TECHNICAL PAPERS
Oct 15, 2009

Carbonated Ladle Slag Fines for Carbon Uptake and Sand Substitute

Publication: Journal of Materials in Civil Engineering
Volume 21, Issue 11

Abstract

The possibility of using a carbonated ladle slag as a fine aggregate in concrete was investigated. The slag was treated with carbon dioxide to reduce the free lime content while binding gaseous CO2 into solid carbonates. The treatment took place with either a high concentration of CO2 at 500kPa for 2h or with a low concentration of CO2 at atmospheric pressure for 56days . It was found that CO2 uptake by the slag particles between 300 and 600μm and by the slag particles smaller than 75μm were about 4.2 and 15.6% of their mass, respectively. The extractable CaO contents were estimated by titration and were found to be significantly reduced by carbonation treatment. The carbonated ladle slag was used as a fine aggregate in zero-slump press-formed compact mortar samples and compared to similar samples containing a control river sand. The 28-day strengths of the mortars made with the carbonated slag sand were comparable to the strengths of the normal river sand mortars. The use of carbonated ladle slag as a fine aggregate in concrete is shown to be a novel way of sequestering CO2 in a beneficial manner.

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Acknowledgments

The project was supported by Natural Science and Engineering Research Council (NSERC)NSERC of Canada and by St. Lawrence Cement. The writers extend their thanks to Mr. Chris Carozza of QIT-Fer et Titane for the supply of ladle slag and to Professor Roderick Guthrie of McGill University for his valuable advice.

References

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Information & Authors

Information

Published In

Go to Journal of Materials in Civil Engineering
Journal of Materials in Civil Engineering
Volume 21Issue 11November 2009
Pages: 657 - 665

History

Received: Mar 28, 2008
Accepted: Mar 11, 2009
Published online: Oct 15, 2009
Published in print: Nov 2009

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Notes

Note. Associate Editor: Jason Weiss

Authors

Affiliations

Sean Monkman
Ph.D. Candidate, Dept. of Civil Engineering and Applied Mechanics, McGill Univ., 817 Sherbrooke St. West, Montreal PQ, Canada H3A 2K6.
Associate Professor, Dept. of Civil Engineering and Applied Mechanics, McGill Univ., 817 Sherbrooke St. West, Montreal PQ, Canada H3A 2K6 (corresponding author). E-mail: [email protected]
Caijun Shi
Professor, College of Civil Engineering, Hunan Univ., Changsha, Hunan, 410082, China; and President, CJS Technology, Burlington ON, Canada L7M 2Z2.

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