Samarium (III)–Modified MCM-41 Supported Ionic Liquids as Efficient Heterogeneous Catalysts toward the Fixation of into Alkynyl Carboxylic Acids
Publication: Journal of Environmental Engineering
Volume 149, Issue 11
Abstract
In this work, a class of transition metal-modified MCM-41 mesoporous silica supported ionic liquids nanocatalysts were constructed and efficiently used as catalysts for the effective carboxylation of terminal alkynes through utilization. The main factors affecting the catalytic performance of carboxylation and its possible reaction mechanism were sufficiently discussed. The results showed that when the dosage was 0.2 g, the temperature was 40°C and the pressure was 0.3 MPa, the supported catalyst MCM-41@IL-Sm showed the optimal catalytic efficiency. The novel catalyst proved to be highly efficient for the sustainable synthesis of alkynyl carboxylic acids attributing good to excellent yields of 82%–95% within 7–12 h. Moreover, MCM-41@IL-Sm could be recycled and reused six times without noticeable decrease in catalytic activity from two-phase system under external heterogeneous field. The application of supported ionic liquids in the field of carbon dioxide carboxylation has injected a new power source for the efficient and effective production of value-added chemicals from waste .
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Data Availability Statement
All data, models, or code that support the findings of this study are available from the corresponding author upon reasonable request.
Acknowledgments
This work was supported by the National Natural Science Foundation of China (22368001), analysis and testing center of Anshun University and Research Foundation of Hubei Three Gorges Laboratory (SC213010).
Author contributions: Yu Lin Hu and Shuai Shuai Yang contributed to the conception of the study and its design. Material preparation, data collection, and analysis were performed by Yu Lin Hu. The manuscript draft was written by Yu Lin Hu and reviewed by Shuai Shuai Yang.
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Published In
Journal of Environmental Engineering
Volume 149 • Issue 11 • November 2023
Copyright
© 2023 American Society of Civil Engineers.
History
Received: Mar 1, 2023
Accepted: Jul 21, 2023
Published online: Sep 11, 2023
Published in print: Nov 1, 2023
Discussion open until: Feb 11, 2024
ASCE Technical Topics:
- [Inorganic compounds]
- Acids
- Business management
- Carbon compounds
- Carbon dioxide
- Chemical compounds
- Chemical properties
- Chemical wastes
- Chemicals
- Chemistry
- Engineering materials (by type)
- Environmental engineering
- Heterogeneity
- Material mechanics
- Materials engineering
- Nanomechanics
- Organic compounds
- Pollutants
- Porous media
- Practice and Profession
- Silica
- Sustainable development
- Wastes
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