Technical Papers
Jan 24, 2024

Investigation on Engineering Characteristics of Lime-Stabilized Phosphogypsum Subgrade Filler

Publication: Journal of Materials in Civil Engineering
Volume 36, Issue 4

Abstract

Phosphogypsum, which contains toxic components (e.g., heavy metal elements and fluoride), is one of the byproducts of phosphoric acid production, and filling subgrade is one of the recycling methods for it. In this study, phosphogypsum was stabilized by lime to improve the mechanical properties [California bearing ratio (CBR), resilience modulus, unconfined compressive strength, and shear strength], water stability, and harmful substances dissolubility. Combined with scanning electron microscopy, the strength formation and water stability enhancement mechanism of lime-stabilized phosphogypsum (LSP) were explored. The results demonstrated that the mechanical properties of LSP were better with the lime content of 6%–10%. The CBR, resilience modulus, unconfined compressive strength, and shear strength were 3.35 times, 2.46 times, 8.61 times, and 1.39 times that of plain phosphogypsum, respectively. An intensity prediction model with a correlation of 97% was constructed. The CBR and resilience modulus softening coefficient of LSP reached best values when lime content was 6%–8%. The leaching concentration of arsenic, chromium, and lead of LSP with 2% lime met the quality standards of groundwater levels I, II, and IV, respectively. Fluoride and phosphate were not detected in LSP when lime content was greater than 6.0%. The results show that LSP is feasible as subgrade filler. Considering the mechanical properties, water stability, and dissolution of hazardous substances of LSP, it is recommended to add 6%–8% lime content to LSP as highway subgrade filler.

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Data Availability Statement

Some or all data, models, or codes that support the results of this study are available from the corresponding author upon reasonable request.

Acknowledgments

This work was supported by the Key R&D plan of Shaanxi Province [number 2023-YBSF-390], Innovation Capability Support Program of Shaanxi [number 2022TD-07], and Fundamental Research Funds for the Central Universities of CHD [number 300102212906].

References

Chambers, P. 2019. Standard methods for the examination of water and wastewater. Atlanta: Scientific e-Resources.
Chen, Q., Q. Zhang, and C. Qi. 2021. “Temperature-depending characteristics of strength and leaching toxicity of phosphogypsum-based cemented paste backfill.” China J. Nonferrous Met. 31 (4): 1084–1095. https://doi.org/10.11817/j.ysxb.1004.0609.2020-39736.
Chinese Standard. 2007. Identification standard for hazardous wastes—Identification for extraction toxicity. GB/T 5085.3. Beijing: Chinese Standard Press.
Chinese Standard. 2017. Standard for groundwater quality. GB/T 14848. Beijing: Chinese Standard Press.
Chinese Standard. 2020. Test methods of soils for highway engineering. JTG 3430-2020. Beijing: Chinese Standard Press.
Dong, M., T. Ling, and Q. Xu. 2002. “Mechanism on the phosphogypsum-improved semi-rigid basecourse.” China J. Highway Transp. 15 (2): 14–18.
Dutta, R. K., V. N. Khatri, and V. Panwar. 2017. “Strength characteristics of fly ash stabilized with lime and modified with phosphogypsum.” J. Build. Eng. 14 (Nov): 32–40. https://doi.org/10.1016/j.jobe.2017.09.010.
Gougar, M. L. D., B. E. Scheetz, and D. M. Roy. 1996. “Ettringite and C-S-H Portland cement phases for waste ion immobilization: A review.” Waste Manage. 16 (4): 295–303. https://doi.org/10.1016/S0956-053X(96)00072-4.
Gu, Z., A. Fang, S. Hua, Q. Zhao, L. Sun, X. Fan, L. Qian, and X. Ren. 2021. “Development of a soil stabilizer for road subgrade based on original phosphogypsum.” J. Renewable Mater. 9 (2): 253. https://doi.org/10.32604/jrm.2021.011912.
Hao, C., Z. Dong, C. Cheng, F. Long, X. Li, and C. Ge. 2022. “Environmental economic policy progress assessment report 2022.” Chin. J. Environ. Manage. 14 (3): 5–13.
Huang, Y., J. Qian, C. Liu, N. Liu, Y. Shen, Y. Ma, H. Sun, and Y. Fan. 2017. “Influence of phosphorus impurities on the performances of calcium sulfoaluminate cement.” Constr. Build. Mater. 149 (Sep): 37–44. https://doi.org/10.1016/j.conbuildmat.2017.05.028.
James, J., C. Arthi, G. Balaji, N. Chandraleka, and R. H. M. Naveen Kumar. 2022. “Lime activated flyash-phosphogypsum blend as a low-cost alternative binder.” Int. J. Environ. Sci. Technol. 19 (9): 8969–8978. https://doi.org/10.1007/s13762-021-03618-2.
James, J., and P. K. Pandian. 2016. “Role of phosphogypsum and ceramic dust in amending the early strength development of a lime stabilized expansive soil.” Int. J. Sustainable Constr. Eng. Technol. 7 (2): 38–49.
Ji, X., C. Dai, Z. Cui, and R. Zhou. 2021. “Research on engineering characteristics of curing agent stabilized phosphogypsum roadbed filler.” China J. Highway Transp. 34 (10): 225–233.
Kaltenbach, R., D. Diehl, and G. E. Schaumann. 2018. “Links between nanoscale and macroscale surface properties of natural root mucilage studied by atomic force microscopy and contact angle.” J. Colloid Interface Sci. 516 (Apr): 446–455. https://doi.org/10.1016/j.jcis.2018.01.079.
Ke, G., Z. Xia, H. Luo, K. Xiong, L. Xie, and F. Ou-Yang. 2018. “Road performance of calcined phosphogypsum modified phosphogypsum waste.” J. Civ. Eng. Manage. 35 (4): 58–64.
Kumar, S., R. K. Dutta, and B. Mohanty. 2014. “Engineering properties of bentonite stabilized with lime and phosphogypsum.” Slovak J. Civ. Eng. 22 (4): 35–44. https://doi.org/10.2478/sjce-2014-0021.
Long, J. 2019. “Application of phosphogypsum in subgrade pavement engineering.” Build. Technol. Dev. 46 (10): 151–152.
Meng, W. 2019. Research on improving road performance of phosphogypsum and titanium gypsum. Chengdu, China: Southwest Jiaotong Univ.
Meng, W., G. Jiang, D. Yuan, and J. Bao. 2022. “Road performance of modified phosphogypsum.” J. Build. Mater. 25 (1): 81–88.
Peng, B., W. Shang, H. Zhao, Y. Song, H. Deng, and Z. Yang. 2020. “Study on the mechanical properties and rational addition of phosphogypsum comprehensive stabilized soil.” New Build. Mater. 47 (8): 86–90.
Rashad, A. M. 2017. “Phosphogypsum as a construction material.” J. Cleaner Prod. 166 (Nov): 732–743. https://doi.org/10.1016/j.jclepro.2017.08.049.
Tian, T., Y. Yan, Z. Hu, Y. Xu, Y. Chen, and J. Shi. 2016. “Utilization of original phosphogypsum for the preparation of foam concrete.” Constr. Build. Mater. 115 (Jul): 143–152. https://doi.org/10.1016/j.conbuildmat.2016.04.028.
Xi, X., Q. Chen, Z. Jiang, and Q. Yang. 2021. “Study on the water resistance of non-calcined phosphogypsum-based composite cementitious materials.” New Build. Mater. 48 (10): 1–5.
Zhang, Y., Y. Luo, A. Xu, and J. Fang. 2020. “Stability of high salinity saline soil subgrade slope under influence of water content and shear strength.” J. Chang’an Univ. 40 (3): 22–32.

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Go to Journal of Materials in Civil Engineering
Journal of Materials in Civil Engineering
Volume 36Issue 4April 2024

History

Received: Mar 13, 2023
Accepted: Sep 14, 2023
Published online: Jan 24, 2024
Published in print: Apr 1, 2024
Discussion open until: Jun 24, 2024

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Ph.D. Candidate, Key Laboratory for Special Area Highway Engineering of Ministry of Education, Chang’an Univ., South Erhuan Middle Section, Xi’an 710064, China. Email: [email protected]
Xiaoping Ji [email protected]
Professor, Key Laboratory for Special Area Highway Engineering of Ministry of Education, Chang’an Univ., South Erhuan Middle Section, Xi’an 710064, China (corresponding author). Email: [email protected]
Junior Engineer, Municipal Administration Division, Management Office of Municipal Public Utilities of Changshu, Changshu, Jiangsu 215500, China. Email: [email protected]
Intermediate Engineer, Hangzhou Environmental Monitoring Center Station, Hangzhou Environmental Protection Bureau, Hangzhou 310007, China. Email: [email protected]
Master’s Candidate, Key Laboratory for Special Area Highway Engineering of Ministry of Education, Chang’an Univ., South Erhuan Middle Section, Xi’an 710064, China. Email: [email protected]
Master’s Candidate, Key Laboratory for Special Area Highway Engineering of Ministry of Education, Chang’an Univ., South Erhuan Middle Section, Xi’an 710064, China. Email: [email protected]
Master’s Candidate, Key Laboratory for Special Area Highway Engineering of Ministry of Education, Chang’an Univ., South Erhuan Middle Section, Xi’an 710064, China. Email: [email protected]
Ph.D. Candidate, Key Laboratory for Special Area Highway Engineering of Ministry of Education, Chang’an Univ., South Erhuan Middle Section, Xi’an 710064, China. Email: [email protected]

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