Critical Analysis of Computing Equations for Determination of BOD by Dilution Methods
Publication: Journal of Environmental Engineering
Volume 132, Issue 5
Abstract
The dilution method has been accepted widely as the standard procedure for determining biochemical oxygen demand (BOD). A mass-balance approach was used to analyze four equations for computing BOD: two involving external seed correction methods (Standard Methods) and two involving internal correction methods (Sawyer and McCarty in 1978 and Kline and Gibbs in 1979). Five testing conditions were identified as being pertinent to the underlying assumptions: seed addition method, uniform BOD bottle volume, uniform initial dissolved oxygen (DO), seed uptake linearity, and data handling method. The results of this study showed that internal methods may provide more reproducible results, primarily due to the inherent correction for dilution water demand and better data handling (regression) technique to cope with the variation in BOD bottle volume and initial DO. However, internal methods may violate the requirements imposed by Standard Methods for minimum final DO for the high spike runs and minimum DO depletion for the low spike runs. Recommendations are also made to improve the reliability of these methods.
Get full access to this article
View all available purchase options and get full access to this article.
Acknowledgments
This work was partially supported by the Taiwan National Science Council under Contract No. NSCTNSC89-2211-E-324-019. The authors appreciate the valuable comments by Professor Tze-Wen Chi of the Department of the Environmental Engineering and Management, Chaoyang University of Technology (CYUT).
References
American Public Health Association (APHA), American Water Works Association, and Water Environment Federation. (1998). “Part 5210B: biochemical oxygen demand.” Standards for examination of water and wastewater, 20th Ed., Washington, D.C.
American Public Health Association (APHA), American Water Works Association, and Water Environment Federation. (2005). “Part 5210B: biochemical oxygen demand.” Standards for examination of water and wastewater, 21st Ed., Washington, D.C.
CEN, European Committee for Standardization. (1997). “Determination of biochemical oxygen demand after n days—Part 1: Dilution and seeding method with allythiourea addition.” Water Quality, ISO 5815, 1989, Brussels.
Chiang, C. F., and Chi, T. W. (2001). “Assessment of alterations in the 2001 edition of BOD analysis of NIEA methods.” J. Chinese Institute of Environ. Eng. (Taiwan), 11(4), 271–278.
Chiang, C. F., Wu, Y. S., and Chi, T. W. (2002). “Evaluation criteria and the latest trends in quality control for BOD analysis by dilution method (in Chinese).” J. Chaoyang Univ. of Tech. (Taiwan), 2(7), 247–260.
Chiang, C. F., Wu, Y. S., and Young, J. C. (2004). “Analyzing the uncorrected error of dilution water demand for the dilution BOD method.” Water Environ. Res., 76(3), 238–244.
Hach Company (1989). “Oxygen demand—Biochemical.” Water analysis handbook, Hach Chemical Company, Loveland, Colo., 453–456.
Klein, R. L., and Gibbs, C. R. (1979). “Graphical method for calculating biochemical oxygen demand.” J. Water Pollut. Control Fed., 51(9), 2257–2264.
Sawyer, C. N., and McCarty, P. L. (1978). “Biochemical oxygen demand.” Chemistry for environmental engineering, McGraw-Hill, New York, 416–432.
Stratton, R. G., Namkung, E., and Rittmann, B. E. (1983). “Secondary utilization of trace organics by biofilms on porous media.” J. Am. Water Works Assoc., 75(9), 463–469.
U.S. Environmental Protection Agency (USEPA). (1986). Method-by-method statistics from water pollution (WP) laboratory performance evaluation studies, Office of Research and Development, Quality Assurance Branch, Environmental Monitoring and Support Lab., Cincinnati.
Woodring, S. L., and Clifford, D. A. (1988). “A comparison of the graphical and standard methods for determination of biochemical oxygen demand.” J. Water Pollut. Control Fed., 60(4), 537–544.
Young, J. C. (1973). “Chemical methods for nitrification control.” J. Water Pollut. Control Fed., 45(4), 637–645.
Young, J. C. (1984). “Waste strength and water pollution parameters.” Water analysis, Vol. III, Academic, New York, 1–39.
Young, J. C., Clesceri, L. S., and Kamhawy, S. (2005). “Changes in the biochemical oxygen demand procedure in the 21st ed. of Standard Methods for the Examination of Water and Wastewater.” Water Environ. Res., 77(4), 404–410.
Young, J. C., McDermott, G. N., and Jenkins, D. (1981). “Alternations in the BOD procedure for the 15th ed. of standard methods for the examination of water and wastewater.” J. Water Pollut. Control Fed., 53(7), 1253–1262.
Information & Authors
Information
Published In
Copyright
© 2006 ASCE.
History
Received: Mar 9, 2004
Accepted: Aug 26, 2005
Published online: May 1, 2006
Published in print: May 2006
Authors
Metrics & Citations
Metrics
Citations
Download citation
If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download.