Technical Papers
Mar 26, 2024

Experimental Investigation on the Performance of Cement Mortar by Partial Replacement of the Standard Sands with Sulfide-Contained Iron Tailings

Publication: Journal of Materials in Civil Engineering
Volume 36, Issue 6

Abstract

The usage of iron tailings as construction aggregates is a potential route to save the cost of standard sands and protect the environment of mining area. This study mainly investigates the performance of cement mortars by partial replacement of the standard sands (SS) with sulfide-contained iron ore tailings (IOT). The physicomechanical properties, microstructure, and hydration products were measured by consistency test, porosity test, strength test, P-wave velocity test, scanning electron microscopy test (SEM), and X-ray diffraction test (XRD). It is proven that the graded IOT (GIOT), which has an identical particle size distribution with SS, is better than the ungraded IOT to serve as fine aggregate by replacing SS because a suitable GIOT content can better reduce the adverse effect of excess fine tailings (<0.15  mm) and sulfide on the cement mortar. The graded tailings cement mortar (GTCM) by using GIOT has denser pore structure, lower porosity, higher strength, and P-wave velocity than ungraded tailings cement mortar (UTCM) by using UIOT at the same curing condition and age. In addition, although a high sulfide content (approximately 4.44% to 5.55% by weight) by adding more than 40% GIOT is conducive to reduce the porosity and improve the strength of GTCM before 28 days, it is harmful for the long-term performance beyond 90 days. The expansive ettringite and gypsum produced by the reaction of excess sulfide will cause microcracks and thus reduce the strength beyond 40% GIOT. To ensure the long-term performance of GTCM, the sulfide content in the aggregate should be controlled below 3% by weight, and the optimal substitution ratio of GIOT corresponding to this sulfide content is approximately 20% to 30%.

Get full access to this article

View all available purchase options and get full access to this article.

Data Availability Statement

Some or all data, models, or code that support the findings of this study are available from the corresponding author upon reasonable request.

Acknowledgments

This work was supported by National Natural Science Foundation of China (Grant Nos. 42072300 and 41702291) and the Project of Natural Science Foundation of Hubei Province (Grant No. 2021CFA094). This work was supported by “The 14th Five Year Plan” Hubei Provincial advantaged characteristic disciplines (groups) project of Wuhan University of Science and Technology (Grant No. 2023A0303).

References

Adiguzel, D., S. Tuylu, and H. Eker. 2022. “Utilization of tailings in concrete products: A review.” Constr. Build. Mater. 360 (Dec): 129574. https://doi.org/10.1016/j.conbuildmat.2022.129574.
Andrews, A., E. F. Nyarko, A. A. Adjaottor, E. Nsiah-Baafi, and M. Adom-Asamoah. 2022. “Reuse and stabilization of sulphide mine tailings as fine aggregate for construction mortar.” J. Cleaner Prod. 357 (Jul): 131971. https://doi.org/10.1016/j.jclepro.2022.131971.
Arunachalam, K. P., S. Avudaiappan, N. Maureira, F. D. C. Garcia Filho, S. N. Monteiro, I. D. Batista, and A. R. de Azevedo. 2023. “Innovative use of copper mine tailing as an additive in cement mortar.” J. Mater. Res. Technol. 25 (Jun-Jul): 2261–2274. https://doi.org/10.1016/j.jmrt.2023.06.066.
Benzaazoua, M., T. Belem, and B. Bussière. 2002. “Chemical factors that influence the performance of mine sulphidic paste backfill.” Cem. Concr. Res. 32 (7): 1133–1144. https://doi.org/10.1016/S0008-8846(02)00752-4.
Chen, J. H., Y. X. Yuan, Q. Zhu, and J. Y. Duan. 2023. “High-temperature resistance of high-strength concrete with iron tailing sand.” J. Build. Eng. 63 (Part A): 105544. https://doi.org/10.1016/j.jobe.2022.105544.
China Tailings Comprehensive Utilization Report. 2022. “2022-2028 China tailings comprehensive utilization industry competition status and development prospect planning report.” Accessed April 15, 2022. https://www.chyxx.com/industry/1120536.html.
Chinese Standard. 2017. Polycarboxylates high performance water-reducing admixture. JG/T 11-2017. Beijing: Chinese Standard.
Chinese Standard. 2022. Sand for construction. GB/T 14684-2022. Beijing: China Building Material Council, Standards Press of China.
Dong, Q., B. Liang, L. F. Jia, and L. G. Jiang. 2019. “Effect of sulfide on the long-term strength of lead-zinc tailings cemented paste backfill.” Constr. Build. Mater. 200 (Mar): 436–446. https://doi.org/10.1016/j.conbuildmat.2018.12.069.
Esmaeili, J., A. Hossein, and O. Obinna. 2020. “Reuse potentials of copper mine tailings in mortar and concrete composites.” J. Mater. Civ. Eng. 32 (5): 04020084. https://doi.org/10.1061/(ASCE)MT.1943-5533.0003145.
Fall, M., and M. Pokharel. 2010. “Coupled effects of sulphate and temperature on the strength development of cemented tailings backfills: Portland cement-paste backfill.” Cement Concrete Comp. 32 (10): 819–828. https://doi.org/10.1016/j.cemconcomp.2010.08.002.
Filho, J. N. S., S. N. Da-Silva, G. C. Silva, and J. C. Mendes. 2017. “Technical and environmental feasibility of interlocking concrete pavers with iron ore tailings from tailings dam.” J. Mater. Civ. Eng. 29 (9): 04017104. https://doi.org/10.1061/(ASCE)MT.1943-5533.0001937.
Fontes, W. C., J. C. Mendes, S. N. Da-Silva, and R. A. F. Peixoto. 2016. “Mortars for laying and coating produced with iron ore tailings from tailing dams.” Constr. Build. Mater. 112 (Jun): 988–995. https://doi.org/10.1016/j.conbuildmat.2016.03.027.
Guner, N. U., E. Yilmaz, M. Sari, and T. Kasap. 2023. “Cementitious backfill with partial replacement of Cu-Rich mine tailings by sand: Rheological, mechanical and microstructural properties.” Minerals 13 (3): 437. https://doi.org/10.3390/min13030437.
Haach, V. G., G. Vasconcelos, and P. B. Lourenco. 2011. “Influence of aggregates grading and water/cement ratio in workability and hardened properties of mortars.” Constr. Build. Mater. 25 (6): 2980–2987. https://doi.org/10.1016/j.conbuildmat.2010.11.011.
He, X. B., J. Gao, Y. X. Liu, Y. K. Fang, D. Qiao, and W. F. Shen. 2022. “Gradation optimization of continuous-graded crushed sand based on mortar performance.” Constr. Build. Mater. 358 (Dec): 129423. https://doi.org/10.1016/j.conbuildmat.2022.129423.
Hu, L. M., H. Wu, L. Zhang, P. W. Zhang, and B. Qin. 2016. “Geotechnical properties of mine tailings.” J. Mater. Civ. Eng. 29 (2): 04016220. https://doi.org/10.1061/(ASCE)MT.1943-5533.0001736.
Huang, Z. Q., S. Cao, and E. Yilmaz. 2023. “Microstructure and mechanical behavior of cemented gold/tungsten mine tailings-crushed rock backfill: Effects of rock gradation and content.” J. Environ. Manage. 339 (Aug): 117897. https://doi.org/10.1016/j.jenvman.2023.117897.
Ince, C. 2019. “Reusing gold-mine tailings in cement mortars: Mechanical properties and socio-economic developments for the Lefke-Xeros area of Cyprus.” J. Cleaner Prod. 238 (Nov): 117871. https://doi.org/10.1016/j.jclepro.2019.117871.
Ince, C., S. Derogar, K. Gurkaya, and R. J. Ball. 2021. “Properties, durability and cost efficiency of cement and hydrated lime mortars reusing copper mine tailings of Lefke-Xeros in Cyprus.” Constr. Build. Mater. 268 (Jan): 121070. https://doi.org/10.1016/j.conbuildmat.2020.121070.
Jayasimha, N., B. Sujini, and B. P. Annapurna. 2022. “A study on durability and strength properties of high strength concrete with partial replacement of iron ore tailings with fine aggregates.” Mater. Today. Proc. 65 (2): 1922–1929. https://doi.org/10.1016/j.matpr.2022.05.163.
Jiang, H. Q., H. S. Yi, E. Yilmaz, S. W. Liu, and J. P. Qiu. 2020. “Ultrasonic evaluation of strength properties of cemented paste backfill: Effects of mineral admixture and curing temperature.” Ultrasonics 100 (Jan): 105983. https://doi.org/10.1016/j.ultras.2019.105983.
Jiang, Z., G. J. Cai, G. L. Tian, and X. N. Liu. 2022b. “Effect of aggregate particle size on mortar pore structure.” Constr. Build. Mater. 352 (Oct): 128988. https://doi.org/10.1016/j.conbuildmat.2022.128988.
Kasap, T., E. Yilmaz, N. U. Guner, and M. Sari. 2022. “Recycling dam tailings as cemented mine backfill: Mechanical and geotechnical properties.” Adv. Mater. Sci. Eng. 2022 (Apr): 6993068. https://doi.org/10.1155/2022/6993068.
Ke, X., H. B. Hou, M. Zhou, Y. Wang, and X. Zhou. 2015. “Effect of particle gradation on properties of fresh and hardened cemented paste backfill.” Constr. Build. Mater. 96 (Oct): 378–382. https://doi.org/10.1016/j.conbuildmat.2015.08.057.
Lee, S. T., H. Y. Moon, and R. N. Swamy. 2005. “Sulfate attack and role of silica fume in resisting strength loss.” Cem. Concr. Compos. 27 (1): 65–76. https://doi.org/10.1016/j.cemconcomp.2003.11.003.
Li, J. J., E. Yilmaz, and S. Cao. 2021. “Influence of industrial solid waste as filling material on mechanical and microstructural characteristics of cementitious backfills.” Constr. Build. Mater. 299 (Sep): 124288. https://doi.org/10.1016/j.conbuildmat.2021.124288.
Li, W. C., and M. Fall. 2016. “Sulphate effect on the early age strength and self-desiccation of cemented paste backfill.” Constr. Build. Mater. 106 (Mar): 296–304. https://doi.org/10.1016/j.conbuildmat.2015.12.124.
Li, X. Y., X. T. Yu, Y. Z. Zhao, X. G. Yu, C. S. Li, and D. Chen. 2022. “Effect of initial curing period on the behavior of mortar under sulfate attack.” Constr. Build. Mater. 326 (Apr): 126852. https://doi.org/10.1016/j.conbuildmat.2022.126852.
Liu, L., J. Xin, Y. Feng, B. Zhang, and K. I. Song. 2019a. “Effect of the cement-tailing ratio on the hydration products and microstructure characteristics of cemented paste backfill.” Arab. J. Sci. Eng. 44 (7): 6547–6556. https://doi.org/10.1007/s13369-019-03954-z.
Liu, L., J. Xin, C. Huan, C. C. Qi, W. W. Zhou, and K. I. Song. 2020. “Pore and strength characteristics of cemented paste backfill using sulphide tailings: Effect of sulphur content.” Constr. Build. Mater. 237 (Mar): 117452. https://doi.org/10.1016/j.conbuildmat.2019.117452.
Liu, L., C. Zhu, C. C. Qi, B. Zhang, and K. I. Song. 2019b. “A microstructural hydration model for cemented paste backfill considering internal sulfate attacks.” Constr. Build. Mater. 211 (Jun): 99–108. https://doi.org/10.1016/j.conbuildmat.2019.03.222.
MOHURD (Ministry of Housing and Urban-Rural Construction of the People’s Republic of China). 2009. Standard for test method of performance on building mortar. JGJ/T 70-2009. Beijing: MOHURD, China Architecture & Building Press.
MOHURD (Ministry of Housing and Urban-Rural Construction of the People’s Republic of China). 2010. Specification for mix proportion design of masonry mortar. JGJ/98-2010. Beijing: MOHURD, China Architecture & Building Press.
Ouellet, S., B. Bussiere, M. Mbonimpa, M. Benzaazoua, and M. Aubertin. 2006. “Reactivity and mineralogical evolution of an underground mine sulphidic cemented paste backfill.” Miner. Eng. 19 (5): 407–419. https://doi.org/10.1016/j.mineng.2005.10.006.
Pokharel, M., and M. Fall. 2013. “Combined influence of sulphate and temperature on the saturated hydraulic conductivity of hardened cemented paste backfill.” Cem. Concr. Compos. 38 (Apr): 21–28. https://doi.org/10.1016/j.cemconcomp.2013.03.015.
Protasio, F. N. M., R. R. Avillez, S. Letichevsky, and F. D. Silva. 2021. “The use of iron ore tailings obtained from the Germano Dam in the production of a sustainable concrete.” J. Cleaner Prod. 278 (Jan): 123929. https://doi.org/10.1016/j.jclepro.2020.123929.
Qiu, J. P., Z. B. Guo, L. Yang, H. Q. Jiang, and Y. L. Zhao. 2020. “Effect of tailings fineness on flow, strength, ultrasonic and microstructure characteristics of cemented paste backfill.” Constr. Build. Mater. 263 (Dec): 120645. https://doi.org/10.1016/j.conbuildmat.2020.120645.
Robeyst, N., C. U. Grosse, and N. De-Belie. 2009. “Measuring the change in ultrasonic p-wave energy transmitted in fresh mortar with additives to monitor the setting.” Cem. Concr. Res. 39 (10): 868–875. https://doi.org/10.1016/j.cemconres.2009.06.016.
Sari, M., E. Yilmaz, and T. Kasap. 2023. “Long-term ageing characteristics of cemented paste backfill: Usability of sand as a partial substitute of hazardous tailings.” J. Cleaner Prod. 401 (May): 136723. https://doi.org/10.1016/j.jclepro.2023.136723.
Shettima, A. U., M. W. Hussin, Y. Ahmad, and J. Mirza. 2016. “Evaluation of iron ore tailings as replacement for fine aggregate in concrete.” Constr. Build. Mater. 120 (Sep): 72–79. https://doi.org/10.1016/j.conbuildmat.2016.05.095.
Siddique, S., and J. G. Jang. 2020. “Assessment of molybdenum mine tailings as filler in cement mortar.” J. Build. Eng. 31 (Sep): 101322. https://doi.org/10.1016/j.jobe.2020.101322.
Wang, M. L., Q. Wang, J. H. Mao, S. S. Xu, and Z. Q. Shi. 2022a. “Study on water-repellent and corrosion-resistant properties of cement mortar using superhydrophobic iron ore tailings.” J. Build. Eng. 62 (Dec): 105360. https://doi.org/10.1016/j.jobe.2022.105360.
Wang, Z. Q., Y. Wang, L. Cui, C. Bi, and A. X. Wu. 2022b. “Insight into the isothermal multiphysics processes in cemented paste backfill: Effect of curing time and cement-to-tailings ratio.” Constr. Build. Mater. 325 (Mar): 126739. https://doi.org/10.1016/j.conbuildmat.2022.126739.
Westerholm, M., B. Lagerblad, J. Silfwerbrand, and E. Forssberg. 2008. “Influence of fine aggregate characteristics on the rheological properties of mortars.” Cem. Concr. Compos. 30 (4): 274–282. https://doi.org/10.1016/j.cemconcomp.2007.08.008.
Wu, D., Y. Zhang, and Y. Liu. 2016. “Mechanical performance and ultrasonic properties of cemented gangue backfill with admixture of fly ash.” Ultrasonics 64 (Jan): 89–96. https://doi.org/10.1016/j.ultras.2015.08.004.
Wu, J. Y., M. M. Feng, X. B. Mao, J. M. Xu, W. L. Zhang, X. Y. Ni, and G. S. Han. 2018. “Particle size distribution of aggregate effects on mechanical and structural properties of cemented rockfill: Experiments and modeling.” Constr. Build. Mater. 193 (Dec): 295–311. https://doi.org/10.1016/j.conbuildmat.2018.10.208.
Wu, J. Y., H. W. Jing, Y. Gao, Q. B. Meng, Q. Yin, and Y. Du. 2022a. “Effects of carbon nanotube dosage and aggregate size distribution on mechanical property and microstructure of cemented rockfill.” Cem. Concr. Compos. 127 (Mar): 104408. https://doi.org/10.1016/j.cemconcomp.2022.104408.
Wu, R. D., Y. Y. Zhang, G. T. Zhang, and S. H. An. 2022b. “Enhancement effect and mechanism of iron tailings powder on concrete strength.” J. Build. Eng. 57 (Oct): 104954. https://doi.org/10.1016/j.jobe.2022.104954.
Xu, W. B., Y. Cao, and B. H. Liu. 2019. “Efficiency evaluation of cemented tailings backfill with different stratified structures.” Eng. Struct. 180 (Feb): 18–28. https://doi.org/10.1016/j.engstruct.2018.11.030.
Ye, G., P. Lura, K. Breugel, and A. L. A. Fraaij. 2004. “Study on the development of the microstructure in cement-based materials by means of numerical simulation and ultrasonic pulse velocity measurement.” Cem. Concr. Compos. 26 (5): 491–497. https://doi.org/10.1016/S0958-9465(03)00081-7.
Yilmaz, E., T. Belem, M. Benzaazoua, A. Kesimal, B. Ercikdi, and F. Cihangir. 2011. “Use of high-density paste backfill for safe disposal of copper/zinc mine tailings.” Gospod. Surowcami. Min. 27 (3): 81–94.
Yilmaz, T., B. Ercikdi, K. Karaman, and G. Kulekci. 2014. “Assessment of strength properties of cemented paste backfill by ultrasonic pulse velocity test.” Ultrasonics 54 (5): 1386–1394. https://doi.org/10.1016/j.ultras.2014.02.012.
Yu, M. J., X. Y. Kong, J. S. Huang, J. X. Liu, J. Li, G. J. Wang, X. N. Li, X. Y. Fan, and B. L. Zhu. 2022. “Status of disposal of tailings as a solid waste and suggestions in China.” [In Chinese.] Ind. Miner. Process. 51 (1): 34–38. https://doi.org/10.16283/j.cnki.hgkwyjg.2022.01.007.
Zhang, W. F., X. W. Gu, J. P. Qiu, J. P. Liu, Y. Q. Zhao, and X. H. Li. 2020. “Effects of iron ore tailings on the compressive strength and permeability of ultra-high performance concrete.” Constr. Build. Mater. 260 (Nov): 1–14. https://doi.org/10.1016/j.conbuildmat.2020.119917.
Zhao, S. J., J. J. Fan, and W. Sun. 2014. “Utilization of iron ore tailings as fine aggregate in ultra-high performance concrete.” Constr. Build. Mater. 50 (Jan): 540–548. https://doi.org/10.1016/j.conbuildmat.2013.10.019.
Zhao, Y. Q., X. W. Gu, J. P. Qiu, W. F. Zhang, and X. H. Li. 2021. “Study on the utilization of iron tailings in ultra-high-performance concrete: Fresh properties and compressive behaviors.” Materials 14 (17): 4807. https://doi.org/10.3390/ma14174807.

Information & Authors

Information

Published In

Go to Journal of Materials in Civil Engineering
Journal of Materials in Civil Engineering
Volume 36Issue 6June 2024

History

Received: May 24, 2023
Accepted: Dec 6, 2023
Published online: Mar 26, 2024
Published in print: Jun 1, 2024
Discussion open until: Aug 26, 2024

Permissions

Request permissions for this article.

Authors

Affiliations

Professor, School of Resources and Environmental Engineering, Wuhan Univ. of Science and Technology, Wuhan 430081, China (corresponding author). ORCID: https://orcid.org/0000-0003-4836-3989. Email: [email protected]
Postgraduate Researcher, School of Resources and Environmental Engineering, Wuhan Univ. of Science and Technology, Wuhan 430081, China. Email: [email protected]
Senior Engineer, China First Metallurgical Construction Group Co., Ltd., No. 3 Gongye Rd., Qingshan District, Wuhan 430080, China. Email: [email protected]
Songyang Zhu [email protected]
Professor of Engineering, China First Metallurgical Construction Group Co., Ltd., No. 3 Gongye Rd., Qingshan District, Wuhan 430080, China. Email: [email protected]
Postgraduate Researcher, School of Resources and Environmental Engineering, Wuhan Univ. of Science and Technology, Wuhan 430081, China. Email: [email protected]
Postgraduate Researcher, School of Resources and Environmental Engineering, Wuhan Univ. of Science and Technology, Wuhan, Hubei 430081, China. Email: [email protected]

Metrics & Citations

Metrics

Citations

Download citation

If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download.

View Options

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Media

Figures

Other

Tables

Share

Share

Copy the content Link

Share with email

Email a colleague

Share