barnard, J. L. (1967). “Corrosion of sewers.” Council for Scientific and Industrial Research (CSIR) Research Rep. 250, CSIR and the National Building Research Institute, Pretoria, South Africa.
Biczok, I. (1986). Betonkorrosion, Bauverlag, Wiesbaden, Germany.
British Standards Institute. (2001). “Concrete: Specification, performance, production and conformity.” BS EN 206-1:2000, British Standards Institute, London.
Costa, A., and Appleton, J. (2002). “Case studies of concrete deterioration in a marine environment in Portugal.” Cem. Concr. Compos.CCOCEG, 24(1), 169–179.
Elsener, B. (2001). “Half-cell potential mapping to assess repair work on RC structures.” Constr. Build. Mater.CBUMEZ, 15(2–3), 133–139.
Grattan-Bellew, P. E., and Mitchell, L. D. (2006). “Quantitative petrographic analysis of concrete—The damage rating index (DRI) method, a review.” Proc., Marc-Andre Bérubé Symp. on Alkali-Aggregate reactivity in Concrete, Montreal, Canada, 321–334.
Henning, O., and Knofel, D. (1989). Baustoffchemie, Bauverlag, Wiesbaden, Germany.
Jauberthie, R., and Rendell, F. (2003). “Physicochemical study of the alteration surface of concrete exposed to ammonium salts.” Cem. Concr. Res.CCNRAI, 33(1), 85–91.
Knoblauch, H., and Schneider, U. (2001). Bauchemie, 5th Ed., Werner, Dusseldorf, Germany.
Krenkler, K. (1980). Chemie des Bauwesens, Bd.1, anorganische Chemie, Springer, Berlin.
Lea, F. M. (1970). The chemistry of cement and concrete, 3rd Ed., Arnold, London.
Leelalerkiet, V., Kyung, J. W., Ohtsu, M., and Yokota, M. (2004). “Analysis of half-cell potential measurement for corrosion of reinforced concrete.” Constr. Build. Mater., 18(3), 155–162.
Mehta, P., and Monteiro, P. (2005). Concrete: Microstructure, properties, and materials, 3rd Ed., McGraw Hill, New York.
Moradian, M., Shekarchi, M., Pargar, F., Bonakdar, A., and Valipour, M. (2010). “Deterioration of concrete caused by complex attack in sewage treatment plant environment.” J. Perform. Constr. Facil.JPCFEV, 26(1), 124–134.
Morgan, D. R. (1996). “Compatibility of concrete repair materials and systems.” Constr. Build. Mater.CBUMEZ, 10(1), 57–67.
Pargar, F., Layssi, H., and Shekarchi, M. (2007). “Investigation the effect of temperature and silica fume on the rate of steel corrosion in concrete.” Proc., 5th Int. Conf. on Concrete under Severe Conditions Environmental and Loading (CONSEC’07), Ecole Nationale des Ponts, Paris, 361–367.
Poupard, O., L’Hostis, V., Catinaud, S., and Petre-Lazar, I. (2006). “Corrosion damage of diagnosis of a reinforced concrete beam after 40 years natural exposure in marine environment.” Cem. Concr. Res.CCNRAI, 36(3), 504–520.
RILEM TC 154-EMC. (2003). “Electrochemical techniques for measuring metallic corrosion: Half-cell potential measurements—Potential mapping on reinforced concrete structures.” Mater. Struct.MASTED, 36(261), 461–471.
Saffarini, H. S., and Samra, R. M. (2001). “Repair of a chemical industry jetty in Aqaba-Jordan.” Mater. Struct.MASTED, 34(3), 178–185.
Schneider, U., and Chen, S.-W. (1998a). “The chemomechanical effect and the mechanochemical effect on high-performance concrete subjected to stress corrosion.” Cem. Concr. Res.CCNRAI, 28(4), 509–522.
Schneider, U., and Chen, S.-W. (1998b). “Modeling and empirical formulas for chemical corrosion and stress corrosion of cementitious materials.” Mater. Struct.MASTED, 31(10), 662–668.
Schneider, U., and Chen, S.-W. (1999). “Behavior of high-performance concrete under ammonium nitrate solution and sustained load.” ACI Mater. J.AMAJEF, 96(1), 47–51.
Schneider, U., and Chen, S.-W. (2005). “Deterioration of high-performance concrete subjected to attack by combination of ammonium nitrate solution and flexure stress.” Cem. Concr. Res.CCNRAI, 35(9), 1705–1713.
Shayan, A., and Grimstad, J. (2006). “Deterioration of concrete in a hydroelectric concrete gravity dam and its characterisation.” Cem. Concr. Res.CCNRAI, 36(2), 371–383.
Shekarchi, M., Moradi-Marani, F., and Pargar, F. (2011). “Corrosion damage of a reinforced concrete jetty structure in the Persian Gulf: A case study.” Struct. Infrastruct. Eng., 7(9), 701–713.
Taylor, H. F. W. (1990). Cement chemistry, Academic Press, London.
Thistlethwayte, D. K. B. (1972). The control of sulphides in sewage systems, Butterworths, Sydney, Australia.
Vaysburd, A. M., Emmons, P. H., Mailvaganam, N. P., McDonald, J. E., and Bissonnette, B. (2004). “Concrete repair technology—A revised approach is needed.” Concr. Int.CNCIEH, 26(1), 58–65.

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Published In

Go to Journal of Performance of Constructed Facilities
Journal of Performance of Constructed Facilities
Volume 26Issue 4August 2012
Pages: 532 - 543

History

Received: Jul 9, 2010
Accepted: Mar 11, 2011
Published online: Mar 14, 2011
Published in print: Aug 1, 2012

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Authors

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Milad Hallaji, S.M.ASCE [email protected]
Graduate Student and Research Assistant, Construction Materials Institute (CMI), School of Civil Engineering, Univ. of Tehran, P.O. Box 11356-4563, Tehran, Iran (corresponding author). E-mail: [email protected]
Mohammad Shekarchi
Associate Professor and Director of Construction Materials Institute (CMI), School of Civil Engineering, Univ. of Tehran, P.O. Box 11356-4563, Tehran, Iran.
Farhad Pargar
Graduate Student and Research Assistant, Construction Materials Institute (CMI), School of Civil Engineering, Univ. of Tehran, P.O. Box 11356-4563, Tehran, Iran.
Seyyed Rahman Taheri
Graduate Student and Research Assistant, Construction Materials Institute (CMI), School of Civil Engineering, Univ. of Tehran, P.O. Box 11356-4563, Tehran, Iran.
Farnam Ghassemzadeh
Graduate Student and Research Assistant, Construction Materials Institute (CMI), School of Civil Engineering, Univ. of Tehran, P.O. Box 11356-4563, Tehran, Iran.

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