TECHNICAL PAPERS
Dec 1, 1998

Predicting Chlorine Residuals and Formation of TTHMs in Drinking Water

Publication: Journal of Environmental Engineering
Volume 124, Issue 12

Abstract

Chlorination is the most widely practiced form of disinfection in the United States. It is highly effective against most microbiological contaminants. However, there is concern that the disinfection by-products (DBPs) formed by the use of chlorine might be carcinogenic. One class of DBPs that are formed and the only class of DBPs that currently are regulated are total trihalomethanes (TTHMs). Therefore, much effort is being expended in developing models that can be used to predict both TTHMs and chlorine residual levels in treated drinking water. This paper presents a model that predicts both TTHMs and chlorine residuals based on the consumption of chlorine and can be used to assist in evaluating the complex balance between microbial and DBP risks associated with disinfecting drinking water with chlorine. The parameters of the model have been found to be functions of total organic carbon, pH, temperature, and initial chlorine residual level. Bromide and the subsequent formation of brominated by-products were not considered in this paper.

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References

1.
Amemiya, T.(1974). “The nonlinear two-stage least-squares estimator.”J. Econometrics, 2, 105–110.
2.
Clark, R. M.(1998). “Chlorine demand and TTHM formation kinetics: A second order model.”J. Envir. Engrg., ASCE, 124(1), 16–24.
3.
Clark, R. M., and Adams, J. Q. (1993). “Control of disinfection by-products: Economic and technological considerations.”Safety of water disinfection: Balancing chemical and microbial risks, G. E. Craun, ed., ILSI Press, Washington, D.C., 345–357.
4.
Clark, R. M., Adams, J. Q., and Lykins, B. W. (1994). “DBP control in drinking water: Cost and performance.”J. Envir. Engrg., 120(4), 759– 782.
5.
Clark, R. M., Pourmoghaddas, H., Wymer, L. J., and Dressman, R. C.(1996). “Modeling the kinetics of chlorination by-products formation: The effects of bromide.”J. Water SRT-Aqua, 45(3), 112–119.
6.
Johnston, J. (1984). Econometric methods. McGraw-Hill, Inc., New York.
7.
Marquardt, D. W.(1963). “An algorithm for least squares estimation of nonlinear parameters.”J. for the Soc. of Industrial and Appl. Mathematics, 11, 431–441.
8.
Pourmoghaddas, H., Stevens, A. A., Kinman, R. N., Dressman, R. C., Moore, L. A., and Ireland, J. A. (1993). “Effect of bromide ion on formation of HAAs during chlorination.”J. Am. Water Works Assoc., 85(1), 82–87. SAS/ETS user's guide . (1988). Version 6, 1st Ed., Chapter 13, SAS Institute, Inc., Cary, N.C., 315–398. SAS system for regression . (1986). 1st Ed., Chapter 2, SAS Institute, Inc., Cary, N.C., 15–45. Standard methods for the examination of water and wastewater . (1995). A. D. Eaton, L. S. Clesceri, and A. E. Greenberg, eds., American Public Health Association, American Water Works Association Water Environment Federation, Denver, Colo.
9.
Vasconcelos, J. J., et al. (1996). Characterization and modeling of chlorine decay in distribution systems. American Water Works Association Research Foundation, Denver, Colo.

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Published In

Go to Journal of Environmental Engineering
Journal of Environmental Engineering
Volume 124Issue 12December 1998
Pages: 1203 - 1210

History

Published online: Dec 1, 1998
Published in print: Dec 1998

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Authors

Affiliations

Robert M. Clark, Member, ASCE,
Dir., Water Supply and Water Resour. Div., Nat. Risk Mgmt. Res. Lab., USEPA, 26 W. Martin L. King Dr., Cincinnati, OH 45268.
Mano Sivaganesan
Statistician, ALM Joint Venture, 250 E. Fifth St., Cincinnati, OH 45202.

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