Development and Evaluation of an Indigenous Natural Corrosion Inhibitor for Steel in Cementitious Systems
Publication: Journal of Materials in Civil Engineering
Volume 36, Issue 5
Abstract
This research developed and evaluated the corrosion-inhibiting efficiency of a natural inhibitor prepared from a bamboo tree [referred to as bamboo leaf extract (BLE)]. The corrosion behavior of steel in BLE-admixed cementitious systems was examined using dynamic-polarization tests and salt-fog tests. The effect of the addition of BLE on the workability and compressive strength of cementitious systems was studied using flow-table and compression tests on mortars. Increased concentration of BLE and the preimmersion period of steel in BLE-admixed pore solution resulted in the increase of corrosion potentials and the reduction of corrosion currents. Furthermore, the addition of BLE improved the workability and compressive strength of mortars, and the mass loss of steel in BLE-admixed mortar was observed to be less than that in the control (BLE-free) specimens. The inhibitor’s adsorption on the steel followed the Langmuir isotherm model, suggesting the formation of a protective layer at the steel–electrolyte interface, and accordingly, a 99% reduction of the corrosion current was achieved by preimmersing the steel in simulated concrete pore solution containing 700 ppm BLE for 7 days.
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Data Availability Statement
Some or all data, models or code that support the findings of this study are available from the corresponding author upon reasonable request.
Acknowledgments
The authors thank Professor Kallol Mondal (Department of Materials Science and Engineering, IIT Kanpur) for extending his lab facilities for corrosion tests. His support and help are gratefully acknowledged.
References
Ababneh, A. N., M. A. Sheban, and M. A. Abu-Dalo. 2012. “Effectiveness of benzotriazole as corrosion protection material for steel reinforcement in concrete.” J. Mater. Civ. Eng. 24 (2): 141–151. https://doi.org/10.1061/(ASCE)MT.1943-5533.0000374.
Ahmed, J. E. S., and G. M. Ganesh. 2022. “A comprehensive overview on corrosion in RCC and its prevention using various green corrosion inhibitors.” Buildings 12 (Aug): 1682. https://doi.org/10.3390/buildings12101682.
Al-Moghrabi, R. S., A. M. Abdel-Gaber, and H. T. Rahal. 2018. “A comparative study on the inhibitive effect of Crataegus oxyacantha and Prunus avium plant leaf extracts on the corrosion of mild steel in hydrochloric acid solution.” Int. J. Ind. Chem. 9 (Sep): 255–263. https://doi.org/10.1007/s40090-018-0154-3.
Anitha, R., S. Chitra, V. Hemapriya, I. Chung, S. Kim, and M. Prabakaran. 2019. “Implications of eco-addition inhibitor to mitigate corrosion in reinforced steel embedded in concrete.” Constr. Build. Mater. 213 (Aug): 246–256. https://doi.org/10.1016/j.conbuildmat.2019.04.046.
Asipita, S. A., M. Ismail, M. Z. Abd Majid, Z. A. Majid, C. Abdullah, and J. Mirza. 2014. “Green Bambusa Arundinacea leaves extract as a sustainable corrosion inhibitor in steel reinforced concrete.” J. Cleaner Prod. 67 (Mar): 139–146. https://doi.org/10.1016/j.jclepro.2013.12.033.
ASTM. 2015. Standard test method for corrosion potentials of uncoated reinforcing steel in concrete. ASTM C876-15. West Conshohocken, PA: ASTM.
ASTM. 2017. Standard practice for preparing, cleaning, and evaluating corrosion test specimens. ASTM G1-03(2017)e1. West Conshohocken, PA: ASTM.
ASTM. 2019. Standard practice for operating salt spray (fog) apparatus. ASTM B117-19. West Conshohocken, PA: ASTM.
ASTM. 2020. Standard test method for flow of hydraulic cement mortar. ASTM C1437-20. West Conshohocken, PA: ASTM.
Bažant, Z. P. 1979. “Physical model for steel corrosion in concrete sea structures—Theory.” J. Struct. Div. 105 (6): 1137–1153. https://doi.org/10.1061/JSDEAG.0005168.
Behera, P. K., S. Misra, and K. Mondal. 2020. “Corrosion behavior of strained rebar in simulated concrete pore solution.” J. Mater. Eng. Perform. 29 (3): 1939–1954. https://doi.org/10.1007/s11665-020-04708-x.
Behera, P. K., A. P. K. Moon, K. Mondal, and S. Misra. 2016. “Estimating critical corrosion for initiation of longitudinal cracks in RC structures considering phases and composition of corrosion products.” J. Mater. Civ. Eng. 28 (12): 04016158. https://doi.org/10.1061/(ASCE)MT.1943-5533.0001666.
BIS (Bureau of Indian Standards). 2005. Methods of physical tests for hydraulic cement. IS 4031: 1988 (Parts 3, 4, 5 and 6) (Reaffirmed 2005). New Delhi, India: BIS.
Bolzoni, F., A. Brenna, and M. Ormellese. 2022. “Recent advances in the use of inhibitors to prevent chloride-induced corrosion in reinforced concrete.” Cem. Concr. Res. 154 (Apr): 106719. https://doi.org/10.1016/j.cemconres.2022.106719.
Elsener, B., and U. Angst. 2016. “Corrosion inhibitors for reinforced concrete.” In Science and technology of concrete admixtures, 321–339. Sawston, UK: Woodhead. https://doi.org/10.1016/B978-0-08-100693-1.00014-X.
Helbert, V. S., L. Gaillet, T. Chaussadent, V. Gaudefroy, and J. Creus. 2020. “Rhamnolipids as an eco-friendly corrosion inhibitor of rebars in simulated concrete pore solution: Evaluation of conditioning and addition methods.” Corros. Eng. Sci. Technol. 55 (2): 91–102. https://doi.org/10.1080/1478422X.2019.1672008.
Liu, Y., and R. E. Weyers. 1998. “Modeling the time-to-corrosion cracking in chloride contaminated reinforced concrete structures.” ACI Mater. J. 95 (6): 675–681. https://doi.org/10.14359/410.
Mo, S., H. Luo, and N. Li. 2016. “Plant extracts as ‘green’ corosion inhibitors for steel in sulphuric acid.” Chem. Pap. 70 (9): 1131–1143. https://doi.org/10.1515/chempap-2016-0055.
Naderi, R., A. Bautista, F. Velasco, M. Soleimani, and M. Pourfath. 2022. “Green corrosion inhibition for carbon steel reinforcement in chloride-polluted simulated concrete pore solution using Urtica Dioica extract.” J. Build. Eng. 58 (Oct): 105055. https://doi.org/10.1016/j.jobe.2022.105055.
Ormellese, M., M. Berra, F. Bolzoni, and T. Pastore. 2006. “Corrosion inhibitors for chlorides induced corrosion in reinforced concrete structures.” Cem. Concr. Res. 36 (3): 536–547. https://doi.org/10.1016/j.cemconres.2005.11.007.
Ormellese, M., L. Lazzari, S. Goidanich, G. Fumagalli, and A. Brenna. 2009. “A study of organic substances as inhibitors for chloride-induced corrosion in concrete.” Corros. Sci. 51 (12): 2959–2968. https://doi.org/10.1016/j.corsci.2009.08.018.
Poursaee, A. 2010. “Corrosion of steel bars in saturated and concrete pore solution.” Concr. Res. Lett. 1 (3): 90–97.
Poursaee, A., and C. M. Hansson. 2007. “Reinforcing steel passivation in mortar and pore solution.” Cem. Concr. Res. 37 (7): 1127–1133. https://doi.org/10.1016/j.cemconres.2007.04.005.
Raja, P. B., S. Ghoreishiamiri, and M. Ismail. 2015. “Natural corrosion inhibitors for steel reinforcement in concrete—A review.” Surf. Rev. Lett. 22 (3): 1550040. https://doi.org/10.1142/S0218625X15500407.
Saraswathy, V., and H. Song. 2007. “Improving the durability of concrete by using inhibitors.” Build. Environ. 42 (1): 464–472. https://doi.org/10.1016/j.buildenv.2005.08.003.
Senguttuvan, J., S. Paulsamy, and K. Karthika. 2014. “Phytochemical analysis and evaluation of leaf and root parts of the medicial herb, Hypochaeris radicata L. for in vitro antioxidant activities.” Supplement, Asian Pac. J. Trop. Biomed. 4 (S5): S359–S367. https://doi.org/10.12980/APJTB.4.2014C1030.
Sliem, M. H., A. B. Radwan, F. S. Mohamed, N. A. Alnuaimi, and A. M. Abdullah. 2020. “An efficient green ionic liquid for the corrosion inhibition of reinforcement steel in neutral and alkaline highly saline simulated concrete pore solutions.” Nat. Sci. Rep. 10 (1): 14565. https://doi.org/10.1038/s41598-020-71222-4.
Söylev, T. A., and M. G. Richardson. 2008. “Corrosion inhibitors for steel in concrete: State-of-the-art report.” Constr. Build. Mater. 22 (4): 609–622. https://doi.org/10.1016/j.conbuildmat.2006.10.013.
Subbaiah, K., H. Lee, S. Mandal, and T. Park. 2021. “Conifer cone (Pinus resinosa) as a green corrosion inhibitor for steel rebar in chloride-contaminated synthetic concrete pore solutions.” ACS Appl. Mater. Interfaces 13 (36): 43676–43695. https://doi.org/10.1021/acsami.1c11994.
Tait, W. S. 1994. An introduction to electrochemical corrosion testing for practicing engineers and scientists. Racine, WI: Pair O Docs.
Teklegirogis, N. S., B. Pradhan, J. K. Prusty, and J. K. Das. 2022. “Effect of sodium nitrite as corrosion inhibitor against chloride-induced corrosion of steel rebar in geopolymer concrete containing fly ash and GGBS.” J. Mater. Civ. Eng. 34 (4): 04022007. https://doi.org/10.1061/(ASCE)MT.1943-5533.0004139.
Zhang, Y., and A. Poursaee. 2015. “Passivation and corrosion behavior of carbon steel in simulated concrete pore solution under tensile and compressive stresses.” J. Mater. Civ. Eng. 27 (8): 1–9. https://doi.org/10.1061/(ASCE)MT.1943-5533.0001199.
Zomorodian, A., R. Bagonyi, and A. Al-Tabbaa. 2021. “The efficiency of eco-friendly corrosion inhibitors in protecting steel reinforcement.” J. Build. Eng. 38 (Aug): 102171. https://doi.org/10.1016/j.jobe.2021.102171.
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© 2024 American Society of Civil Engineers.
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Received: Jun 7, 2023
Accepted: Nov 6, 2023
Published online: Feb 26, 2024
Published in print: May 1, 2024
Discussion open until: Jul 26, 2024
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