Technical Notes
Jun 25, 2024

Microwave-Mediated Polymer Bonding of Sands: Experimental Study

Publication: Journal of Materials in Civil Engineering
Volume 36, Issue 9

Abstract

Bonding of soil grains can be achieved by melting added polymer particles initially mixed with dry soil. Salient challenges associated with conventional external heating via boundary conduction include long treatment durations and inhomogeneous bonding. The current study aims to overcome these challenges via the use of microwaves to induce quick internal heating. Results of experiments on sand-silt specimens that contain a 10% fraction of natural microwave susceptor grains confirmed that internal heating produces homogeneous bonding much quicker than external heating (by a factor of 20), particularly when the target soil mass is relatively large. The tensile strength (qt) of specimens bonded via microwave heating was found to be inversely proportional to their fines content (FC), although the temperatures sustained by soils increased with increasing FC. Bonded specimens subject to a wetting–drying cycle exhibited lower tensile strengths than the unwetted counterparts. Yet, specimens subject to reexposure to microwaves after a wetting–drying cycle exhibited tensile strengths of at least 85% that of analogous unwetted specimens. The power penetration depth for 2.45 GHz microwaves was calculated to be 0.5  m<Sp<0.8  m for dry soils. Therefore, applications deemed worthy of future consideration include large brick manufacturing, rapid repair of temporary runways, and treatment of polymer particle-laden rammed-earth walls.

Get full access to this article

View all available purchase options and get full access to this article.

Data Availability Statement

Some or all the data, models, or code that support the findings of this study are available from the corresponding author upon reasonable request.

Acknowledgments

We acknowledge support by the SDSU Research Foundation, SEM support by Nha Uyen Huynh, FTIR spectrum by Amritesh Kumar, experimental support by Amanda Martinez, and insight offered by Milton Torikachvili. We also acknowledge support from the National Science Foundation (CMMI 1925539 and 2035663 and DBI 0959908) and the Department of Defense (W911NF1410039 and W911NF1810477).

References

Appleton, T. J., R. I. Colder, S. W. Kingman, I. S. Lowndes, and A. G. Read. 2005. “Microwave technology for energy-efficient processing of waste.” Appl. Energy 81 (1): 85–113. https://doi.org/10.1016/j.apenergy.2004.07.002.
ASTM. 2015. Standard test methods for wetting and drying compacted soil-cement mixtures. ASTM D559/D559M−15. West Conshohocken, PA: ASTM.
ASTM. 2016. Standard test method for splitting tensile strength of intact rock core specimens. ASTM D3967-16. West Conshohocken, PA: ASTM.
Bhattacharya, M., and T. Basak. 2016. “A review on the susceptor assisted microwave processing of materials.” Energy 97 (1): 306–338. https://doi.org/10.1016/j.energy.2015.11.034.
Cho, G. C., and J. C. Santamarina. 2001. “Unsaturated particulate materials—particle-level studies.” J. Geotech. Geoenviron. Eng. 127 (1): 84–96. https://doi.org/10.1061/(ASCE)1090-0241(2001)127:1(84).
Consoli, N. C., R. C. Cruz, M. F. Floss, and L. Festugato. 2010. “Parameters controlling tensile and compressive strength of artificially cemented sand.” J. Geotech. Geoenviron. Eng. 136 (5): 759–763. https://doi.org/10.1061/(ASCE)GT.1943-5606.0000278.
Cowger, W., Z. Steinmetz, A. Gray, K. Munno, J. Lynch, H. Hapich, S. Primpke, H. De Frond, C. Rochman, and O. Herodotou. 2021. “Microplastic spectral classification needs an open source community: Open specy to the rescue!” Anal. Chem. 93 (21): 7543–7548. https://doi.org/10.1021/acs.analchem.1c00123.
Daniels, D. J. 2005. Ground penetrating radar. Encyclopedia of RF and Microwave Engineering. Hoboken, NJ: Wiley.
Dash, S. K., and M. Hussain. 2011. “Lime stabilization of soils: Reappraisal.” J. Mater. Civ. Eng. 707–714. https://doi.org/10.1061/(ASCE)MT.1943-5533.0000431.
Decareau, R. V. 1985. Microwaves in the food processing industry. Cambridge, MA: Academic Press.
Filho, H. C. S., G. D. Miguel, and N. C. Consoli. 2022. “Porosity/cement index over a wide range of porosities and cement contents.” J. Mater. Civ. Eng. 34 (3): 06021011. https://doi.org/10.1061/(ASCE)MT.1943-5533.0004115.
Formela, K., A. Hejna, L. Zedler, X. Colom Fajula, and F. J. Cañavate Ávila. 2019. “Microwave treatment in waste rubber recycling–recent advances and limitations.” eXPRESS Polym. Lett. 13 (6): 565–588. https://doi.org/10.3144/expresspolymlett.2019.48.
Garcia, N. F., J. R. Valdes, and D. D. Cortes. 2015. “Strength characteristics of polymer bonded sands.” Geotech. Lett. 5 (3): 212–216. https://doi.org/10.1680/jgele.15.00089.
Gunasekera, C., S. Setunge, and D. W. Law. 2017. “Correlations between mechanical properties of low-calcium fly ash geopolymer concretes.” J. Mater. Civ. Eng. 29 (9): 04017111. https://doi.org/10.1061/(ASCE)MT.1943-5533.0001916.
Haeri, S. M., A. Hamidi, and N. Tabatabaee. 2005. “The effect of gypsum cementation on the mechanical behaviour of gravely sands.” Geotech. Test. J. 28 (4): 380–390. https://doi.org/10.1520/GTJ12574.
Hallikainen, M. T., F. T. Ulaby, M. C. Dobson, M. A. El-Rayes, and L.-K. Wu. 1985. “Microwave dielectric behavior of wet soil–Part 1: Empirical models and experimental observations.” IEEE Trans. Geosci. Remote Sens. GE-23 (1): 25–34. https://doi.org/10.1109/TGRS.1985.289497.
Katz, J. D. 1992. “Microwave sintering of ceramics.” Annu. Rev. Mater. Sci. 22 (1): 153–170. https://doi.org/10.1146/annurev.ms.22.080192.001101.
Kim, S., and J. C. Santamarina. 2016. “Rock crushing using microwave pre-treatment.” In Geo-Chicago 2016: Sustainable materials and resource conservation, 720–729. Reston, VA: ASCE. https://doi.org/10.1061/9780784480151.071.
Kingman, S. W. 2006. “Recent developments in microwave processing of minerals.” Int. Mater. Rev. 51 (1): 1–12. https://doi.org/10.1179/174328006X79472.
Latifi, N., S. Horpibulsuk, C. L. Meehan, M. Z. Abd Majid, M. M. Tahir, and E. T. Mohamad. 2017. “Improvement of problematic soils with biopolymer—An environmentally friendly soil stabilizer.” J. Mater. Civ. Eng. 29 (2): 04016204. https://doi.org/10.1061/(ASCE)MT.1943-5533.0001706.
Leblanc, J. L. 2009. Filled polymers: Science and industrial applications. Boca Raton, FL: CRC Press.
Lee, M., Y. M. Kwon, D. Y. Park, I. Chang, and G. C. Cho. 2022. “Durability and strength degradation of xanthan gum based biopolymer treated soil subjected to severe weathering cycles.” Sci. Rep. 12 (1): 19453. https://doi.org/10.1038/s41598-022-23823-4.
Matzler, C. 1998. “Microwave permittivity of dry sand.” IEEE Trans. Geosci. Remote Sens. 36 (1): 317–319. https://doi.org/10.1109/36.655342.
McGill, S., J. W. Walkiewicz, and A. Clark. 1995. Microwave heating of chemicals and minerals. Washington, DC: US Department of the Interior, Bureau of Mines.
Menezes, R. R., P. M. Souto, and R. H. G. A. Kiminami. 2012. “Microwave fast sintering of ceramic materials.” In Sintering of ceramics–new emerging techniques, edited by A. Lakshmanan, 3–26. Rijeka, Croatia: IntechOpen.
Meredith, R. J. 1976. “Microwave energy for high speed efficient vulcanization of extruded rubber.” J. Elastomers Plast. 8 (2): 191. https://doi.org/10.1177/009524437600800205.
Metaxas, A. C., and R. J. Meredith, eds. 1983. Industrial microwave heating: Power and energy series 4. 357. London: Peter Peregrinus.
Miranda, L. V., J. R. Valdes, and D. D. Cortes. 2017. “Solar bricks for lunar construction.” Constr. Build. Mater. 139 (1): 241–246. https://doi.org/10.1016/j.conbuildmat.2017.02.029.
Okrasinski, T. A., R. M. Koerner, and A. E. Lord. 1979. “Dielectric constant determination of soils at L band microwave frequencies.” Geotech. Test. J. 1 (3): 134–140. https://doi.org/10.1520/GTJ10384J.
Oliveira, P. J. V., L. D. Freitas, and J. P. Carmona. 2017. “Effect of soil type on the enzymatic calcium carbonate precipitation process used for soil improvement.” J. Mater. Civ. Eng. 29 (4): 04016263. https://doi.org/10.1061/(ASCE)MT.1943-5533.0001804.
Park, J., and J. C. Santamarina. 2017. “Revised soil classification system for coarse-fine mixtures.” J. Geotech. Geoenviron. Eng. 143 (8): 1–13. https://doi.org/10.1061/(ASCE)GT.1943-5606.0001705.
Park, S. S., T. T. Le, Z. Nong, H. D. Moon, and D. E. Lee. 2020. “Chemically induced calcium carbonate precipitation for improving strength of sand.” J. Mater. Civ. Eng. 32 (9): 04020238. https://doi.org/10.1061/(ASCE)MT.1943-5533.0003318.
Rios, S., A. Viana da Fonseca, N. C. Consoli, M. Floss, and N. Cristelo. 2013. “Influence of grain size and mineralogy on the porosity/cement ratio.” Géotech. Lett. 3 (3): 130–136. https://doi.org/10.1680/geolett.13.00003.
Roshankhah, S., A. V. Garcia, and J. C. Santamarina. 2021. “Thermal conductivity of sand-silt mixtures.” J. Geotech. Geoenviron. Eng. 147 (2): 06020031. https://doi.org/10.1061/(ASCE)GT.1943-5606.0002425.
Saitoh, S., Y. Suzuki, S. Nishioka, and R. Okumura. 1996. “Required strength of cement improved ground.” In Grouting and deep mixing, 557–562. Boca Raton, FL: CRC Press.
Santamarina, J. C., V. A. Rinaldi, D. Fratta, K. A. Klein, Y. H. Wang, G. C. Cho, and G. Cascante. 2005. “A survey of elastic and electromagnetic properties of near-surface soils.” In Near-surface geophysics: Society of exploration geophysicists, edited by D. K. Butler, 71–88. Tulsa, OK: Society of Exploration Geophysicists Library. https://doi.org/10.1190/1.9781560801719.ch4.
Sidess, A., V. Holdengraber, and A. Buchman. 1993. “A fundamental model for prediction of optimal particulate composite properties.” Composites 24 (4): 355–360. https://doi.org/10.1016/0010-4361(93)90046-B.
Sun, J., W. Wang, and Q. Yue. 2016. “Review on microwave-matter interaction fundamentals and efficient microwave-associated heating strategies.” Materials 9 (4): 231–256. https://doi.org/10.3390/ma9040231.
Tang, J. 2015. “Unlocking potentials of microwaves for food safety and quality.” J. Food Sci. 80 (8): E1776–E1793. https://doi.org/10.1111/1750-3841.12959.
Valdes, J. R., and D. D. Cortes. 2014. “Heat-induced bonding of sands.” In Vol. 234 of Proc., 2014 Geo-Congress: Geo-Characterization and Modeling for Sustainability, M. Abu-Farsakh, X. Yu, and L. R. Hoyos, 3721–3733. Reston, VA: ASCE.
Xiao, Y., H. Liu, B. Nan, and J. S. McCartney. 2018. “Gradation-dependent thermal conductivity of sands.” J. Geotech. Geoenviron. Eng. 144 (9): 06018010. https://doi.org/10.1061/(ASCE)GT.1943-5606.0001943.
Youssef, G. 2022. Applied mechanics of polymers: Properties, processing, and behavior. Amsterdam, Netherlands: Elsevier.
Yu, C., H. Wang, A. Zhou, X. Cai, and Z. Wu. 2019. “Experimental study on strength and microstructure of cemented soil with different suctions.” J. Mater. Civ. Eng. 31 (6): 04019082. https://doi.org/10.1061/(ASCE)MT.1943-5533.0002717.

Information & Authors

Information

Published In

Go to Journal of Materials in Civil Engineering
Journal of Materials in Civil Engineering
Volume 36Issue 9September 2024

History

Received: Apr 24, 2023
Accepted: Feb 5, 2024
Published online: Jun 25, 2024
Published in print: Sep 1, 2024
Discussion open until: Nov 25, 2024

Permissions

Request permissions for this article.

ASCE Technical Topics:

Authors

Affiliations

Ranya A. Zina
Graduate Research Assistant, Dept. of Civil, Construction, and Environmental Engineering, San Diego State Univ., 5500 Campanile Dr., San Diego, CA 92182.
Marco Pardo
Undergraduate Research Assistant, Dept. of Civil, Construction, and Environmental Engineering, San Diego State Univ., 5500 Campanile Dr., San Diego, CA 92182.
Professor, Dept. of Mechanical Engineering, San Diego State Univ., 5500 Campanile Dr., San Diego, CA 92182. ORCID: https://orcid.org/0000-0003-2029-7692
Professor, Dept. of Civil, Construction, and Environmental Engineering, San Diego State Univ., 5500 Campanile Dr., San Diego, CA 92182 (corresponding author). ORCID: https://orcid.org/0000-0002-1356-2788. Email: [email protected]

Metrics & Citations

Metrics

Citations

Download citation

If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download.

View Options

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Media

Figures

Other

Tables

Share

Share

Copy the content Link

Share with email

Email a colleague

Share