Abstract

Groundwater flowing through a nonaqueous-phase liquid (NAPL) source zone may generate large NAPL-contaminated saturated soils and act as a long-term source of soils and groundwater contamination. Remediation efficiency and cost are greatly influenced by an accurate prediction of the thermal conductivity of NAPL-contaminated saturated soils. In this work, a series of thermal conductivity tests were carried out using a thermal probe method to investigate the influencing factors together with the prediction model. The results show that the thermal conductivity of contaminated saturated soil versus NAPL content can be divided into three stages. The variation of the thermal conductivity with NAPL content shows a slow decrease in the first stage, a significant decrease in the second stage, and a more moderate decrease in the third stage. Based on the 53 complete mineral data of soils collected from the literature, the thermal conductivity of the solid particle equation was modified. It is confirmed that quartz content is a crucial factor influencing ks and cannot be replaced by sand content. Subsequently, a new model is proposed for the prediction of the thermal conductivity of contaminated saturated soil. To improve the prediction accuracy of the model, a new normalized thermal conductivity equation (ke) and a relationship of θ and ks/kl were proposed to modify the new model. After modification, the new model can provide a well-performing prediction for the thermal conductivity of NAPL-contaminated saturated soils.

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Data Availability Statement

All data, models, and code generated or used during the study appear in the published article.

Acknowledgments

This research was financially supported by the National Key Research and Development Program of China (No. 2022YFC3702502), the National Natural Science Foundation of China (No. 41877240), and the Scientific Research Foundation of the Graduate School of Southeast University (No. YBPY1930).

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Go to Journal of Environmental Engineering
Journal of Environmental Engineering
Volume 149Issue 12December 2023

History

Received: Mar 24, 2023
Accepted: Jul 27, 2023
Published online: Sep 25, 2023
Published in print: Dec 1, 2023
Discussion open until: Feb 25, 2024

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Ph.D. Student, Jiangsu Key Laboratory of Urban Underground Engineering and Environmental Safety, Institute of Geotechnical Engineering, Southeast Univ., Nanjing, Jiangsu 210096, PR China. ORCID: https://orcid.org/0000-0003-1394-6690. Email: [email protected]
Professor, Jiangsu Key Laboratory of Urban Underground Engineering and Environmental Safety, Southeast Univ., Nanjing, Jiangsu 210096, PR China (corresponding author). ORCID: https://orcid.org/0000-0001-6602-1275. Email: [email protected]
Professor, Key Laboratory of Energy Thermal Conversion and Control of Ministry of Education, School of Energy and Environment, Southeast Univ., Nanjing, Jiangsu 210096, PR China. Email: [email protected]
Quanbin Jin [email protected]
Ph.D. Student, Jiangsu Key Laboratory of Urban Underground Engineering and Environmental Safety, Southeast Univ., Nanjing, Jiangsu 210096, PR China. Email: [email protected]
Qingsong Zhang [email protected]
Ph.D. Student, Jiangsu Key Laboratory of Urban Underground Engineering and Environmental Safety, Southeast Univ., Nanjing, Jiangsu 210096, PR China. Email: [email protected]
Ph.D. Student, Dept. of Earth and Environmental Sciences, Univ. of Manchester, Manchester M13 9PL, UK. ORCID: https://orcid.org/0000-0002-3276-8589. Email: [email protected]

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