Effect of Antioxidant/CA-LDHs on the Properties of SBS-Modified Bitumen
Publication: Journal of Materials in Civil Engineering
Volume 36, Issue 3
Abstract
The cinnamic acid intercalated layered double hydroxides (CA-LDHs) were prepared by anion exchange method and analyzed by X-ray diffractometer (XRD) Fourier transform infrared (FTIR) spectrometer, scanning electron microscopy (SEM), contact angle goniometer, ultraviolet and visible (UV-vis) spectroscopy, and thermogravimetric (TG) analysis system. Then, the CA-LDHs were added to styrene-butadiene-styrene (SBS) modified bitumen together with an antioxidant composed of octadecyl-3-(3,5di-tert-butyl-4-hydroxyphenyl)-propionate (1076) and tris(2,4-di-tert-butylphenyl) phosphite (168) at a mass ratio of . The effects of antioxidant/CA-LDHs on the physical and rheological properties and chemical composition and characteristics of SBS-modified bitumen before and after pressurized aging vessel (PAV) and ultraviolet (UV) aging were investigated. The results revealed that CA was successfully intercalated into the interlayer space of LDHs. Meanwhile, the CA-LDHs performed improved hydrophobicity and UV absorption capacity compared with LDHs, resulting in enhanced compatibility of LDHs with SBS-modified bitumen, and then the antiaging properties of SBS-modified bitumen could be further strengthened, especially the anti-UV aging properties. Moreover, the mixture of antioxidants and CA-LDHs could synergistically improve the SBS-modified bitumen’s thermal- and photo-oxidative aging resistance.
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Data Availability Statement
The data sets generated or analyzed during this study are available from the corresponding author upon reasonable request.
Acknowledgments
This work is supported by the National Natural Science Foundation of China (Nos. 51708121, 52278446, and 52008113), and the Natural Science Foundation of Fujian Province (No. 2023J01061). The authors gratefully acknowledge their financial support.
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Published In
Journal of Materials in Civil Engineering
Volume 36 • Issue 3 • March 2024
Copyright
© 2023 American Society of Civil Engineers.
History
Received: May 3, 2023
Accepted: Aug 18, 2023
Published online: Dec 23, 2023
Published in print: Mar 1, 2024
Discussion open until: May 23, 2024
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