Technical Papers
Nov 8, 2023

Treatment of Landfill Nanofiltration Concentrated Leachate by Flocculation Combined with a Multistage Ozone/Bioreactor Based on a Field Scale

Publication: Journal of Environmental Engineering
Volume 150, Issue 1

Abstract

Nanofiltration concentrated leachate (NFCL) is a high-concentration organic wastewater produced from landfill leachate during the process of membrane advanced treatment, which is more difficult to treat than landfill leachate. In this study, the effect and cost of treating NFCL by flocculation combined with a multistage ozone/bioreactor process based on a field scale are discussed. The results show that the process has a good effect on the removal of organic matter and nitrogen pollutants in NFCL, with removal efficiencies of chemical oxygen demand, ammonia nitrogen, nitrate, and total nitrogen being 96.6%, 90.1%, 38.2%, and 75.8%, respectively. The effluent can meet the discharge standard of China’s standard with a direct operating cost of approximately USD 18.4820.82/m3. This study proved the effectiveness, structural rationality, and economic benefit of the process in a practical engineering application, and provided a certain theoretical basis and engineering reference for the wide application of the process in the treatment of leachate membrane concentrate.

Get full access to this article

View all available purchase options and get full access to this article.

Data Availability Statement

The data that support the findings of this study are available upon reasonable request from the corresponding author.

References

Ali, I., P. Singh, H. Y. Aboul-Enein, and B. Sharma. 2009. “Chiral analysis of ibuprofen residues in water and sediment.” Anal. Lett. 42 (12): 1747–1760. https://doi.org/10.1080/00032710903060768.
Bai, F., H. Tian, C. Wang, and J. Ma. 2023. “Treatment of nanofiltration concentrate of landfill leachate using advanced oxidation processes incorporated with bioaugmentation.” Environ. Pollut. 318 (Feb): 120827. https://doi.org/10.1016/j.envpol.2022.120827.
Basheer, A. A. 2018a. “Chemical chiral pollution: Impact on the society and science and need of the regulations in the 21st century.” Chirality 30 (4): 402–406. https://doi.org/10.1002/chir.22808.
Basheer, A. A. 2018b. “New generation nano-adsorbents for the removal of emerging contaminants in water.” J. Mol. Liq. 261 (Jul): 583–593. https://doi.org/10.1016/j.molliq.2018.04.021.
Basheer, A. A., and I. Ali. 2018. “Stereoselective uptake and degradation of (±)-o,p-DDD pesticide stereomers in water-sediment system.” Chirality 30 (9): 1088–1095. https://doi.org/10.1002/chir.22989.
Boumechhour, F., K. Rabah, C. Lamine, and B. M. Said. 2013. “Treatment of landfill leachate using Fenton process and coagulation/flocculation.” Water Environ. J. 27 (1): 114–119. https://doi.org/10.1111/j.1747-6593.2012.00332.x.
Chen, W., Z. Gu, S. Guo, and Q. Li. 2020. “Microwave-assisted Fe0-activated persulfate process for treating explosives in production wastewater.” Chem. Eng. J. 391 (Jan): 123497. https://doi.org/10.1016/j.cej.2019.123497.
Chen, W., Z. Gu, C. He, and Q. Li. 2023. “Molecular-level transformation of refractory organic matter during flocculation-ultraviolet/peroxymonosulfate treatment of MBR-treated landfill leachate.” J. Hazard. Mater. 443 (Feb): 130086. https://doi.org/10.1016/j.jhazmat.2022.130086.
Chen, W., Z. Gu, G. Ran, and Q. Li. 2021. “Application of membrane separation technology in the treatment of leachate in China: A review.” Waste Manage. 121 (Feb): 127–140. https://doi.org/10.1016/j.wasman.2020.12.002.
Chen, W., Z. Gu, P. Wen, and Q. Li. 2019. “Degradation of refractory organic contaminants in membrane concentrates from landfill leachate by a combined coagulation-ozonation process.” Chemosphere 217 (Feb): 411–422. https://doi.org/10.1016/j.chemosphere.2018.11.002.
Chen, W., P. Westerhoff, J. Leenheer, and K. Booksh. 2004. “Fluorescence excitation−Emission matrix regional integration to quantify spectra for dissolved organic matter.” Environ. Sci. Technol. 37 (24): 5701–5710. https://doi.org/10.1021/es034354c.
Chen, W., A. Zhang, Z. Gu, and Q. Li. 2018. “Enhanced degradation of refractory organics in concentrated landfill leachate by Fe0/H2O2 coupled with microwave irradiation.” Chem. Eng. J. 354 (Dec): 680–691. https://doi.org/10.1016/j.cej.2018.08.012.
Cheng, H., J. Ai, W. Zhang, X. Fu, Y. Du, and D. Wang. 2019. “Preparation of biological activated carbon (BAC) using aluminum salts conditioned sludge cake for the bio-refractory organic contaminants removal from anaerobically digested liquor.” Colloids Surf., A 561 (Jan): 89–100. https://doi.org/10.1016/j.colsurfa.2018.10.053.
China Environmental Science Press. 2002. Analysis method of water and wastewater. 4th ed. Beijing: China Environmental Science Press.
Chinese Standard. 2008. Standard for pollution control on the landfill site of municipal solid waste. GB 16889-2008. Beijing: China Environmental Science Press.
Dang, Q., X. Zhao, Y. Li, and B. Xi. 2022. “Revisiting the biological pathway for methanogenesis in landfill from metagenomic perspective-A case study of county-level sanitary landfill of domestic waste in North China plain.” Environ. Res. 222 (Apr): 115185. https://doi.org/10.1016/j.envres.2022.115185.
Deng, Y., and C. M. Ezyske. 2011. “Sulfate radical-advanced oxidation process (SR-AOP) for simultaneous removal of refractory organic contaminants and ammonia in landfill leachate.” Water Res. 45 (18): 6189–6194. https://doi.org/10.1016/j.watres.2011.09.015.
Deng, Y., C. Jung, R. Zhao, K. Torrens, and L. Wu. 2018. “Adsorption of UV-quenching substances (UVQS) from landfill leachate with activated carbon.” Chem. Eng. J. 350 (Oct): 739–746. https://doi.org/10.1016/j.cej.2018.04.056.
Ding, J., M. Jiang, G. Zhao, L. Wei, S. Wang, and Q. Zhao. 2021. “Treatment of leachate concentrate by electrocoagulation coupled with electro-Fenton-like process: Efficacy and mechanism.” Sep. Purif. Technol. 255 (Jan): 117668. https://doi.org/10.1016/j.seppur.2020.117668.
Feng, K., M. Bao, H. Li, and Q. Li. 2022. “Removal characteristics of ammonia nitrogen and refractory organic matter in waste leachate by Co2+/peroxymonosulfate process at high chloride ion concentration.” J. Environ. Chem. Eng. 10 (6): 108590. https://doi.org/10.1016/j.jece.2022.108590.
Feng, K., S. Mu, J. Bai, and Q. Li. 2021. “Microwave-enhanced iron–carbon-activated hydrogen peroxide process for the advanced treatment of semi-aerobic aged refuse biofilter effluent.” Environ. Sci. Water Res. Technol. 7 (12): 2321–2334. https://doi.org/10.1039/D1EW00577D.
Fu, L., C. Wu, Y. Zhou, J. Zuo, G. Song, and Y. Tan. 2019. “Ozonation reactivity characteristics of dissolved organic matter in secondary petrochemical wastewater by single ozone, ozone/H2O2, and ozone/catalyst.” Chemosphere 233 (Oct): 34–43. https://doi.org/10.1016/j.chemosphere.2019.05.207.
Gao, D.-W., and Z.-D. Wen. 2016. “Phthalate esters in the environment: A critical review of their occurrence, biodegradation, and removal during wastewater treatment processes.” Sci. Total Environ. 541 (Mar): 986–1001. https://doi.org/10.1016/j.scitotenv.2015.09.148.
Gripa, E., S. D. A. Daflon, R. de Almeida, F. V. da Fonseca, and J. C. Campos. 2023. “Landfill leachate treatment by high-pressure membranes and advanced oxidation techniques with a focus on ecotoxicity and by-products management: A review.” Process Saf. Environ. Prot. 173 (Mar): 747–764. https://doi.org/10.1016/j.psep.2023.03.074.
Gu, Z., W. Chen, C. He, and Q. Li. 2022. “Molecular insights into the transformation of refractory organic matter in landfill leachate nanofiltration concentrates during a flocculation and O3/H2O2 treatment.” J. Hazard. Mater. 435 (Aug): 128973. https://doi.org/10.1016/j.jhazmat.2022.128973.
Hoigné, J., and H. Bader. 1976. “The role of hydroxyl radical reactions in ozonation processes in aqueous solutions.” Water Res. 10 (5): 377–386. https://doi.org/10.1016/0043-1354(76)90055-5.
Hu, Y., Z. Gu, J. He, and Q. Li. 2022. “Novel strategy for controlling colloidal instability during the flocculation pretreatment of landfill leachate.” Chemosphere 287 (Jan): 132051. https://doi.org/10.1016/j.chemosphere.2021.132051.
Iskander, S. M., J. T. Novak, B. Brazil, and Z. He. 2017. “Percarbonate oxidation of landfill leachates towards removal of ultraviolet quenchers.” Environ. Sci. Water Res. Technol. 3 (6): 1162–1170. https://doi.org/10.1039/C7EW00343A.
Keyikoglu, R., O. Karatas, H. Rezania, M. Kobya, V. Vatanpour, and A. Khataee. 2021. “A review on treatment of membrane concentrates generated from landfill leachate treatment processes.” Sep. Purif. Technol. 259 (Mar): 118182. https://doi.org/10.1016/j.seppur.2020.118182.
Li, L., and R. K. Goel. 2010. “Role of hydroxyl radical during electrolytic degradation of contaminants.” J. Hazard. Mater. 181 (1–3): 521–525. https://doi.org/10.1016/j.jhazmat.2010.05.045.
Long, Y., J. Xu, D. Shen, Y. Du, and H. Feng. 2017. “Effective removal of contaminants in landfill leachate membrane concentrates by coagulation.” Chemosphere 167 (Jan): 512–519. https://doi.org/10.1016/j.chemosphere.2016.10.016.
Ntampou, X., A. I. Zouboulis, and P. Samaras. 2006. “Appropriate combination of physico-chemical methods (coagulation/flocculation and ozonation) for the efficient treatment of landfill leachates.” Chemosphere 62 (5): 722–730. https://doi.org/10.1016/j.chemosphere.2005.04.067.
Oloibiri, V., I. Ufomba, M. Chys, W. T. Audenaert, K. Demeestere, and S. W. Van Hulle. 2015. “A comparative study on the efficiency of ozonation and coagulation-flocculation as pretreatment to activated carbon adsorption of biologically stabilized landfill leachate.” Waste Manage. 43 (Sep): 335–342. https://doi.org/10.1016/j.wasman.2015.06.014.
Pinedo, M. L., B. D. Riascos, X. E. Quintero, and C. Costa. 2022. “Mechanism of pH sensitive flocculation for organic load and colour reduction in landfill leachate.” Waste Manage. 144 (May): 163–172. https://doi.org/10.1016/j.wasman.2022.03.020.
Ren, X., X. Xu, Y. Xiao, W. Chen, and K. Song. 2019. “Effective removal by coagulation of contaminants in concentrated leachate from municipal solid waste incineration power plants.” Sci. Total Environ. 685 (Oct): 392–400. https://doi.org/10.1016/j.scitotenv.2019.05.392.
Sato, Y., Q. Zeng, L. Meng, and G. Chen. 2021. “Importance of combined electrochemical process sequence and electrode arrangements: A lab-scale trial of real reverse osmosis landfill leachate concentrate.” Water Res. 192 (Mar): 116849. https://doi.org/10.1016/j.watres.2021.116849.
Schwantes, R., K. Chavan, D. Winter, C. Felsmann, and J. Pfafferott. 2018. “Techno-economic comparison of membrane distillation and MVC in a zero liquid discharge application.” Desalination 428 (Feb): 50–68. https://doi.org/10.1016/j.desal.2017.11.026.
State Environmental Protection Administration of China. 2002. Methods for detection and analysis of water and wastewater. 4th ed. Beijing: China Environmental Science Press.
Teng, C., K. Zhou, C. Peng, and W. Chen. 2021. “Characterization and treatment of landfill leachate: A review.” Water Res. 203 (Sep): 117525. https://doi.org/10.1016/j.watres.2021.117525.
Tizaoui, C., L. Bouselmi, L. Mansouri, and A. Ghrabi. 2007. “Landfill leachate treatment with ozone and ozone/hydrogen peroxide systems.” J. Hazard. Mater. 140 (1–2): 316–324. https://doi.org/10.1016/j.jhazmat.2006.09.023.
Turan, A., M. Kobya, C. Iskurt, E. Gengec, and A. Khataee. 2023. “A techno-economical assessment of treatment by coagulation-flocculation with aluminum and iron-bases coagulants of landfill leachate membrane concentrates.” Chemosphere 314 (Feb): 137750. https://doi.org/10.1016/j.chemosphere.2023.137750.
Wang, H., S. Zhang, X. He, Y. Yang, X. Yang, and S. W. H. Van Hulle. 2023. “Comparison of macro and micro-pollutants abatement from biotreated landfill leachate by single ozonation, O3/H2O2, and catalytic ozonation processes.” Chem. Eng. J. 452 (Jan): 139503. https://doi.org/10.1016/j.cej.2022.139503.
Wu, C., W. Chen, Z. Gu, and Q. Li. 2021. “A review of the characteristics of Fenton and ozonation systems in landfill leachate treatment.” Sci. Total Environ. 762 (Mar): 143131. https://doi.org/10.1016/j.scitotenv.2020.143131.
Xin, C., Z. Cheng, Z. You, H. Bai, and J. Wang. 2020. “Using EEM fluorescence to characterize the membrane integrity of membrane bioreactor (MBR).” J. Membr. Sci. 610 (Sep): 118356. https://doi.org/10.1016/j.memsci.2020.118356.
Yang, H.-R., B. Li, C.-Q. Zhang, J.-C. Yang, Y.-M. Zheng, M. Younas, Y.-H. Jiang, and Z.-H. Yuan. 2023. “Bipolar membrane electrodialysis for sustainable utilization of inorganic salts from the reverse osmosis concentration of real landfill leachate.” Sep. Purif. Technol. 308 (Mar):122898. https://doi.org/10.1016/j.seppur.2022.122898.
Yang, S., J. Yang, J. Tang, X. Zhang, J. Ma, and A. Zhang. 2022. “A comparative study of the degradation of refractory organic matter in MBR effluent from landfill leachate treatment by the microwave-enhanced iron-activated hydrogen peroxide and peroxydisulfate processes.” Process Saf. Environ. Prot. 162 (Jan): 955–964. https://doi.org/10.1016/j.psep.2022.04.003.
Yuan, Y., J. Liu, B. Gao, and J. Hao. 2021. “Ozone direct oxidation pretreatment and catalytic oxidation post-treatment coupled with ABMBR for landfill leachate treatment.” Sci. Total Environ. 794 (Nov): 148557. https://doi.org/10.1016/j.scitotenv.2021.148557.
Zhao, J., F. Ouyang, Y. Yang, and W. Tang. 2020. “Degradation of recalcitrant organics in nanofiltration concentrate from biologically pretreated landfill leachate by ultraviolet-Fenton method.” Sep. Purif. Technol. 235 (Mar): 116076. https://doi.org/10.1016/j.seppur.2019.116076.
Zhou, X., Y. Zheng, J. Zhou, and S. Zhou. 2015. “Degradation kinetics of photoelectrocatalysis on landfill leachate using codoped TiO2/Ti photoelectrodes.” J. Nanomater. 2015 (Jan): 810579. https://doi.org/10.1155/2015/810579.

Information & Authors

Information

Published In

Go to Journal of Environmental Engineering
Journal of Environmental Engineering
Volume 150Issue 1January 2024

History

Received: Jun 9, 2023
Accepted: Sep 18, 2023
Published online: Nov 8, 2023
Published in print: Jan 1, 2024
Discussion open until: Apr 8, 2024

Permissions

Request permissions for this article.

ASCE Technical Topics:

Authors

Affiliations

Qing Wang
Director, Xingrong Renewable Energy Co., Ltd., No. 57 Dong Qiachang St., Jinjiang District, Chengdu 610000, China.
Director, Sichuan Solid Waste and Chemicals Management Center, No. 57 Yingtong St., Jinniu District, Chengdu 610036, China (corresponding author). Email: [email protected]

Metrics & Citations

Metrics

Citations

Download citation

If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download.

View Options

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Media

Figures

Other

Tables

Share

Share

Copy the content Link

Share with email

Email a colleague

Share