TECHNICAL PAPERS
Jul 1, 2008

Are Deicing Salts Necessary to Promote Scaling in Concrete?

Publication: Journal of Engineering Mechanics
Volume 134, Issue 7

Abstract

The main purpose of the present study is to investigate the role of the material parameters such as permeability, thermal diffusivity, and pore size distribution on the mechanical behavior of cementitious structures submitted to frost action, such as surface scaling. An experimental device, in which a cement paste specimen is exposed to freezing-thawing cycles under a thermal gradient, has been developed. The experimental results show that under high thermal gradient (up to 1.5°Cmm ), skin damage can occur without a saline layer in contact with the frozen surface. This can be explained and quantified in the framework of poromechanics. The model is based on the coupling between liquid-ice crystal thermodynamic equilibrium, liquid water transport, thermal conduction, and elastic properties of the different phases that form the saturated porous material. It eventually predicts that a less permeable sample is more susceptible to damage by surface defacement, which explains the observed experimental result.

Get full access to this article

View all available purchase options and get full access to this article.

References

Baroghel-Bouny, V., Arnaud, S., Henry, D., Carcasse, M., and Quenard, D. (2002). “Vieillissement des bétons en milieu naturel: Une expérimentation pour le XXIe siècle. III—Propriétés de durabilité des bétons mesurées sur éprouvettes conservées en laboratoire.” Bull. Lab. Ponts Chaussees, 13–59.
Baroghel-Bouny, V., Thierry, M., Barberon, F., Coussy, O., and Villain, G. (2007). “Assessment of transport properties of cementitious materials: A major challenge as regards durability.” Revue Européenne de Génie Civil, accepted.
Bazant, Z., Chern, J., Rosenberg, A., and Gaidis, J. (1988). “Mathematical-model for freeze-thaw durability of concrete.” J. Am. Ceram. Soc., 71, 776–783.
Beaudoin, J., and MacInnis, C. (1974). “The mechanism of frost damage in hardened cement paste.” Cem. Concr. Res., 4, 139–147.
Brun, M., Lallemand, A., Quinson, J., and Eyraud, C. (1977). “A new method for the simultaneous determination of the size and the shape of pores: The thermoporometry.” Thermochim. Acta, 21, 59–88.
Chateau, X., and Dormieux, L. (2002). “Micromechanics of saturated and unsaturated porous media.” Int. J. Numer. Analyt. Meth. Geomech., 26, 831–844.
Coussy, O. (2004). Poromechanics, Wiley, New York.
Coussy, O. (2005). “Poromechanics of freezing materials.” J. Mech. Phys. Solids, 53, 1689–1718.
Coussy, O., and Fen-Chong, T. (2005). “Crystallization, pore relaxation and micro-cryosuction in cohesive porous materials.” C. R. Mec., 333, 507–512.
Coussy, O., and Monteiro, P. (2007). “Unsaturated poroelasticity for crystallization in pores.” Comput. Geotech., 34, 279–290.
Cui, L., and Cahyadi, J. (2001). “Permeability and pore structure of OPC cement paste.” Cem. Concr. Res., 31, 277–282.
de Schutter, G., and Taerwe, L. (1995). “Specific head and thermal diffusivity of hardening concrete.” Mag. Concrete Res., 47(172), 203–207.
Dormieux, L., and Bourgeois, E. (2003). Introduction la micromécanique des milieux poreux, Presses de l’Ecole Nationale des Ponts et Chaussées, Paris.
Eymard, R., Gallouët, T., and Herbin, R. (2000). Handbook of numerical analysis, The finite volume method, Ph. Ciarlet, and J. L. Lions, eds., Elsevier, Amsterdam, New York, 7, 715–1022.
Fabbri, A. (2006). “Physico-mécanique des matériaux cimentaires soumis au gel-dégel.” Ph.D. thesis, Univ. de Marne-la-Vallée, Champs-sur-Marne, France.
Fabbri, A., Fen-Chong, T., and Coussy, O. (2006). “Dielectric capacity, liquid water content, and pore structure of thawing-freezing materials.” Cold Regions Sci. Technol., 44, 52–66.
Fen-Chong, T., Fabbri, A., Guilbaud, J.-P., and Coussy, O. (2004). “Determination of liquid water content and dielectric constant in porous media by the capacitive method.” C. R. Mec., 332, 639–645.
Garboczi, E., and Bentz, D. (1996). “Modelling the microstructure and transport properties of concrete.” Constr. Build. Mater., 10(5), 293–300.
Harris, K., and Woolf, L. (2004). “Temperature and volume dependence of the viscosity of water and heavy water at low temperatures.” J. Chem. Eng. Data, 49(4), 1064–1069.
Hearn, N., and Morley, C. (1997). “Self-sealing property of concrete-experimental evidence.” Mater. Struct., 30, 404–411.
Hervé, E. (2002). “Thermal and thermoelastic behaviour of multiply coated inclusion-reinforced composites.” Int. J. Solids Struct., 39, 1041–1058.
Jehng, J., Sprague, D., and Halperin, W. (1996). “Pore structure of hydrating cement paste by magnetic resonance relaxation analysing and freezing.” Magn. Reson. Imaging, 14(7/8), 785–791.
Katz, A., and Thompson, A. (1986). “Quantitative prediction of permeability in porous rock.” Phys. Rev. B, 34(11), 8179–8181.
Kaufmann, J. (1999). “Experimental identification of damage mechanisms in cementitious porous materials on phase transition of pore solution under frost deicing salt attack.” Ph.D. thesis, École Polytechnique Fédérale de Lausanne, Lausanne, Switzerland.
Kim, K.-H., Jeon, S.-E., Kim, J.-K., and Yang, S. (2003). “An experimental study on thermal conductivity of concrete.” Cem. Concr. Res., 33, 363–371.
Kleinberg, R. L., and Griffin, D. D. (2005). “NMR measurements of permafrost: Unfrozen water assay, pore-scale distribution of ice, and hydraulic permeability of sediments.” Cold Regions Sci. Technol., 42, 63–77.
Laboratoire Central des Ponts et Chaussées (LCPC). (2003). “Recommendations pour la durabilité des bétons durcis soumis au gel.” Techniques et méthodes des laboratoires des ponts et chaussées, Paris.
Lide, D. R. (2001). Handbook of chemistry and physics 2001-2002, 82nd Ed., CRC, Boca Raton, Fla.
Penttala, V. (2006). “Surface and internal deterioration due to saline and non-saline freeze thaw loads.” Cem. Concr. Res., 36, 921–928.
Pigeon, M. (1984). “Microstructure et résistance au gel des ciments et bétons.” Ph.D. thesis, Univ. Pierre et Marie Curie, Paris.
Pigeon, M., Marchand, J., and Pleau, R. (1996). “Frost resistant concrete.” Constr. Build. Mater., 10(5), 339–348.
Powers, T. (1949). “The air requirement of frost-resistant concrete.” Highw. Res. Board, Proc. Annu. Meet., 29, 184–211.
Powers, T. (1959). “Capillary continuity or discontinuity in cement pastes.” PCA Bulletin, 10, 2–12.
Powers, T., and Helmuth, R. (1953). “Theory of volume changes in hardened portland-cement paste during freezing.” Highw. Res. Board, Proc. Annu. Meet., 32, 285–297.
Scherer, G. (1993). “Freezing gels.” J. Non-Cryst. Solids, 155, 1–25.
Sellevold, E., and Bager, D. (1980). “Low temperature calorimetry as a pore structure probe.” Proc., 7th Int. Congress on the Chemistry of Cement, Vol. 4, Paris, 394–399.
Sellevold, E., and Farstad, T. (1991). “Frost/salt-testing of concrete: Effect of test parameters and concrete moisture history.” Nordic Concrete Research, 10, 121–138.
Shafiq, N., and Cabrera, J. (2004). “Effects of initial curing condition on the fluid transport properties in OPC and fly ash bended cement concrete.” Cem. Concr. Compos., 26, 381–387.
Speedy, R. (1987). “Thermodynamic properties of supercooled water at 1atm .” J. Phys. Chem., 91, 3354–3358.
Taylor, H. F. W. (1997). Cement Chemistry, 2nd Ed., Thomas Telford Ltd., London.
Ulm, F.-J., Acker, P., and Lévy, M. (1999). “The “chunnel” fire. II: Analysis of concrete damage.” J. Eng. Mech., 125(3), 283–289.
Ulm, F.-J., Constantinides, G., and Heukamp, F. (2004). “Is concrete a poromechanics material? A multiscale investigation of poroelastic properties.” Mater. Struct., 37, 43–58.
Valenza, J., and Scherer, G. (2005). “Mechanisms of salt scaling.” Mater. Struct., 38, 479–488.
Van Genuchten, M. (1980). “A closed form equation for predicting the hydraulic conductivity of unsaturated soils.” Soil Sci. Soc. Am. J., 44(5), 892–898.
Verbeck, G., and Klieger, P. (1957). “Studies of salt scaling of concrete.” Highw. Res. Board, Proc. Annu. Meet., Bulletin 100, 1–17.
Vignes, M., and Dijkema, K. (1974). “A model for the freezing of water in a dispersed medium.” J. Colloid Interface Sci., 49, 165–172.
Vignes-Adler, M. (1976). “On the origin of the water aspiration in a freezing dispersed medium.” J. Colloid Interface Sci., 60, 162–171.
Zuber, B., and Marchand, J. (2004). “Predicting the volume instability of hydrated cement systems upon freezing using poro-mechanics and local phase equilibria.” Concr. Sci. Eng., 37(268), 257–270.

Information & Authors

Information

Published In

Go to Journal of Engineering Mechanics
Journal of Engineering Mechanics
Volume 134Issue 7July 2008
Pages: 589 - 598

History

Received: Sep 22, 2006
Accepted: Nov 19, 2007
Published online: Jul 1, 2008
Published in print: Jul 2008

Permissions

Request permissions for this article.

Notes

Note. Associate Editor: Christian Hellmich

Authors

Affiliations

Antonin Fabbri, Ph.D.
Institut Navier, Univ. Paris-Est, LMSGC 2 allée Kepler-77420, Champs-sur-Marne, France; presently, BRGM, 3 Ave. Claude Guillemin, 45060 Orléans Cedex 2, France.
Olivier Coussy
Research Director, Institut Navier, EymardUniv. Paris-Est, ENPC 6-8 Av. Blaise Pascal, Cité Descartes, 77455 Marne-la-Valle, France.
Teddy Fen-Chong [email protected]
Research Fellow, Institut Navier, Univ. Paris-Est, LMSGC 2 allée Kepler, 77420 Champs-sur-Marne, France (corresponding author). E-mail: [email protected]
Paulo J. Monteiro
Professor, Structural Engineering, Mechanics, and Materials, Dept. of Civil and Environmental Engineering, 725 Davis Hall, Univ. of California at Berkeley, Berkeley, CA 94720.

Metrics & Citations

Metrics

Citations

Download citation

If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download.

Cited by

View Options

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Media

Figures

Other

Tables

Share

Share

Copy the content Link

Share with email

Email a colleague

Share