TECHNICAL NOTES
Jul 1, 1996

Dissolution of Lead Paint in Aqueous Solutions

Publication: Journal of Environmental Engineering
Volume 122, Issue 7

Abstract

An analysis of the rate and extent of lead leaching from a lead-based paint was completed. At low-solution pH, dissolution was rapid and approached 80 of the total lead. Residual lead can be estimated based on the predicted solubility of lead carbonate and basic lead carbonate. Release of lead from the paint was slower than that from pure basic lead carbonate due to inhibition by the paint matrix. Although the dissolved concentration of lead in solution at neutral/high pH was low, the paint binder was apparently destroyed at these pH values, releasing colloidal lead pigment particles. The presence of ethylenediaminetetraacetic acid (EDTA) and nitrilotriacetic acid (NTA) enhanced both the rate and degree of lead dissolution, while benzoic acid had a minimal effect.

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References

1.
Carter, D. L., Mortland, M. M., and Kemper, W. D. (1986). “Specific surface.”Methods of soil analysis. Part I: physical and mineralogical methods, 2nd Ed., Am. Soc. of Agronomy-Soil Sci., Madison, Wisc., 413–422.
2.
Furrer, G., and Stumm, W. (1983). “The role of surface coordination in the dissolution of δ-Al 2 O 3 in dilute acids.”Chimia, Zurich, Switzerland, Vol. 37, 338–341.
3.
Furrer, G., and Stumm, W. (1986). “The coordination of weathering. I: dissolution kinetics of δ-Al 2 O 3 and BeO.”Geochim. Cosmochim. Acta, Vol. 50, 1847–1860.
4.
Holm, T. R., and Schock, M. R.(1991). “Potential effects of polyphosphate products on lead solubility in plumbing systems.”J. AWWA, 83(7), 76–82.
5.
Marani, D., Macchi, G., and Pagano, M.(1995). “Lead precipitation in the presence of sulphate and carbonate: testing of thermodynamic predictions.”Water Res., 29(4), 1085–1092.
6.
Schock, M. R. (1980). “Response of lead solubility to dissolved carbonate in drinking water.”J. AWWA, 72(12), 695–704; Erratum, J. AWWA, 73(3), 36.
7.
Schock, M. R.(1989). “Understanding corrosion control strategies for lead.”J. AWWA, 81(7), 88–100.
8.
Schock, M. R. (1990). “Internal corrosion and deposition control.”Water quality and treatment, 4th Ed., McGraw Hill Book Co., Inc., New York, N.Y., 997–1112.
9.
Schock, M. R., and Gardels, M. C.(1983). “Plumbosolvency reduction by high pH and low carbonate—solubility relationships.”J. AWWA, 75(2), 87–91.
10.
Smith, A. E., and Martell, R. M. (1977). Critical stability constants, Volume III . Plenum Press, New York, N.Y.
11.
Streitweiser Jr., A., and Heathcock, C. H. (1981). Introduction to organic chemistry, 2nd Ed., Macmillan, New York, N.Y.
12.
Stumm, W., and Furrer, G. (1987). “The dissolution of oxides and aluminum silicates: examples of surface-coordination-controlled kinetics.”Aquatic surface chemistry, W. Stumm, ed., John Wiley & Sons, Inc., New York, N.Y.
13.
Van Cappellen, P., Charlet, L., Stumm, W., and Wersin, P. (1993). “A surface complexation model of the carbonate mineral-aqueous solution interface.”Geochim. Cosmochim. Acta, Vol. 57, 3505–3518.

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Published In

Go to Journal of Environmental Engineering
Journal of Environmental Engineering
Volume 122Issue 7July 1996
Pages: 663 - 666

History

Published online: Jul 1, 1996
Published in print: Jul 1996

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Authors

Affiliations

Gregory L. Barnes
Engr., Gerald A. Cump & Associates, 121 E. Baltimore St., Hagarstown, MD 21740; formerly, Grad. Student, Civil Engrg. Dept., Univ. of Maryland, College Park, MD 20742.
Allen P. Davis, Member, ASCE
Assoc. Prof., Envir. Engrg. Program, Civil Engrg. Dept., Univ. of Maryland, College Park, MD.

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