Technical Papers
Oct 4, 2023

Bonding Performance of Sulfur-Based Polymers for Pavement Repair

Publication: Journal of Transportation Engineering, Part B: Pavements
Volume 149, Issue 4

Abstract

The bonding performance between sulfur-based polymers and silicate cement mortars was evaluated in this study. A sulfur-based polymer with high strength and rapid setting properties was developed using fly ash, sand, sulfur, and rubber, without water. The correlation of sulfur and rubber contents with flexural bonding strength, as well as the correlation of the polymerization process and pore distribution with flexural bonding strength, were examined. Results revealed that a certain threshold value exists for the effect of porosity on the flexural bonding strength, and the sulfur-based polymer shows improved adhesion performance when the pore-size distribution is roughly equivalent. The incorporation of rubber particles can significantly improve the matrix compactness and increase the flexural bonding strength of sulfur-based polymers. The flexural bonding of sulfur-based polymers tended to initially increase and then decrease at the sulfur contents of 20%, 25%, 30%, 35%, and 40%, and rubber contents of 1%, 2%, 3%, 4%, and 5%. The optimal flexural bonding strength of 6.29 MPa was achieved at 30% sulfur and 2% rubber, which was close to the original flexural strength of silicate cement mortar, and the compressive strength reached 36.7 MPa. Hence, the proposed sulfur-based polymer meets some basic mechanical property requirements of road repair materials.

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Data Availability Statement

All data, models, and code generated or used during the study appear in the published article.

Acknowledgments

The authors would like to thank the funding provided by Natural Science Foundation of Inner Mongolia (Grant No. 2020LH05003), Science and Technology Plan Project of Inner Mongolia (Grant No. 2021GG0317), and National Natural Science Foundation of China (Grant No. 52068059).

References

ACI (American Concrete Institute). 1993. Guide for mixing and placing sulfur concrete in construction. ACI 548.2R-93. Farmington Hills, MI: ACI.
Al-Fakih, A., B. S. Mohammed, and M. S. Liew. 2021. “On rubberized engineered cementitious composites (R-ECC): A review of the constituent material.” Case Stud. Constr. Mater. 14 (Jun): e00536. https://doi.org/10.1016/j.cscm.2021.e00536.
Al-Otaibi, S., A. Al-Aibani, S. Al-Bahar, M. Abdulsalam, and S. Al-Fadala. 2019. “Potential for producing concrete blocks using sulphur polymeric concrete in Kuwait.” J. King Saud Univ. Eng. Sci. 31 (4): 327–331. https://doi.org/10.1016/j.jksues.2018.02.004.
Al-Tayeb, M. M., B. H. Abu Bakar, H. M. Akil, and H. Ismail. 2013. “Performance of rubberized and hybrid rubberized concrete structures under static and impact load conditions.” Exp. Mech. 53 (3): 377–384. https://doi.org/10.1007/s11340-012-9651-z.
Al-Tayyib, A.-H. J., M. F. Tewfik, and M. S. Khan. 1991. “Strength and durability of sulfur mortar.” J. Mater. Civ. Eng. 3 (2): 154–164. https://doi.org/10.1061/(ASCE)0899-1561(1991)3:2(154).
ASTM. 2020. Standard specification for packaged, dry, rapid-hardening cementitious materials for concrete repairs. ASTM C928/C928M. West Conshohocken, PA: ASTM.
Beaudoin, J. J., and R. F. Feldman. 1984. “Durability of porous systems impregnated with dicyclopentadiene-modified sulphur.” Cem. Concr. Compos. 6 (1): 13–18. https://doi.org/10.1016/0262-5075(84)90055-1.
Chen, J., et al. 2021. “New innovations in pavement materials and engineering: A review on pavement engineering research 2021.” J. Traffic Transp. Eng. 8 (6): 815–999. https://doi.org/10.1016/j.jtte.2021.10.001.
Delatte, N. 2018. Concrete pavement design, construction, and performance. Boca Raton, FL: CRC Press.
Enayaty-Ahangar, T., and S. Motahari. 2014. “Fiber reinforcement of DCPD-modified sulfur mortar.” J. Mater. Civ. Eng. 26 (1): 1–5. https://doi.org/10.1061/(ASCE)MT.1943-5533.0000778.
Fediuk, R., Y. H. Mugahed Amran, M. A. Mosaberpanah, A. Danish, M. El-Zeadani, S. V. Klyuev, and N. Vatin. 2020. “A critical review on the properties and applications of sulfur-based concrete.” Materials 13 (21): 4712. https://doi.org/10.3390/ma13214712.
Guan, Y., Y. Gao, R. Sun, M. C. Won, and Z. Ge. 2017. “Experimental study and field application of calcium sulfoaluminate cement for rapid repair of concrete pavements.” Front. Struct. Civ. Eng. 11 (3): 338–345. https://doi.org/10.1007/s11709-017-0411-0.
Gwon, S., Y. Jeong, J. E. Oh, and M. Shin. 2017. “Sustainable sulfur composites with enhanced strength and lightweightness using waste rubber and fly ash.” Constr. Build. Mater. 135 (Mar): 650–664. https://doi.org/10.1016/j.conbuildmat.2017.01.024.
Gwon, S., S.-Y. Oh, and M. Shin. 2018. “Strength and microstructural characteristics of sulfur polymer composites containing binary cement and waste rubber.” Constr. Build. Mater. 181 (Aug): 276–286. https://doi.org/10.1016/j.conbuildmat.2018.06.043.
Lin, S.-L., J. S. Lai, and E. S. Chian. 1995. “Modifications of sulfur polymer cement (SPC) stabilization and solidification (S/S) process.” Waste Manage. 15 (5–6): 441–447. https://doi.org/10.1016/0956-053X(95)00049-6.
Liu, J., C.-W. Yan, J. Zhang, S.-G. Liu, and Z.-L. Jiang. 2023a. “Experimental study and modeling analysis of strength properties of sulfur-based polymers of waste ceramic fine aggregates.” Mater. Chem. Phys. 301 (Jun): 127614. https://doi.org/10.1016/j.matchemphys.2023.127614.
Liu, J. X., C. W. Yan, J. Li, J. Zhang, and S. G. Liu. 2023b. “Investigation on the mechanical properties and strengthening mechanism of solid-waste–sulfur-based cementitious composites.” Materials 16 (3): 1203. https://doi.org/10.3390/ma16031203.
Matusinović, T., J. Šipušić, and N. Vrbos. 2003. “Porosity-strength relation in calcium aluminate cement pastes.” Cem. Concr. Res. 33 (11): 1801–1806. https://doi.org/10.1016/S0008-8846(03)00201-1.
Mehta, P. K., and P. Monteiro. 2013. Concrete: Microstructure, properties, and materials. New York: McGraw-Hill.
Mohamed, A., and M. E. Gamal. 2007. “Sulfur based hazardous waste solidification.” Eng. Geol. 53 (1): 159–175. https://doi.org/10.1007/s00254-006-0631-4.
Mohamed, A.-M. O., and M. E. Gamal. 2009. “Hydro-mechanical behavior of a newly developed sulfur polymer concrete.” Cem. Concr. Compos. 31 (3): 186–194. https://doi.org/10.1016/j.cemconcomp.2008.12.006.
Mohammed, S., and V. Poornima. 2018. “Strength and durability study of sulphur concrete with replaced fine aggregate.” Mater. Today: Proc. 5 (11): 23888–23897. https://doi.org/10.1016/j.matpr.2018.10.181.
Moon, J., P. D. Kalb, L. Milian, and P. A. Northrup. 2016. “Characterization of a sustainable sulfur polymer concrete using activated fillers.” Cem. Concr. Compos. 67 (Mar): 20–29. https://doi.org/10.1016/j.cemconcomp.2015.12.002.
Nguyen, H.-A., T.-P. Chang, and J.-Y. Shih. 2018. “Engineering properties and bonding behavior of self-compacting concrete made with no-cement binder.” J. Mater. Civ. Eng. 30 (3): 04017294. https://doi.org/10.1061/(ASCE)MT.1943-5533.0002136.
Öztürk, O., and A. Öner. 2022. “Long-term durability of bitumen modified sulfur polymer concrete under freeze–thaw cycles.” Int. J. Civ. Eng. 20 (5): 529–543. https://doi.org/10.1007/s40999-021-00672-2.
Qasim, O. A. 2020. “Different concrete types affecting the bond strength and interfacial joints between new and old concrete.” IOP Conf. Ser.: Mater. Sci. Eng. 745 (1): 012169. https://doi.org/10.1088/1757-899X/745/1/012169.
Ren, G., Z. Tian, J. Wu, and X. Gao. 2021. “Effects of combined accelerating admixtures on mechanical strength and microstructure of cement mortar.” Constr. Build. Mater. 304 (Oct): 124642. https://doi.org/10.1016/j.conbuildmat.2021.124642.
SAC (Standardization Administration of the People’s Republic of China). 2011. Specifications for design of highway cement concrete pavement. JTG D40-2011. Beijing: Standards Press of China.
SAC (Standardization Administration of the People’s Republic of China). 2007. Common portland cement. GB175-2007. Beijing: Standards Press of China.
Shin, M., K. Kim, S.-W. Gwon, and S. Cha. 2014. “Durability of sustainable sulfur concrete with fly ash and recycled aggregate against chemical and weathering environments.” Constr. Build. Mater. 69 (Oct): 167–176. https://doi.org/10.1016/j.conbuildmat.2014.07.061.
Szajerski, P., A. Bogobowicz, H. Bem, and A. Gasiorowski. 2019. “Quantitative evaluation and leaching behavior of cobalt immobilized in sulfur polymer concrete composites based on lignite fly ash, slag and phosphogypsum.” J. Cleaner Prod. 222 (Jun): 90–102. https://doi.org/10.1016/j.jclepro.2019.03.010.
Vasilev, Y., V. Eremin, and D. Gorky. 2021. “Innovative sulfur-containing materials for transport construction in the Arctic region.” Transp. Res. Procedia 57 (Jan): 728–734. https://doi.org/10.1016/j.trpro.2021.09.106.
Vlahovic, M. M., S. P. Martinovic, T. D. Boljanac, P. B. Jovanic, and T. D. Volkov-Husovic. 2011. “Durability of sulfur concrete in various aggressive environments.” Constr. Build. Mater. 25 (10): 3926–3934. https://doi.org/10.1016/j.conbuildmat.2011.04.024.
Vlahović, M. M., M. M. Savić, S. P. Martinović, T. Đ. Boljanac, and T. D. Volkov-Husović. 2012. “Use of image analysis for durability testing of sulfur concrete and Portland cement concrete.” Mater. Des. 34 (Feb): 346–354. https://doi.org/10.1016/j.matdes.2011.08.026.
Wagenfeld, J. G., K. Al-Ali, S. Almheiri, A. F. Slavens, and N. Calvet. 2019. “Sustainable applications utilizing sulfur, a by-product from oil and gas industry: A state-of-the-art review.” Waste Manage. 95 (Jul): 78–89. https://doi.org/10.1016/j.wasman.2019.06.002.
Wang, X., S. Dong, A. Ashour, and B. Han. 2021. “Bond of nanoinclusions reinforced concrete with old concrete: Strength, reinforcing mechanisms and prediction model.” Constr. Build. Mater. 283 (May): 122741. https://doi.org/10.1016/j.conbuildmat.2021.122741.

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Go to Journal of Transportation Engineering, Part B: Pavements
Journal of Transportation Engineering, Part B: Pavements
Volume 149Issue 4December 2023

History

Received: Jan 31, 2022
Accepted: May 26, 2023
Published online: Oct 4, 2023
Published in print: Dec 1, 2023
Discussion open until: Mar 4, 2024

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Doctoral Student, College of Science, Inner Mongolia Univ. of Technology, Hohhot 010051, China. Email: [email protected]
Full Professor, Dept. of Mining Engineering, Inner Mongolia Autonomous Region Engineering Research Center for Eco-Building Materials and Fabricated Structure, Inner Mongolia Univ. of Technology, Hohhot 010051, China (corresponding author). Email: [email protected]
Changwang Yan [email protected]
Full Professor, Dept. of Mining Engineering and Civil Engineering, Inner Mongolia Autonomous Region Engineering Research Center for Eco-Building Materials and Fabricated Structure, Inner Mongolia Univ. of Technology, Hohhot 010051, China. Email: [email protected]
Shuguang Liu [email protected]
Full Professor, Dept. of Mining Engineering and Civil Engineering, Inner Mongolia Autonomous Region Engineering Research Center for Eco-Building Materials and Fabricated Structure, Inner Mongolia Univ. of Technology, Hohhot 010051, China. Email: [email protected]
Zhuolin Jiang [email protected]
Postgraduate Student, Dept. of Civil Engineering, Inner Mongolia Univ. of Technology, Hohhot 010051, China. Email: [email protected]

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